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Anti-dusting wave-transparent aerogel, and preparation method and application thereof

An airgel and wave-transmitting technology, applied in gel preparation, chemical instruments and methods, colloid chemistry, etc., can solve the problems of cumbersome operation, reduced wave-transmitting performance, and not suitable for mass production, etc., and achieve the effect of simple operation

Active Publication Date: 2021-06-22
AEROSPACE INST OF ADVANCED MATERIALS & PROCESSING TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] However, for wave-transparent airgel materials, the above methods have defects: ①Using needle and thread to penetrate and sew the middle of the airgel will cause pinholes on the surface of the airgel, which will affect its thermal insulation performance; and manual sewing is required, The operation is cumbersome and not suitable for mass production; ②The multi-component coating used in the prior art is applied to the surface of the wave-transparent aerogel, which will reduce its wave-transmission performance and fail to meet the use requirements

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0026] In a first aspect, the present invention provides a method for preparing an anti-powder drop-off wave-transmitting aerogel, the method comprising the following steps:

[0027] (1) The wave-transparent fiber preform is impregnated with the sol, and then undergoes an aging step, a solvent replacement step, a supercritical drying step, and a hydrophobizing treatment step in order to obtain a wave-transparent aerogel;

[0028] (2) The surface of the wave-transparent aerogel obtained in step (1) is coated with three anti-adhesives to prepare an anti-powder drop-off wave-transparent aerogel (an anti-powder drop-off wave-transparent airgel material).

[0029] According to some preferred embodiments, in step (2), the conformal coating is DC3-1953 conformal coating; in the present invention, DC3-1953 conformal coating is also referred to as DC3-1953 conformal coating.

[0030] As we all know, solvent-free conformal coating DC3-1953 is generally coated on circuit boards or semico...

Embodiment 1

[0044] A preparation method of anti-powder drop-off wave-permeable airgel, the steps are as follows:

[0045] ①Weigh 20wt% alkaline silica sol, add 1mol / L hydrochloric acid and 4mol / L ammonium fluoride in sequence, and stir evenly to obtain silica sol, wherein, alkaline silica sol:hydrochloric acid:ammonium fluoride=100:3: 3 (mass ratio).

[0046] ②Put the wave-transparent quartz fiber preform into the sealed mold, and inject the silica sol obtained in step ① into the mold through vacuum injection and pressure injection, so that the quartz fiber preform is fully impregnated with the silica sol to obtain an impregnated body.

[0047] ③ Place the impregnated body obtained in step ② to age at room temperature for 24 hours, and then age at 70°C for 48 hours to obtain a wet gel.

[0048] ④ Remove the wet gel obtained in step ③ from the mold, and immediately put it into absolute ethanol for replacement. After 96 hours of replacement, replace with new absolute ethanol, continue the...

Embodiment 2

[0054] A preparation method of anti-powder drop-off wave-permeable airgel, the steps are as follows:

[0055] ①Weigh 20wt% alkaline silica sol, add 1mol / L hydrochloric acid and 4mol / L ammonium fluoride in sequence, and stir evenly to obtain silica sol, wherein, alkaline silica sol:hydrochloric acid:ammonium fluoride=100:3: 3 (mass ratio).

[0056] ②Put the wave-transparent quartz fiber preform into the sealed mold, and inject the silica sol obtained in step ① into the mold through vacuum injection and pressure injection, so that the quartz fiber preform is fully impregnated with the silica sol to obtain an impregnated body.

[0057] ③ The impregnated body obtained in step ② was left to age at room temperature for 48 hours, and then aged at 70°C for 24 hours to obtain a wet gel.

[0058] ④ Remove the wet gel obtained in step ③ from the mold, and immediately put it into absolute ethanol for replacement. After 144 hours of replacement, replace with new absolute ethanol, continu...

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Abstract

The invention relates to anti-dusting wave-transparent aerogel, and a preparation method and application thereof. The preparation method comprises the following steps: (1) dipping a wave-transparent fiber preform into sol, and then sequentially carrying out an aging step, a solvent replacement step, a supercritical drying step and a hydrophobization treatment step to obtain wave-transparent aerogel; and (2) coating the surface of the wave-transparent aerogel obtained in the step (1) with three-proofing glue to prepare the anti-dusting wave-transparent aerogel. According to the method disclosed by the invention, the surface of the wave-transparent aerogel is coated with the DC3-1953 three-proofing glue, so that the anti-dusting wave-transparent aerogel can be obtained; the three-proofing glue adopted by the invention is a single-component environment-friendly wave-transparent material, does not need to be prepared and dispersed, is simple to operate, can be cured at room temperature for a short time, does not cause pollution to the environment, and does not influence the wave-transparent performance of the wave-transparent aerogel.

Description

technical field [0001] The invention belongs to the technical field of thermal insulation materials, and in particular relates to a powder-drop-proof wave-transmitting aerogel and a preparation method and application thereof. Background technique [0002] Airgel is a porous material with a nanostructure. Its porosity can reach up to 99%, and the size of the cavity and skeleton is generally between 1 and 100nm. It has the characteristics of low thermal conductivity, low dielectric, and low loss. In order to To enhance its mechanical properties, fibers are usually used as reinforcements to prepare fiber-reinforced airgel materials. In some parts that have high requirements for wave transmission and heat insulation, a wave-transparent and heat-insulating integrated material is needed, commonly known as wave-transparent aerogel, and the fibers introduced into it are wave-transparent quartz fibers. [0003] The introduction of fibers effectively improves the mechanical propertie...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J13/00C01B33/158C09D5/00
CPCB01J13/0052C01B33/1585C09D5/00C01P2006/32
Inventor 孙景景张丽娟郭建业张鸶鹭李文静杨洁颖张昊
Owner AEROSPACE INST OF ADVANCED MATERIALS & PROCESSING TECH