Laminated film and packaging container
A technology of laminated film and adhesive layer, applied in the direction of packaging, containers, wrapping paper, etc., can solve the problems of difficult manufacturing, film damage, etc., and achieve excellent adhesion, simple manufacturing, retort resistance and content tolerance excellent effect
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Embodiment 1
[0163] The structure of the gas barrier film portion is the structure of the gas barrier film portion 10 in which a base film layer, a primer layer, a metal oxide vapor-deposited layer, and a gas barrier coating layer are sequentially laminated. After laminating the pattern ink on the side of the gas barrier coating layer, (A) (maleic anhydride graft-polymerized polypropylene, melting point: 106°C, density: 0.89g / cm 3 , MFR: 12g / 10 minutes), an adhesive layer was formed. Next, a corona discharge treatment was performed on one surface of an unstretched polypropylene film for retort sterilization (CPP, thickness 70 μm, manufactured by "Toray Film Processing" Co., Ltd., trade name "ZK500"), and the treated surface was pasted on On the adhesive layer side, a thermoplastic resin layer was laminated on the gas barrier film portion via the adhesive layer by thermal lamination to obtain the laminated film of Example 1.
[0164] Two sheets of the laminated film of Example 1 were pre...
Embodiment 2
[0167] The structure of the gas barrier film portion is the structure of the gas barrier film portion 10A in which a base film layer (treated with plasma), a metal oxide vapor-deposited layer, and a gas barrier coating layer are sequentially laminated. Use (B) (maleic anhydride graft polymerized polypropylene, melting point: 161°C, density: 0.88g / cm 3 , MFR: 9g / 10 minutes) and FL02C (polypropylene (not modified PP), melting point: 138°C, density: 0.89g / cm 3 , MFR: 18g / 10 minutes, "Nippon Polypro" Co., Ltd.) as an adhesive to form an adhesive layer, and utilize the melt extrusion method to laminate the entire surface with a thickness of each 10 μm, except that it is the same as in Example 1 The laminated film and packaging container of Example 2 were successfully produced.
Embodiment 3
[0169] The structure of the gas barrier film portion is the structure of the gas barrier film portion 10B in which the base film layer 11 and the gas barrier layer 16 are sequentially laminated. Using the trade name "Unistoll R-300" (maleic anhydride graft-polymerized polypropylene, melting point: 140°C, solid content concentration: 18% by mass, average particle diameter: 10 μm, manufactured by "Mitsui Chemicals Co., Ltd.") as Adhesives that form the bonding layer, and at 1.5g / m 2 Coated on the gas barrier film part. Other points were similar to Example 1, and the laminated film and packaging container of Example 3 were produced.
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