Method for identifying gum medicinal materials based on chemical oscillation fingerprint technology
A technology of glue-like medicinal materials and fingerprints, which is applied in the direction of scientific instruments, analytical materials, and material analysis through electromagnetic means. It can solve the problems of few analytical applications, high detection costs, and unsuitability for wide application by enterprises, and achieve simple testing steps. , low detection cost, rich feature parameters
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Embodiment 1
[0039] Example 1 Chemical Oscillation Fingerprint Test and Qualitative Discriminant Analysis of Colloidal Medicinal Materials from Different Animal Sources
[0040] At a temperature of 55°C, 0.4 g of donkey-hide gelatin sample crushed through a 40-mesh sieve was added to the three-neck flask, and then 40 mL of 0.2 mol / L dilute sulfuric acid solution was added to carry out the acid hydrolysis reaction for 60 minutes, and the reaction ended.
[0041] After the acid hydrolysis step, at a temperature of 35°C and a rotational speed of 800r / min, add an oscillation system solution to the hydrolyzate: 0.75 mol / L dilute sulfuric acid solution, 0.25 mol / L copper sulfate catalyst solution, Acetone dissipation, stirring for 8 minutes, adding 0.1mol / L potassium bromate oxidant solution, the volumes of the added dilute sulfuric acid solution, catalyst, dissipation and oxidant were 16mL, 12mL, 8mL, 4mL respectively. Using the platinum wire electrode as the working electrode and the saturated c...
Embodiment 2
[0046] Example 2 Chemical Oscillation Fingerprint Test and Qualitative Discriminant Analysis of Colloidal Medicinal Materials in Different Regions
[0047] At a temperature of 60°C, 0.2 g of a donkey-hide gelatin sample from Shandong area that had been crushed through a 60-mesh sieve was added to the three-necked bottle, and then 40 mL of 0.4 mol / L dilute sulfuric acid solution was added to carry out the acid hydrolysis reaction for 100 minutes, and the reaction ended.
[0048] After the acid hydrolysis step, at a temperature of 40° C. and a rotational speed of 1000 r / min, add an oscillation system solution to the hydrolyzate: 1.0 mol / L dilute sulfuric acid solution, 0.50 mol / L copper sulfate catalyst solution, For malonic acid dissipation, after stirring for 10 minutes, add 0.2mol / L potassium bromate oxidant solution, and the volumes of the added dilute sulfuric acid solution, catalyst, dissipation and oxidant are 8mL, 6mL, 4mL, and 2mL, respectively. Using the platinum wire ...
Embodiment 3
[0053] Example 3 Chemical Oscillation Fingerprint Test and Qualitative Discriminant Analysis of Colloidal Medicinal Materials in Different Years
[0054] At a temperature of 55°C, 0.4 g of donkey-hide gelatin sample in 2007 crushed through a 40-mesh sieve was added to the three-necked bottle, and then 40 mL of 0.2 mol / L dilute sulfuric acid solution was added to carry out the acid hydrolysis reaction for 60 minutes, and the reaction ended.
[0055] After the acid hydrolysis step, at a temperature of 35°C and a rotational speed of 800r / min, add an oscillation system solution to the hydrolyzate: 0.75 mol / L dilute sulfuric acid solution, 0.25 mol / L copper sulfate catalyst solution, For acetone dissipation, add 0.1 mol / L potassium bromate oxidant solution after stirring for 8 minutes. The volumes of the added dilute sulfuric acid solution, catalyst, dissipation and oxidant are 16mL, 12mL, 8mL, and 4mL, respectively. Using the platinum wire electrode as the working electrode and th...
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