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Microwave dielectric ceramic, preparation method thereof and microwave device

A technology for microwave dielectric ceramics and conditions, applied in the field of ceramic materials, can solve the problems of poor uniformity, consistency and dielectric properties, low qualification rate of microwave dielectric ceramics, complex processing procedures, etc., and achieve good uniformity and consistency. , excellent dielectric properties, simple processing effect

Active Publication Date: 2021-06-18
BEIJING ZHONG KE SAN HUAN HI TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The existing microwave dielectric ceramics have a large deformation before and after sintering, and the internal stress generated makes the proportion of cracks inside the microwave dielectric ceramic products higher, which leads to a low pass rate of microwave dielectric ceramic products, and the uniformity, consistency and dielectric properties Both are poor. When using such microwave dielectric ceramics to process and prepare microwave devices, the processing procedures are complicated and the processing costs are high.

Method used

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  • Microwave dielectric ceramic, preparation method thereof and microwave device
  • Microwave dielectric ceramic, preparation method thereof and microwave device
  • Microwave dielectric ceramic, preparation method thereof and microwave device

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0060] The microwave dielectric ceramic of the present disclosure is prepared by the following method:

[0061] (1) Place the microwave dielectric ceramic granules in an injection molding machine for injection molding to obtain a microwave dielectric ceramic green body, wherein the injection molding conditions include: the mold temperature is 140°C, and the pressure holding speed is 30mm / s , the injection temperature is 180°C, the injection pressure is 120MPa, and the injection speed is 50mm / s;

[0062] Wherein, the microwave dielectric ceramic granules used in this embodiment are composed of microwave dielectric ceramic powder and a binder composition. Based on the microwave dielectric ceramic granules, the amount of microwave dielectric ceramic powder is 80% by weight. The amount of the binder composition is 20% by weight, the average particle size of the microwave dielectric ceramic particles is 3.3 μm, and the melt index under the condition of 190°C / 2.16kg is 40 cm 3 / 10m...

Embodiment 2

[0071] Microwave dielectric ceramics were prepared according to the method in Example 1, except that the melt index of the microwave dielectric ceramic pellets used in this example was 15 cm under the condition of 190 °C / 2.16 kg 3 / 10min; wherein, in the microwave dielectric ceramic granules, the particle size D50 of the microwave dielectric ceramic powder is 3.4 μm, the particle size D90 is 7.2 μm, and the particle size D10 is 1.2 μm; The melt index is 180 g / 10min, the weight average molecular weight is 20000 g / mol, the crystallinity is 65%, the tensile strength is 40 MPa, and the elongation at break is 3%;

[0072] The microstructure of the microwave dielectric ceramics prepared in this example was observed by scanning electron microscopy, and the results showed that the microwave dielectric ceramics contained MgTiO 3 Grains and CaTiO 3 grains, the CaTiO 3 grain embedded distribution in the MgTiO 3 between the grains, where the CaTiO 3 CaTiO with a grain size D50 of 2.5 ...

Embodiment 3

[0075] Prepare microwave dielectric ceramics according to the method of Example 1, the difference is: the melting index of the microwave dielectric ceramic pellets used in this example is 25cm under the condition of 190°C / 2.16kg 3 / 10min; wherein, in the microwave dielectric ceramic granules, the particle size D50 of the microwave dielectric ceramic powder is 3.5 μm, the particle size D90 is 7.0 μm, and the particle size D10 is 1.0 μm; The melt index is 220 g / 10min, the weight average molecular weight is 70000 g / mol, the crystallinity is 70%, the tensile strength is 60 MPa, and the elongation at break is 8%;

[0076] The microstructure of the microwave dielectric ceramics prepared in this example was observed by scanning electron microscopy, and the results showed that the microwave dielectric ceramics contained MgTiO 3 Grains and CaTiO 3 grains, the CaTiO 3 grain embedded distribution in the MgTiO 3 between the grains, where the CaTiO 3 CaTiO with a grain size D50 of 3.0 ...

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Abstract

The invention relates to a microwave dielectric ceramic and a preparation method thereof and a microwave device. The microwave dielectric ceramic contains MgTiO3 crystal grains and CaTiO3 crystal grains; the CaTiO3 crystal grains are distributed among the MgTiO3 crystal grains in an embedded manner, the particle size D50 of the CaTiO3 crystal grains is 1.5-3.5 microns, the number of the CaTiO3 crystal grains with the particle size of 1-7 microns accounts for not less than 99% of the number of all the CaTiO3 crystal grains, and based on any cross-sectional area of the microwave dielectric ceramic, the proportion of the cross-sectional area of the CaTiO3 crystal grains is 3.5-5%. The microwave dielectric ceramic provided by the invention is formed by closely arranging the MgTiO3 crystal grains and the CaTiO3 crystal grains which are uniformly distributed among the MgTiO3 crystal grains in an embedded manner, and the sizes of the CaTiO3 crystal grains are uniform, so that the microwave dielectric ceramic is relatively good in uniformity and consistency, relatively high in density and strength and excellent in dielectric property, and when the microwave dielectric ceramic is used for processing and preparing a microwave device, the processing procedure is simple, and the processing cost is low.

Description

technical field [0001] The present disclosure relates to the technical field of ceramic materials, in particular, to a microwave dielectric ceramic, a preparation method thereof, and a microwave device prepared by using the microwave dielectric ceramic. Background technique [0002] Microwave dielectric ceramics refer to specific functional materials used in microwave frequency band (mainly UHF, SHF frequency band, 300MHz ~ 300GHz) circuits as dielectric materials and complete one or more functions. They are used in modern communications for resonators, In microwave devices such as filters, dielectric substrates, dielectric antennas, and dielectric waveguide circuits. Compared with metal cavity microwave devices with air or local dielectric materials as the medium, microwave devices prepared by microwave dielectric ceramics have excellent characteristics such as high dielectric constant, low loss, and low vibration frequency temperature coefficient, which promotes microwave ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B35/465C04B35/622C04B35/638C04B35/64
CPCC04B35/465C04B35/622C04B35/638C04B35/64C04B2235/6562C04B2235/6567C04B2235/77C04B2235/786C04B2235/96
Inventor 陈巍强王云王迎馨郑昭亮汪茂林李晓东徐国强王聪聪蔡道炎敖学如秦国超王湛饶晓雷胡伯平
Owner BEIJING ZHONG KE SAN HUAN HI TECH
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