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Portable photothermal seawater desalination hollow fiber membrane, preparation method, device and application

A fiber membrane and portable technology, applied in the field of portable photothermal seawater desalination hollow fiber membrane and its preparation, can solve the problems of unavoidable heat loss, limited wide use, low photothermal efficiency, etc., and achieve uniform black appearance, excellent mechanical strength, The effect of high specific surface area

Active Publication Date: 2022-06-21
ZHEJIANG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the above photothermal materials and devices all use two-dimensional photothermal conversion surfaces to perform photothermal conversion to achieve water evaporation during use, which leads to low photothermal efficiency, and at the same time, due to factors such as large volume and heavy weight, it greatly limits their use. widely used
Patent CN111573780A discloses a hollow fiber photothermal membrane equipment and its preparation method and application, as well as water treatment equipment, mainly by inserting the two ends of the hollow fiber membrane into the support and passing through the surface of the support to realize However, the photothermal membrane equipment does not maximize the specific surface area of ​​the hollow fiber membrane, and both ends are inserted into the water body, so heat loss is inevitable

Method used

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  • Portable photothermal seawater desalination hollow fiber membrane, preparation method, device and application
  • Portable photothermal seawater desalination hollow fiber membrane, preparation method, device and application
  • Portable photothermal seawater desalination hollow fiber membrane, preparation method, device and application

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0064] First of all, Example 1 provides a preparation method of a photothermal seawater desalination hollow fiber membrane: an ultra-thin film with an average pore size of 0.9 μm, a porosity of 60%, a membrane thickness of 200 μm, and an inner / outer diameter of 0.5 mm / 1.0 mm is used. The hydrophilic polysulfone hollow fiber gradient membrane was used as a polymer-based membrane, and the 0.5 wt% carbon nanotube dispersion was fixed on the outer surface of the hollow fiber membrane by surface adsorption by vacuum filtration technology for 1 h, and the outer surface had photothermal function. The hollow fiber membrane with black appearance of the layer can be obtained after cleaning and drying.

[0065] The polymer hollow fiber membrane modified by carbon nanotubes has excellent self-siphoning performance, and the appearance is uniform black. Secondly, this embodiment 1 also provides a portable photothermal seawater desalination device. The operation method is as follows: One end...

Embodiment 2

[0067] First, Example 2 provides a preparation method of a photothermal seawater desalination hollow fiber membrane: Step 1: adopt an average pore diameter of 2 μm, a porosity of 80%, a membrane thickness of 50 μm, and an inner / outer diameter of 0.1 mm / 0.25 mm, respectively. The hydrophobic polyethylene hollow fiber membrane is a polymer-based membrane, and dopamine and polyethyleneimine are dispersed and dissolved in a buffer solution with a pH of 8.5 to configure a homogeneous solution, wherein the ratio of dopamine:polyethyleneimine is 1:1; The surface coating technology is treated for 12h so that the homogeneous solution is fixed on the inner surface of the hollow fiber membrane, cleaned and dried for later use;

[0068] Step 2: The polymer base membrane treated in Step 1 is placed in a 2wt% polypyrrole solution for outer surface vapor deposition modification for 3 hours to obtain a black-looking hollow fiber membrane with a photothermal functional layer on the outer surfac...

Embodiment 3

[0072] First of all, Example 3 provides a preparation method of a photothermal seawater desalination hollow fiber membrane: an ultra-thin film with an average pore size of 1.0 μm, a porosity of 40%, a membrane thickness of 200 μm, and an inner / outer diameter of 2.0 mm / 3.5 mm is used. The hydrophilic polyethersulfone hollow fiber membrane is a polymer-based membrane. The superhydrophilic polyethersulfone hollow fiber membrane was placed in a 20 wt% polyaniline solution for cross-linking fixation and modification on the outer surface for 6 h. The black appearance hollow fiber membrane of the thermal functional layer can be washed and dried to obtain the hollow fiber membrane of photothermal seawater desalination. The polyaniline-modified polymer hollow fiber membrane prepared in Example 3 has excellent self-siphoning performance, and the appearance is uniform black.

[0073]Secondly, this embodiment 3 also provides a portable photothermal seawater desalination device, and the op...

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Abstract

The invention discloses a portable photothermal seawater desalination hollow fiber membrane, a preparation method, a device and an application. The preparation method includes step 1): dispersing and dissolving hydrophilic polymers and nanoparticles in a buffer solution with a pH of 8.5 It is configured as a homogeneous solution in which the ratio of hydrophilic polymer:nanoparticles is 1-20:0-20, and the hollow fiber membrane is flushed with the homogeneous solution for 1-24 hours, and then cleaned and dried for later use to obtain super-hydrophilic hollow membranes on the inner surface. Fiber membrane; step 2): placing the super-hydrophilic hollow fiber membrane on the inner surface obtained in step 1) in an atmosphere of 0.1 to 20 wt% photothermal modification material solution through surface adsorption, surface vapor deposition, surface crosslinking, Suction filtration and / or coating modification are treated for 1-24 hours to prepare a hollow fiber membrane with super-hydrophilic inner surface and photothermal function on the outer surface. The present invention selects a three-dimensional hollow fiber membrane as a base material, and the photothermal seawater desalination hollow fiber membrane obtained through inner / outer surface modification can realize photothermal seawater desalination.

Description

technical field [0001] The invention relates to the technical field of photothermal conversion, in particular to a portable photothermal seawater desalination hollow fiber membrane and a preparation method, device and application thereof. Background technique [0002] Freshwater is one of the basic substances for the survival and development of human society, but at present, only existing in rivers, lakes and underground freshwater that can be directly used by human beings is less than 0.36%. my country has a long coastline, and some islands, coastal saline-alkali areas and inland brackish water areas are all areas lacking fresh water. People have suffered from various diseases due to long-term drinking of water that does not meet the hygienic standards, which directly affects their health and local economic development. Therefore, desalination of seawater and brackish water has become an effective way to expand freshwater sources. [0003] At present, there are many method...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01D69/08B01D69/02C02F1/04C02F1/14C02F103/08
CPCB01D69/08B01D69/02C02F1/048C02F1/14C02F2103/08Y02A20/212
Inventor 黄小军魏晨杰张曦航
Owner ZHEJIANG UNIV
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