Organic compound, electroluminescent device containing organic compound and application thereof
An organic compound, an unsubstituted technology, applied in the field of electroluminescent devices, can solve the problems of further improvement of device comprehensive performance and high driving voltage, and achieve excellent comprehensive performance, reduce driving voltage and improve efficiency
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[0120] The preparation method of the compound of the present invention is not limited, typically but not limited to the following compounds as an example, its synthetic route and preparation method are as follows:
[0121] Synthesis Example 1: Synthesis of Compound a-1
[0122] Step 1: Synthesis of Intermediate B
[0123]
[0124] In a two-necked round bottom flask, A (12.0g, 37.24mmol), pinacol borate (14.19g, 55.86mmol), Pd(dppf)Cl 2 (0.82g, 1.12mmol), KOAc (9.14g, 93.1mmol) were added to 1,4-dioxane (220mL), under nitrogen protection, heated to reflux overnight. Heating was stopped, cooled to room temperature, filtered through diatomaceous earth, the filtrate was spin-dried and purified by silica gel column chromatography (PE / DCM=2:1) to obtain white solid Intermediate B (11.6g, 31.41mmol), with a yield of 84.4 %.
[0125] Step 2: Synthesis of compound a-1
[0126]
[0127] In a two-necked round bottom flask, B (10.3g, 27.89mmol), C (2.86g, 12.69mmol), Pd (PPh ...
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