A kind of rare earth extraction composite material, preparation method and application
A composite material and extraction technology, which is applied in the field of preparation and rare earth extraction composite materials, can solve the problems of low resource utilization rate and low extraction rate of extraction materials, and achieve the effects of low production cost, convenient production, and improved absorption rate
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Embodiment 1
[0029] A preparation method for composite material for extraction, comprising the following steps:
[0030] S1, the preparation of manganese-zirconium compound:
[0031] Mix the manganese sulfate solution with a concentration of 0.3mol / L and the sodium hydroxide solution with a concentration of 15%, and stir for 1~2h; then slowly add (NH 4 ) 2 S 2 o 8 Aqueous solution, let it stand for 0.5~1 h, add zirconia powder and stir evenly, among them, manganese sulfate solution, sodium hydroxide solution, (NH 4 ) 2 S 2 o 8 The weight ratio of aqueous solution to zirconia powder is 10:4:5:0.02, let it stand for 11 hours, centrifuge and separate the precipitate, wash the precipitate with distilled water until the washing liquid is free of SO 4 2- , followed by drying to obtain a manganese-zirconium compound;
[0032] Preparation of S2, 3-phenoxypropionate manganese-zirconium compound complex:
[0033] Mix 3-phenoxypropionic acid with the manganese-zirconium compound prepared by...
Embodiment 2
[0039] A preparation method for composite material for extraction, comprising the following steps:
[0040] S1, the preparation of manganese-zirconium compound:
[0041] Mix the manganese sulfate solution with a concentration of 0.3mol / L and the sodium hydroxide solution with a concentration of 15%, and stir for 1~2h; then slowly add (NH 4 ) 2 S 2 o 8Aqueous solution, let it stand for 0.5~1 h, add zirconia powder and stir evenly, among them, manganese sulfate solution, sodium hydroxide solution, (NH 4 ) 2 S 2 o 8 The weight ratio of aqueous solution to zirconia powder is 10:4:5:0.04, let it stand for 12 hours, centrifuge and separate the precipitate, wash the precipitate with distilled water until the washing liquid is free of SO 4 2- , followed by drying to obtain a manganese-zirconium compound;
[0042] Preparation of S2, 3-phenoxypropionate manganese-zirconium compound complex:
[0043] Mix 3-phenoxypropionic acid with the manganese-zirconium compound prepared by ...
Embodiment 3
[0049] A preparation method for composite material for extraction, comprising the following steps:
[0050] S1, the preparation of manganese-zirconium compound:
[0051] Mix the manganese sulfate solution with a concentration of 0.3mol / L and the sodium hydroxide solution with a concentration of 15%, and stir for 1~2h; then slowly add (NH 4 ) 2 S 2 o 8 Aqueous solution, let it stand for 0.5~1 h, add zirconia powder and stir evenly, among them, manganese sulfate solution, sodium hydroxide solution, (NH 4 ) 2 S 2 o 8 The weight ratio of the aqueous solution to the zirconia powder is 10:4:5:0.03, let it stand for 10 hours, centrifuge and separate the precipitate, wash the precipitate with distilled water until the washing liquid is free of SO 4 2- , followed by drying to obtain a manganese-zirconium compound;
[0052] Preparation of S2, 3-phenoxypropionate manganese-zirconium compound complex:
[0053] Mix 3-phenoxypropionic acid with the manganese-zirconium compound pre...
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