Scratch-resistant thermoplastic elastomer and preparation method thereof

A thermoplastic elastomer and scratch-resistant technology, applied in the field of thermoplastic elastomers, can solve the problems of the appearance of easy wear marks on the surface, easy wear marks on the surface, and inconspicuous whitening from scratches, etc. The hardness range is adjustable and good. Mechanical properties, the effect of improving flow and gloss

Inactive Publication Date: 2021-03-30
安徽中翰高分子科技有限公司
View PDF10 Cites 2 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, due to the interface between the filled inorganic component and the polymer matrix, the interface is the most easily damaged part of the two phases. When the content of the inorganic material exceeds a certain content, the material is prone to scratching and whitening, and the surface is easy to wear and leave marks Insufficient and poor appearance and other problems; in order to solve the problems of scratch whitening, easy wear and tear on the surface, etc., the prior art usually chooses to reduce the content of inorganic materials. When the amount is less than 10%, the scratch whitening is not obvious, But the cost is to sacrifice the cost performance of materials and a certain degree of market competition space.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] A scratch-resistant thermoplastic elastomer, comprising the following raw materials in parts by weight: 100 parts of hydrogenated styrene thermoplastic elastomer, 200 parts of plasticizing system, 135 parts of plasticizing reinforcing resin, 140 parts of filling system, 1 part of antioxidant, 10 parts of scratching agent, 6 parts of coloring agent.

[0027] The hydrogenated styrene-based thermoplastic elastomer is styrene-ethylene / butylene-styrene block copolymer, which is SEBSYH-503T; the plasticizing system is paraffin oil PIONIER 1535; the plasticizing reinforcing resin is polypropylene, and the filling system is 800 mesh Calcium carbonate; antioxidant 1010 antioxidant and 168 antioxidant, 1010 antioxidant and 168 antioxidant mixed in a mass ratio of 1:2; anti-scratch agent is polysiloxane.

[0028] The preparation method of the scratch-resistant thermoplastic elastomer specifically includes the following steps:

[0029] (1) Add hydrogenated styrene-based thermoplas...

Embodiment 2

[0034] A scratch-resistant thermoplastic elastomer, comprising the following raw materials in parts by weight: 100 parts of hydrogenated styrene thermoplastic elastomer, 150 parts of plasticizing system, 85 parts of plasticizing reinforcing resin, 140 parts of filling system, 1 part of antioxidant, silicon 8 parts of ketone powder, 6 parts of coloring agent.

[0035] The hydrogenated styrene-based thermoplastic elastomer is styrene-ethylene / butylene-styrene block copolymer, which is SEBSYH-503T; the plasticizing system is paraffin oil PIONIER 1535; the plasticizing reinforcing resin is polypropylene, and the filling system is 800 mesh Calcium carbonate; antioxidant 1010 antioxidant and 168 antioxidant, 1010 antioxidant and 168 antioxidant mixed in a mass ratio of 1:2; silicone powder is a commercially available general molecular weight organic silicone.

[0036] The preparation method of the scratch-resistant thermoplastic elastomer specifically includes the following steps:

...

Embodiment 3

[0042] A scratch-resistant thermoplastic elastomer, comprising the following raw materials in parts by weight: 100 parts of hydrogenated styrene thermoplastic elastomer, 200 parts of plasticizing system, 145 parts of plasticizing reinforcing resin, 140 parts of filling system, 1 part of antioxidant, 3 parts of scratching agent, 6 parts of coloring agent.

[0043] Hydrogenated styrene-based thermoplastic elastomer adopts styrene-ethylene / butylene-styrene block copolymer, which is SEBSYH-503T; the plasticizing system adopts paraffin oil PIONIER 1535; the plasticizing reinforcing resin is polypropylene, and the filling system is talcum powder ; The antioxidant uses 1010 antioxidant and 168 antioxidant, and the 1010 antioxidant and 168 antioxidant are mixed in a mass ratio of 1:2; the scratch-resistant agent is polysiloxane.

[0044] The preparation method of the scratch-resistant thermoplastic elastomer specifically includes the following steps:

[0045] (1) Add hydrogenated sty...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
flash pointaaaaaaaaaa
tensile strengthaaaaaaaaaa
melt flow indexaaaaaaaaaa
Login to view more

Abstract

The invention discloses a scratch-resistant thermoplastic elastomer and a preparation method thereof in the technical field of thermoplastic elastomers. The scratch-resistant thermoplastic elastomer comprises the following raw materials, by weight: 50-200 parts of hydrogenated styrene thermoplastic elastomers, 20-400 parts of a plasticizing system, 40-200 parts of plasticizing reinforced resin, 0-200 parts of a filling system, 0.2-2 part of an antioxidant, 0.2-40 part of a scratch-resistant agent and 0-30 parts of a coloring agent. The thermoplastic elastomer material prepared by processing the hydrogenated styrene thermoplastic elastomer, the plasticizing system, the plasticizing reinforced resin, the filling system, the antioxidant, the scratch-resistant agent and the coloring system according to a certain ratio has good surface scratch resistance, soft touch and good mechanical properties; and the phenomena of whitening and mark leaving caused by interface damage in the scraping process are avoided, and wide application prospects are achieved in the fields of daily supplies, office automation, automobile accessories, household appliances, electric tools and the like.

Description

technical field [0001] The invention relates to the technical field of thermoplastic elastomers, in particular to a scratch-resistant thermoplastic elastomer and a preparation method thereof. Background technique [0002] With the rapid development of thermoplastic elastomers in the fields of daily necessities, office automation, auto parts, household appliances and electric tools, more and more applications begin to pay attention to the good quality of products while satisfying the appearance, touch and mechanical properties of materials. Scratch resistance. At present, composite materials are widely used in automotive interior products. However, the toughness and scratch resistance of most composite materials are poor. In order to make thermoplastic elastomer materials better meet the application requirements of automotive interior and other fields, especially the requirements of high-end automotive interior product materials, there is an urgent need for thermoplastic ela...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): C08L91/06C08L23/12C08L53/02C08L83/04C08K13/02C08K3/26C08K5/134C08K5/526C08K3/34
CPCC08L91/06C08K2003/265C08L2205/035C08L2207/04C08L2201/08
Inventor 夏玉洁龚梦晴
Owner 安徽中翰高分子科技有限公司
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products