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A kind of alkyd resin and preparation method thereof

A technology of alkyd resin and basic acid, which is applied in coatings, polyester coatings, etc., can solve the problems of insufficient solid content of coatings, environmental damage, and low gloss, so as to reduce environmental pollution, eliminate treatment costs, and reduce solid content in construction. high effect

Active Publication Date: 2021-12-07
东胜化学(上海)有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] DINCH (diisononyl cyclohexane 1,2-dicarboxylate) is a common chemical raw material. During the production of DINCH, a large number of by-products will be produced, which will cause damage to the environment. The general treatment method is to increase the subsequent Therefore, various treatment costs will be incurred; at the same time, the coatings prepared by existing resins have one or more defects such as insufficient solid content, low gloss, and poor distinctness of image.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0047] This example provides a alkyd resin comprising a DinCH by-product 180 kg; propanediol 38kg; trimethylolpropane 240 kg; phthalic anhydride 260kg; ispanyonic acid 160 kg; 1 kg of hypophosphite; phosphite 1kg; xylene 120kg.

[0048] The method of preparing the alkyd resin of the present embodiment is:

[0049] S1, DINCH by-products, propanediol, trimethylolpropane, phthalic anhydride, 160 kg, phosphite triphenyl ester, input reactor, nitrogen gas, flow rate 5m 3 / h, start stirring, heating to the water, heat for 1 h at the effluent temperature, then raised to 230 ° C for 5 h, and 20 kg of xylene is added to 230 ° C to the solid acid value of less than 15 mgKOH / g, the viscosity 25 ° C: Z4 ~ Z6;

[0050] S2, cooling to 120 ° C to 170 ° C, adding residual xylene, stir well.

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PUM

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Abstract

The invention discloses an alkyd resin, which comprises the following components in terms of mass percentage: 5-25% of cyclohexane 1,2-dicarboxylic acid diisononyl by-product; 20-30% of polyhydric alcohol; 20-35% polybasic acid; 5-20% monobasic acid; 0.01-1% color reducer; 0.01-5% reflux solvent; 10-25% dilution solvent; cyclohexane 1,2-dicarboxylic acid The diisononyl ester by-product comprises 5-15% nonanol by mass percentage, 5-15% nonanoic acid, 25-35% nonyl nonanoate, 25-35% hydroxymethyl dinonyl ester, 5-15% aldol condensate from nonanal, 5-15% high carbon ester from nonanoic acid. The alkyd resin of the invention can effectively utilize the by-products of DINCH, avoid subsequent by-product treatment costs, reduce environmental pollution, and can prepare coatings with high solid content in construction, high gloss and high vividness of image.

Description

Technical field [0001] The present invention relates to the field of polymer synthesis, particularly alcoholic resin and a preparation method thereof. Background technique [0002] DINCH (cyclohexane 1,2-dimethylene) is a common chemical raw material that will accompany a large number of by-products when producing DINCH, which will damage the environment, and the general treatment method is to increase subsequent. The processing process treats its by-products, thereby producing various processing costs; at the same time, the coating prepared by the existing resin is insufficient, the gloss is not high, and the premium premium is poor. [0003] There is an urgent need for a by-product that can effectively utilize DINCH, eliminating the renewal of by-product treatment cost, reducing environmental pollution, can prepare a coating of coating, high gloss, high gloss, high gloss, and preparation Method to solve the above technical problems. Inventive content [0004] In order to solve...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08G63/50C09D167/00
CPCC08G63/50C09D167/00
Inventor 张华徐从青谢宠阮晓亮
Owner 东胜化学(上海)有限公司
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