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Reactive dye acidproof agent and preparation method thereof

A technology of reactive dyes and acid-proofing agents, applied in dyeing methods, organic dyes, textiles and papermaking, etc., can solve the problems of low wet treatment fastness, fading, easy hydrolysis of chemical bonds, etc., and achieve the effect of improving acid-proofing effect.

Active Publication Date: 2021-03-30
临清三和纺织集团有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Although the reactive group in the reactive dye molecule is easy to bond with the fiber by covalent bond, the color fastness is not ideal
During the dyeing process, especially when dyeing dark colors, there will often be a large amount of unfixed reactive dyes on the dyed fabric due to the high concentration of the dye. These unfixed dyes are difficult to wash off from the dyed fabric. This part The dye will fade during the washing process; at the same time, the chemical bonds formed between some active groups and fibers are easily hydrolyzed, resulting in low wet fastness
Moreover, the acid resistance of fabrics dyed with reactive dyes is poor, causing problems such as fabrics are easy to fade

Method used

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  • Reactive dye acidproof agent and preparation method thereof

Examples

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Comparison scheme
Effect test

Embodiment 1

[0028] A kind of preparation method of reactive dye anti-acid agent, first take triethylenetetramine and methyl acrylate as raw materials to react to prepare terminal amine compound, then mix terminal amine compound with fluorine-containing monomer, initiator and crosslinking agent , modified nanomaterials are added together in the mixed solution of tributylmethylammonium bis(trifluoromethanesulfonyl)imide salt and 1-hydroxyethyl-3-methylimidazole dinitrile amine salt, and the ultrasonic wave is dispersed evenly to obtain A reactive dye anti-acid agent; wherein, the modified nano-material is made of nano-titanium carbonitride and selenous acid as raw materials, and then utilizes γ-aminoethylaminopropyltrimethoxy It is obtained by modifying silane.

[0029] The preparation method of the amino-terminated compound is as follows: first place 1kg of triethylenetetramine in a cold water bath, slowly and uniformly drop a mixed solution of 0.7kg of methyl acrylate and 3kg of methanol ...

Embodiment 2

[0039] A kind of preparation method of reactive dye anti-acid agent, first take triethylenetetramine and methyl acrylate as raw materials to react to prepare terminal amine compound, then mix terminal amine compound with fluorine-containing monomer, initiator and crosslinking agent , modified nanomaterials are added together in the mixed solution of tributylmethylammonium bis(trifluoromethanesulfonyl)imide salt and 1-hydroxyethyl-3-methylimidazole dinitrile amine salt, and the ultrasonic wave is dispersed evenly to obtain A reactive dye anti-acid agent; wherein, the modified nano-material is made of nano-titanium carbonitride and selenous acid as raw materials, and then utilizes γ-aminoethylaminopropyltrimethoxy It is obtained by modifying silane.

[0040]The preparation method of the amine-terminated compound is as follows: first place 1kg of triethylenetetramine in a cold water bath, slowly and uniformly drop a mixed solution of 0.9kg of methyl acrylate and 2kg of methanol u...

Embodiment 3

[0050] A kind of preparation method of reactive dye anti-acid agent, first take triethylenetetramine and methyl acrylate as raw materials to react to prepare terminal amine compound, then mix terminal amine compound with fluorine-containing monomer, initiator and crosslinking agent , modified nanomaterials are added together in the mixed solution of tributylmethylammonium bis(trifluoromethanesulfonyl)imide salt and 1-hydroxyethyl-3-methylimidazole dinitrile amine salt, and the ultrasonic wave is dispersed evenly to obtain A reactive dye anti-acid agent; wherein, the modified nano-material is made of nano-titanium carbonitride and selenous acid as raw materials, and then utilizes γ-aminoethylaminopropyltrimethoxy It is obtained by modifying silane.

[0051] The preparation method of the amine-terminated compound is as follows: first place 1 kg of triethylenetetramine in a cold water bath, slowly and uniformly drop a mixed solution of 0.8 kg of methyl acrylate and 2.5 kg of meth...

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Abstract

The invention discloses a reactive dye acidproof agent and a preparation method thereof. The preparation method comprises the following steps: firstly, taking trivinyl tetramine and methyl acrylate asraw materials to react to prepare an amino-terminated compound; and then adding the amino-terminated compound, a fluorine-containing monomer, an initiator, a cross-linking agent and the modified nanomaterial into a mixed solution of tributyl methyl ammonium bis (trifluoromethanesulfonyl) imide salt and 1-hydroxyethyl-3-methylimidazole dinitrile amine salt, and carrying out uniform ultrasonic dispersion to obtain the reactive dye acid-proof agent, so that the acid-proof effect of the reactive dye is greatly improved.

Description

technical field [0001] The invention relates to an antiacid agent for reactive dyes and a preparation method thereof. It belongs to the technical field of dye auxiliaries. Background technique [0002] Reactive dyes, also known as reactive dyes, are a new class of water-soluble dyes that appeared in the 1950s. Reactive dye molecules contain active groups that can react with hydroxyl groups in cellulose and amino groups in protein fibers. A covalent bond is formed, resulting in a "dye-fiber" compound. Reactive dyes have the characteristics of bright color, good level dyeing, simple dyeing method, high color fastness, complete color spectrum and low cost. [0003] Although the reactive groups in the reactive dye molecules are easy to bond with the fibers through covalent bonds, the color fastness is not ideal. During the dyeing process, especially when dyeing dark colors, there will often be a large amount of unfixed reactive dyes on the dyed fabric due to the high concentr...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F220/24C08F222/14C08F220/28C08K9/06C08K3/28C09B67/24C09B67/10D06P1/52D06P1/673
CPCC08F220/24C08K9/06C08K3/28C09B67/0014C09B67/0072D06P1/525D06P1/673C08K2201/011C08F222/103C08F220/58
Inventor 宛斌杜尧森王腾军刘秀峰袁辉刘鹏远陈冬冬
Owner 临清三和纺织集团有限公司
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