The invention provides a piezoelectric ceramic composite material and a preparation method thereof. The preparation method comprises the following steps: firstly, mixing and stirring Portland cement, aluminate cement, octadecanamide, beeswax, bisphenol A epoxy resin, bisphenol F epoxy resin, erythritol, 651 low-molecular polyamide, m-phenylenediamine, polyvinyl acetal, calcium propionate, sodium carboxymethyl cellulose, absolute ethyl alcohol and water, vacuumizing, and eliminating gas; then putting a piezoelectric ceramic sheet into a mold, pouring the mixture into the mold and vibrating, and continuing pouring to make the mold full of the mixture; and putting the mold into a vacuum system, vacuumizing, eliminating gas, then putting the mold into a standard curing room, curing, demolding, and continuing curing; and finally cutting until the piezoelectric ceramic sheet is exposed at two surfaces of the sample. The piezoelectric ceramic composite material has relatively low acoustic impedance rate and relatively high compressive strength, besides, noise can be effectively shielded, the sensor receiving performance is good, and in addition, a cement hydration reaction can be effectively detected.