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A kind of rare earth extraction composite material, preparation method and application

A composite material and extraction technology, which is applied in the field of preparation and rare earth extraction composite materials, can solve the problems of low resource utilization rate and low extraction rate of extraction materials, and achieve the effects of low production cost, convenient production, and improved absorption rate

Active Publication Date: 2022-04-12
XUZHOU NANFANG YONGCI MATERIAL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the extraction rate of the extraction material prepared by the above method is low, resulting in low resource utilization in the rare earth extraction process.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] A preparation method for composite material for extraction, comprising the following steps:

[0030] S1, the preparation of manganese-zirconium compound:

[0031] Mix the manganese sulfate solution with a concentration of 0.3mol / L and the sodium hydroxide solution with a concentration of 15%, and stir for 1~2h; then slowly add (NH 4 ) 2 S 2 o 8 Aqueous solution, let it stand for 0.5~1 h, add zirconia powder and stir evenly, among them, manganese sulfate solution, sodium hydroxide solution, (NH 4 ) 2 S 2 o 8 The weight ratio of aqueous solution to zirconia powder is 10:4:5:0.02, let it stand for 11 hours, centrifuge and separate the precipitate, wash the precipitate with distilled water until the washing liquid is free of SO 4 2- , followed by drying to obtain a manganese-zirconium compound;

[0032] Preparation of S2, 3-phenoxypropionate manganese-zirconium compound complex:

[0033] Mix 3-phenoxypropionic acid with the manganese-zirconium compound prepared by...

Embodiment 2

[0039] A preparation method for composite material for extraction, comprising the following steps:

[0040] S1, the preparation of manganese-zirconium compound:

[0041] Mix the manganese sulfate solution with a concentration of 0.3mol / L and the sodium hydroxide solution with a concentration of 15%, and stir for 1~2h; then slowly add (NH 4 ) 2 S 2 o 8Aqueous solution, let it stand for 0.5~1 h, add zirconia powder and stir evenly, among them, manganese sulfate solution, sodium hydroxide solution, (NH 4 ) 2 S 2 o 8 The weight ratio of aqueous solution to zirconia powder is 10:4:5:0.04, let it stand for 12 hours, centrifuge and separate the precipitate, wash the precipitate with distilled water until the washing liquid is free of SO 4 2- , followed by drying to obtain a manganese-zirconium compound;

[0042] Preparation of S2, 3-phenoxypropionate manganese-zirconium compound complex:

[0043] Mix 3-phenoxypropionic acid with the manganese-zirconium compound prepared by ...

Embodiment 3

[0049] A preparation method for composite material for extraction, comprising the following steps:

[0050] S1, the preparation of manganese-zirconium compound:

[0051] Mix the manganese sulfate solution with a concentration of 0.3mol / L and the sodium hydroxide solution with a concentration of 15%, and stir for 1~2h; then slowly add (NH 4 ) 2 S 2 o 8 Aqueous solution, let it stand for 0.5~1 h, add zirconia powder and stir evenly, among them, manganese sulfate solution, sodium hydroxide solution, (NH 4 ) 2 S 2 o 8 The weight ratio of the aqueous solution to the zirconia powder is 10:4:5:0.03, let it stand for 10 hours, centrifuge and separate the precipitate, wash the precipitate with distilled water until the washing liquid is free of SO 4 2- , followed by drying to obtain a manganese-zirconium compound;

[0052] Preparation of S2, 3-phenoxypropionate manganese-zirconium compound complex:

[0053] Mix 3-phenoxypropionic acid with the manganese-zirconium compound pre...

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PUM

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Abstract

The present invention provides a kind of preparation method of rare earth extraction composite material, at first manganese sulfate solution and sodium hydroxide solution are mixed, slowly add (NH 4 ) 2 S 2 o 8 Aqueous solution, add zirconia powder and stir evenly, let stand, centrifuge, and dry to obtain manganese-zirconium compound; mix manganese-zirconium compound with 3-phenoxypropionic acid to obtain 3-phenoxypropionate manganese-zirconium compound compound ; Triethylenetetramine and N-n-butyl diacetimide are mixed and stirred to obtain modified N-n-butyl diacetimide; The manganese-zirconium oxypropionate compound compound is mixed and stirred evenly to form a target product rare earth extraction material; the invention also provides the application of the rare earth extraction compound material in the field of rare earth extraction. The invention has simple process, low production cost, can effectively improve the extraction rate, further improves the resource utilization rate in the rare earth extraction process, is simple to operate, has strong practicability, is suitable for industrial production, and can be widely used in the field of rare earth element extraction.

Description

technical field [0001] The invention belongs to the technical field of rare earth extraction materials, and in particular relates to a rare earth extraction composite material, a preparation method and an application. Background technique [0002] Rare earth elements, also known as rare earth metals, refer to the general term for 17 metal elements including lanthanides, scandium and yttrium. It is an important, non-renewable, scarce strategic resource, especially an important raw material for high-tech industries, and has been widely used in electronics, petrochemicals, metallurgy, machinery, energy, light industry, environmental protection, agriculture and other fields. my country is the country with the largest reserves of rare earth resources in the world. The application of rare earth elements in various fields is becoming more and more extensive. However, because the properties of different rare earth elements are very similar, the separation efficiency of rare earth el...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22B3/40C22B59/00
CPCC22B59/00
Inventor 张作州刘强
Owner XUZHOU NANFANG YONGCI MATERIAL
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