Reactive dye acidproof agent and preparation method thereof
A technology of reactive dyes and acid-proofing agents, applied in dyeing methods, organic dyes, textiles and papermaking, etc., can solve the problems of low wet treatment fastness, fading, easy hydrolysis of chemical bonds, etc., and achieve the effect of improving acid-proofing effect.
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Embodiment 1
[0028] A kind of preparation method of reactive dye anti-acid agent, first take triethylenetetramine and methyl acrylate as raw materials to react to prepare terminal amine compound, then mix terminal amine compound with fluorine-containing monomer, initiator and crosslinking agent , modified nanomaterials are added together in the mixed solution of tributylmethylammonium bis(trifluoromethanesulfonyl)imide salt and 1-hydroxyethyl-3-methylimidazole dinitrile amine salt, and the ultrasonic wave is dispersed evenly to obtain A reactive dye anti-acid agent; wherein, the modified nano-material is made of nano-titanium carbonitride and selenous acid as raw materials, and then utilizes γ-aminoethylaminopropyltrimethoxy It is obtained by modifying silane.
[0029] The preparation method of the amino-terminated compound is as follows: first place 1kg of triethylenetetramine in a cold water bath, slowly and uniformly drop a mixed solution of 0.7kg of methyl acrylate and 3kg of methanol ...
Embodiment 2
[0039] A kind of preparation method of reactive dye anti-acid agent, first take triethylenetetramine and methyl acrylate as raw materials to react to prepare terminal amine compound, then mix terminal amine compound with fluorine-containing monomer, initiator and crosslinking agent , modified nanomaterials are added together in the mixed solution of tributylmethylammonium bis(trifluoromethanesulfonyl)imide salt and 1-hydroxyethyl-3-methylimidazole dinitrile amine salt, and the ultrasonic wave is dispersed evenly to obtain A reactive dye anti-acid agent; wherein, the modified nano-material is made of nano-titanium carbonitride and selenous acid as raw materials, and then utilizes γ-aminoethylaminopropyltrimethoxy It is obtained by modifying silane.
[0040]The preparation method of the amine-terminated compound is as follows: first place 1kg of triethylenetetramine in a cold water bath, slowly and uniformly drop a mixed solution of 0.9kg of methyl acrylate and 2kg of methanol u...
Embodiment 3
[0050] A kind of preparation method of reactive dye anti-acid agent, first take triethylenetetramine and methyl acrylate as raw materials to react to prepare terminal amine compound, then mix terminal amine compound with fluorine-containing monomer, initiator and crosslinking agent , modified nanomaterials are added together in the mixed solution of tributylmethylammonium bis(trifluoromethanesulfonyl)imide salt and 1-hydroxyethyl-3-methylimidazole dinitrile amine salt, and the ultrasonic wave is dispersed evenly to obtain A reactive dye anti-acid agent; wherein, the modified nano-material is made of nano-titanium carbonitride and selenous acid as raw materials, and then utilizes γ-aminoethylaminopropyltrimethoxy It is obtained by modifying silane.
[0051] The preparation method of the amine-terminated compound is as follows: first place 1 kg of triethylenetetramine in a cold water bath, slowly and uniformly drop a mixed solution of 0.8 kg of methyl acrylate and 2.5 kg of meth...
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