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Deblocking agent for decontamination of high molecular polymer, preparation method and application thereof

A high-molecular polymer and plug-removing agent technology, which can be used in drilling compositions, chemical instruments and methods, earthwork drilling and mining, etc., can solve the problem that blockages are difficult to effectively contact and react, the effective distance of action is short, and the reaction speed is too fast and other problems, to achieve the effect of removing the clogging of polymer pollutants, good stability of the agent, and solving the difficulty of injection

Active Publication Date: 2022-07-05
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Through the sampling and analysis of the vomitus in the field operation of plugged wells, it is found that the polymer formation plugs are black viscoelastic jelly, mainly composed of water, oil, polymers and their cross-linked gels, mud and sand, and inorganic impurities. Substances are wrapped together, and it is difficult to effectively separate the components without using chemical methods
[0003] At present, there are generally the following technical problems in the technology of polymer blockage removal: first, the complexity of polymer blockages is ignored, and only focus on the blockage removal of polymers and their cross-linked gel blockages, ignoring oil pollution and various Inorganic plugging is also an important cause of formation plugging; second, the differences in physical and chemical properties of various plugging materials are not considered, and it is difficult to effectively contact and react with corresponding plugging materials; 2 to 3 meters, ignoring the blockage in the deep formation, and failing to achieve the purpose of deep blockage removal
Fourth, most of the plug-removing agents used are strongly oxidizing, and the oxidizing solution is very unstable, and it is not easy to store for a long time, and it cannot be stored in metal containers, and direct sunlight is strictly prohibited.
In the field application process, there are great safety hazards, and there are also problems such as too fast response speed, short effective action distance, and difficulty in achieving deep plugging removal.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] The present embodiment provides a blocking removal agent for decontamination of high molecular polymers, including a first blocking agent and a second blocking agent with a volume ratio of 1:7; wherein,

[0042] The first plug removing agent comprises paraffin oil, tallow propylene diamine, ammonium chloride and calcium oxide with a mass ratio of 85:1:3:20;

[0043] The second plug removing agent includes 10wt% of the main agent and 90wt% of water;

[0044] The main agent comprises water, sodium carbonate, biuret, sodium nitrite and sodium α-alkenyl sulfonate in a mass ratio of 40:4:4:3:2.

[0045] The present embodiment also provides the above-mentioned preparation method of the blocking removing agent for removing the pollution of the high molecular polymer, which comprises the following steps:

[0046] The paraffin oil was added to the reaction kettle, the reaction kettle was started, and the temperature was controlled at 35 ° C; tallow propylene diamine and ammoniu...

Embodiment 2

[0049] The present embodiment provides a method for removing the contamination of high molecular polymer by a deblocking agent, which comprises the following steps:

[0050] 1) Calculate the amount of plug-relieving agent:

[0051] According to the depth of Well Jin 2-6-A247 in Liaohe Oilfield, the depth is 1454m, the injection pressure is 10.7MPa, and the daily injection pressure is 30m. 3 , the porosity of the oil layer is 24%, the thickness H of the treatment section of the injection well is 4.9m, and the treatment radius R is 3m:

[0052] Blocking agent dosage Q=3.14R 2 HФ=3.14×3 2 ×4.9×24%=34(m 3 );

[0053] 2) The volume ratio of the first blocking agent and the second blocking agent in the blocking agent is 1:7, so the amount of the first blocking agent is 4.25m 3 , the dosage of the second plugging agent is 29.75m 3 , the main agent in the second plugging agent is 3 tons;

[0054] Wherein, the preparation steps of the first plug-relieving agent are as follows: ...

Embodiment 3

[0065] The present embodiment provides a blocking removal agent for decontamination of high molecular polymers, including a first blocking agent and a second blocking agent with a volume ratio of 1:7; wherein,

[0066] The first plug removing agent comprises paraffin oil, tallow propylene diamine, ammonium chloride and calcium oxide with a mass ratio of 90:2:3:30;

[0067] The second plug removing agent includes 12 wt % of the main agent and 88 wt % of water;

[0068] The main agent includes water, sodium carbonate, biuret, sodium nitrite and sodium α-alkenyl sulfonate in a mass ratio of 45:5:5:3:3.

[0069] The present embodiment also provides the above-mentioned preparation method of the blocking removing agent for removing the pollution of the high molecular polymer, which comprises the following steps:

[0070] The paraffin oil was added to the reaction kettle, the reaction kettle was started, and the temperature was controlled at 40 ° C; tallow propylene diamine and ammo...

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PUM

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Abstract

The invention discloses a blocking removing agent for removing the pollution of high molecular polymer and its preparation method and application. The blocking remover for decontamination of high molecular polymers includes a first blocking agent and a second blocking agent; wherein, the first blocking agent includes paraffin oil, tallow propylene diamine, ammonium chloride and calcium oxide; the second plugging agent includes a main agent and a first solvent; the main agent includes a second solvent, sodium carbonate, biuret, sodium nitrite and sodium α-alkenyl sulfonate. The present invention also provides a preparation method and application of a blocking removing agent for removing the pollution of the high molecular polymer. The blocking removing agent for removing the pollution of high molecular polymer provided by the invention does not use strong oxidizing raw materials, can effectively remove the blocking of the polymer, and has good blocking removing performance; the chemical stability is good, and the deep blocking removal can be carried out. Treatment; can effectively solve the problem of difficult implantation in the existing process.

Description

technical field [0001] The invention relates to the technical field of oil production in oil fields. More specifically, it relates to a blocking removing agent for removing the pollution of high molecular polymer and its preparation method and application. Background technique [0002] Polymers have played an important role in oilfield development and are mainly used in polymer flooding, chemical flooding, and high-dose deep profile flooding. Because the adsorption, retention and mechanical trapping of polymers in the formation porous media can easily lead to formation plugging, the formation liquid absorption generally decreases after plugging. Sampling and analysis of the revomited material from the plugged well site operation found that the polymer formation blockage is a black viscoelastic jelly, which is mainly composed of water, oil, polymer and its cross-linked gel, mud sand and inorganic impurities. Substances are intertwined together, and the components are diffic...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09K8/524E21B37/06
CPCC09K8/524E21B37/06
Inventor 孙倩茹柳荣伟王浩张俊戴倩倩王磊高峰李瑞马昌明刘强王尧陈小凯
Owner PETROCHINA CO LTD
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