Preparation method of catalyst for formaldehyde degradation
A formaldehyde degradation and catalyst technology, applied in chemical instruments and methods, physical/chemical process catalysts, separation methods, etc., can solve the problems of secondary pollution of waste cathode materials, high cost of formaldehyde degradation catalysts, complex recovery procedures, etc. The effect of easy, simple method and high formaldehyde degradation efficiency
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Embodiment 1
[0031] A method for preparing a catalyst degradation of formaldehyde, formaldehyde for the preparation of a catalyst degradation comprising the steps of:
[0032] (A), an argon atmosphere in a glove box, a small hydraulic means removal of waste carbon batteries, the positive electrode material obtained was collected, the pulverization;
[0033] (B), the step (a) the powder obtained was weighed, compared with the powder mass of 2000ml / g ratio of deionized water was stirred 5 times washing powder, each stirring speed of 300 revolutions / minute, time 10 minutes, then filtered and the filtrate to a pH of 8, a black powder was collected by filtration after washing;
[0034] (Iii), the step (b) the obtained powder placed in an oven at 60 ℃, dried for 6 hours after collection, as compared to the collected solid was mixed with 1mol / L sulfuric acid solution, wherein the volume of the sulfuric acid solution with the powder mass is 100ml / g, the mixture was heated for 5 hours at 120 de...
Embodiment 2
[0038] A method for preparing a catalyst degradation of formaldehyde, formaldehyde for the preparation of a catalyst degradation comprising the steps of:
[0039] (A), an argon atmosphere in a glove box, a small hydraulic means removal of waste carbon batteries, the positive electrode material obtained was collected, the pulverization;
[0040] (B), the step (a) the powder obtained was weighed, compared with the powder mass of 500ml / g ratio of deionized water was stirred 10 times washing powder, each stirring speed of 100 revolutions / minute, time was 40 minutes, then filtered until the filtrate was pH 7, a black powder was collected by filtration after washing;
[0041](3), the powder obtained by step (b) is placed in an oven at a 150 ° C, and then collected after 12 hours, and the collected solid is mixed with 3 mol / L sulfuric acid solution, wherein the volume of the sulfuric acid solution is compared with the quality of the powder. In 200 ml / g, the mixture was heated und...
Embodiment 3
[0043] A method for preparation for formaldehyde decomposition catalysts comprising the steps of:
[0044] (1) In the glove box of the argon atmosphere, the waste carbon battery is removed using a small hydraulic device, and the resulting positive material is collected, and the grinding is pulverized;
[0045] (Ii), the powder obtained by the step (1) is weighed, and the powder is stirred with a deionized moisture of 500 ml / g compared to the mass mass, and the stirring speed is 200 rpm, time. For 30 minutes, it is filtered to the filtrate pH 7, and the black powder after cleaning is collected;
[0046] (3), the powder obtained by step (b) is placed in an oven at 60 ° C, and then collected after 12 hours, and the collected solid is mixed with 2.5 mol / L of sulfuric acid solution, wherein the volume of the sulfuric acid solution is from the powder mass phase. The ratio was 50 mL / g, and the mixture was stirred at 80 ° C oil bath for 12 hours, the stirring speed was 200 rpm, and ...
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