Environment-friendly low-cost titanium-containing metal etching liquid composition and use method thereof

A technology of etching solution and composition, which is applied in the field of environment-friendly and low-cost titanium-containing metal etching solution composition, which can solve the problems of low metal ion loading capacity, increased etching process cost, and inability to guarantee etching precision, etc., and achieve good etching morphology , slow down the etching rate, the effect of etching rate balance

Pending Publication Date: 2021-06-08
四川和晟达电子科技有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, most of the commonly used etching solutions contain fluorine ions. Although the etching rate is improved, the etching accuracy cannot be guaranteed, and the loading capacity of the etching solution for metal ions is not high. The etching process produces a large amount of etching solution, which increases the cost of the etching process. , can not meet the requirements of environmental friendliness

Method used

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  • Environment-friendly low-cost titanium-containing metal etching liquid composition and use method thereof
  • Environment-friendly low-cost titanium-containing metal etching liquid composition and use method thereof
  • Environment-friendly low-cost titanium-containing metal etching liquid composition and use method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0082] An environment-friendly and low-cost titanium-containing metal etchant composition, including a main agent and an auxiliary agent.

[0083] The components of the main agent are based on the mass percentage of the main agent, including: 7.25% hydrogen peroxide, 4.4% nitric acid, 9.58% tetramethylammonium hydroxide, 0.2% p-hydroxybenzenesulfonic acid, and 0.02% 5-aminotetrazole , supplemented with deionized water.

[0084] The components of the adjuvant include: 9.45% nitric acid, 23.15% tetramethylammonium hydroxide, 0.3% p-hydroxybenzenesulfonic acid, 0.04% 5-aminotetrazole, and deionized water to supplement the balance by mass percentage of the adjuvant .

[0085] A method for using an environment-friendly and low-cost titanium-containing metal etching solution composition, the steps are as follows:

[0086] Soak the titanium-containing metal in the main agent of the etching solution. The titanium-containing metal includes copper film and molybdenum-titanium-nickel f...

Embodiment 2

[0088] An environment-friendly and low-cost titanium-containing metal etchant composition, including a main agent and an auxiliary agent.

[0089] The components of the main agent are based on the mass percentage of the main agent, including: hydrogen peroxide 7.25%, nitric acid 2.86%, tetramethylammonium hydroxide 7.28%, p-hydroxybenzenesulfonic acid 0.25%, 5-aminotetrazole 0.02% , supplemented with deionized water.

[0090] The components of the auxiliary agent include: 7.36% of nitric acid, 17.94% of tetramethylammonium hydroxide, 0.5% of p-hydroxybenzenesulfonic acid, 0.04% of 5-aminotetrazole, and deionized water to supplement the balance .

[0091] A method for using an environment-friendly and low-cost titanium-containing metal etching solution composition, the steps are as follows:

[0092] Soak the titanium-containing metal in the main agent of the etching solution. The titanium-containing metal includes copper film and molybdenum-titanium-nickel film. The thickness...

Embodiment 3

[0094] An environment-friendly and low-cost titanium-containing metal etchant composition, including a main agent and an auxiliary agent.

[0095] The components of the main agent are based on the mass percentage of the main agent, including: 7.25% hydrogen peroxide, 4.4% nitric acid, 11.2% dimethylethanolamine, 0.2% p-hydroxybenzenesulfonic acid, 0.02% 5-aminotetrazole, Ionized water replenishes the balance.

[0096] The components of the auxiliary agent include: 9.45% of nitric acid, 29.8% of dimethylethanolamine, 0.3% of p-hydroxybenzenesulfonic acid, 0.04% of 5-aminotetrazole, and deionized water to supplement the balance.

[0097] A method for using an environment-friendly and low-cost titanium-containing metal etching solution composition, the steps are as follows:

[0098] Soak the titanium-containing metal in the main agent of the etching solution. The titanium-containing metal includes copper film and molybdenum-titanium-nickel film. The thickness of the copper film ...

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Abstract

The invention discloses an environment-friendly low-cost titanium-containing metal etching liquid composition and a using method thereof. The etching liquid comprises a main agent and an auxiliary agent, wherein the main agent comprises components of, in percentage by mass, 1%-20% of hydrogen peroxide, 1%-10% of strong oxidizing acid, 1%-10% of alkali compounds, 0.01%-5% of hydrogen peroxide stabilizer and 0.01%-2% of aminoazole compounds, and deionized water is used for supplementing the balance; and the auxiliary agent is prepared from the following components of, in percentage by mass, 1%-20% of strong oxidizing acid, 1%-20% of alkali compound, and 0.01%-2% of aminoazole compound, and deionized water is used for supplementing the balance. The etching liquid composition prepared by the method is free of fluorine and phosphorus, environment-friendly, low in waste liquid treatment cost and high in copper ion loading capacity, and metal obtained through etching has good etching morphology and can meet the production requirements of ultra-high-precision and small and medium-sized display products.

Description

technical field [0001] The invention relates to the field of metal surface chemical treatment, in particular to an environment-friendly and low-cost titanium-containing metal etching solution composition and a use method thereof. Background technique [0002] Etching is a technology that removes materials by chemical reaction or physical impact. It is mainly used to manufacture copper plates, zinc plates and other printing concave-convex plates, reduce weight instrument panels, and process electronic thin parts in aviation, machinery, and chemical industries. / Semiconductor and other precision etching products. [0003] Etching solution is a liquid that achieves the purpose of etching by eroding materials. At present, most of the commonly used etching solutions contain fluorine ions. Although the etching rate is improved, the etching accuracy cannot be guaranteed, and the loading capacity of the etching solution for metal ions is not high. The etching process produces a lar...

Claims

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Application Information

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IPC IPC(8): C23F1/18C23F1/44
CPCC23F1/18C23F1/44
Inventor 徐帅张红伟李闯胡天齐钱铁民
Owner 四川和晟达电子科技有限公司
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