Preparation process of high-performance polycarboxylic acid water reducer applied to concrete
A kind of polycarboxylic acid series, preparation technology technology, applied in the field of concrete water reducing agent
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Embodiment 1
[0026] A preparation process of a high-performance polycarboxylate water reducer applied to concrete, comprising the following steps:
[0027] A. Dissolving the surfactant in ethanol, adding a hydrophilic fullerene derivative, performing mechanical stirring, ball milling, ultrasonic reaction treatment in sequence, and spray drying to obtain a surface-modified fullerene;
[0028] B. Take 100 parts of allyl polyoxyethylene ether in parts by mass, mix 40-60 parts of surface-modified fullerene and 3-8 parts of concentrated sulfuric acid, stir and heat up to 60-75°C, keep warm and ultrasonically treat for 30 -45min, obtain fullerene modified allyl polyoxyethylene ether;
[0029] C, then add 5-15 parts of methacrylic acid, 1-3 parts of sodium methacryl sulfonate, 0.1-0.4 parts of hydroquinone and 60-120 parts of deionized water and continue ultrasonic treatment for 15-25 minutes to obtain a mixed monomer solution;
[0030] D. Add 60-90 parts of deionized water into the reactor, ad...
Embodiment 2
[0042] A preparation process of a high-performance polycarboxylate water reducer applied to concrete, comprising the following steps:
[0043] A. Dissolving the surfactant in ethanol, adding a hydrophilic fullerene derivative, performing mechanical stirring, ball milling, ultrasonic reaction treatment in sequence, and spray drying to obtain a surface-modified fullerene;
[0044]B. Take 100 parts of allyl polyoxyethylene ether in parts by mass, mix 40-60 parts of surface-modified fullerene and 3-8 parts of concentrated sulfuric acid, stir and heat up to 60-75°C, keep warm and ultrasonically treat for 30 -45min, obtain fullerene modified allyl polyoxyethylene ether;
[0045] C, then add 5-15 parts of methacrylic acid, 1-3 parts of sodium methacryl sulfonate, 0.1-0.4 parts of hydroquinone and 60-120 parts of deionized water and continue ultrasonic treatment for 15-25 minutes to obtain a mixed monomer solution;
[0046] D. Add 60-90 parts of deionized water into the reactor, add...
Embodiment 3
[0058] A preparation process of a high-performance polycarboxylate water reducer applied to concrete, comprising the following steps:
[0059] A. Dissolving the surfactant in ethanol, adding a hydrophilic fullerene derivative, performing mechanical stirring, ball milling, ultrasonic reaction treatment in sequence, and spray drying to obtain a surface-modified fullerene;
[0060] B. Take 100 parts of allyl polyoxyethylene ether in parts by mass, mix 40-60 parts of surface-modified fullerene and 3-8 parts of concentrated sulfuric acid, stir and heat up to 60-75°C, keep warm and ultrasonically treat for 30 -45min, obtain fullerene modified allyl polyoxyethylene ether;
[0061] C, then add 5-15 parts of methacrylic acid, 1-3 parts of sodium methacryl sulfonate, 0.1-0.4 parts of hydroquinone and 60-120 parts of deionized water and continue ultrasonic treatment for 15-25 minutes to obtain a mixed monomer solution;
[0062] D. Add 60-90 parts of deionized water into the reactor, ad...
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