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Preparation method of catalyst for formaldehyde degradation

A formaldehyde degradation and catalyst technology, applied in chemical instruments and methods, physical/chemical process catalysts, separation methods, etc., can solve the problems of secondary pollution of waste cathode materials, high cost of formaldehyde degradation catalysts, complex recovery procedures, etc. The effect of easy, simple method and high formaldehyde degradation efficiency

Pending Publication Date: 2021-09-10
CHINA JILIANG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] The present invention aims to solve the problems that the current positive electrode recovery method of waste carbon batteries requires complex recovery procedures, and the waste positive electrode materials have potential secondary pollution and other disadvantages; while commercially available formaldehyde degradation catalysts have high cost, complicated operation, and low degradation efficiency. The invention provides a method for preparing a formaldehyde degradation catalyst by recycling waste carbon batteries

Method used

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  • Preparation method of catalyst for formaldehyde degradation
  • Preparation method of catalyst for formaldehyde degradation
  • Preparation method of catalyst for formaldehyde degradation

Examples

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Effect test

Embodiment 1

[0031] A method for preparing a catalyst degradation of formaldehyde, formaldehyde for the preparation of a catalyst degradation comprising the steps of:

[0032] (A), an argon atmosphere in a glove box, a small hydraulic means removal of waste carbon batteries, the positive electrode material obtained was collected, the pulverization;

[0033] (B), the step (a) the powder obtained was weighed, compared with the powder mass of 2000ml / g ratio of deionized water was stirred 5 times washing powder, each stirring speed of 300 revolutions / minute, time 10 minutes, then filtered and the filtrate to a pH of 8, a black powder was collected by filtration after washing;

[0034] (Iii), the step (b) the obtained powder placed in an oven at 60 ℃, dried for 6 hours after collection, as compared to the collected solid was mixed with 1mol / L sulfuric acid solution, wherein the volume of the sulfuric acid solution with the powder mass is 100ml / g, the mixture was heated for 5 hours at 120 de...

Embodiment 2

[0038] A method for preparing a catalyst degradation of formaldehyde, formaldehyde for the preparation of a catalyst degradation comprising the steps of:

[0039] (A), an argon atmosphere in a glove box, a small hydraulic means removal of waste carbon batteries, the positive electrode material obtained was collected, the pulverization;

[0040] (B), the step (a) the powder obtained was weighed, compared with the powder mass of 500ml / g ratio of deionized water was stirred 10 times washing powder, each stirring speed of 100 revolutions / minute, time was 40 minutes, then filtered until the filtrate was pH 7, a black powder was collected by filtration after washing;

[0041](3), the powder obtained by step (b) is placed in an oven at a 150 ° C, and then collected after 12 hours, and the collected solid is mixed with 3 mol / L sulfuric acid solution, wherein the volume of the sulfuric acid solution is compared with the quality of the powder. In 200 ml / g, the mixture was heated und...

Embodiment 3

[0043] A method for preparation for formaldehyde decomposition catalysts comprising the steps of:

[0044] (1) In the glove box of the argon atmosphere, the waste carbon battery is removed using a small hydraulic device, and the resulting positive material is collected, and the grinding is pulverized;

[0045] (Ii), the powder obtained by the step (1) is weighed, and the powder is stirred with a deionized moisture of 500 ml / g compared to the mass mass, and the stirring speed is 200 rpm, time. For 30 minutes, it is filtered to the filtrate pH 7, and the black powder after cleaning is collected;

[0046] (3), the powder obtained by step (b) is placed in an oven at 60 ° C, and then collected after 12 hours, and the collected solid is mixed with 2.5 mol / L of sulfuric acid solution, wherein the volume of the sulfuric acid solution is from the powder mass phase. The ratio was 50 mL / g, and the mixture was stirred at 80 ° C oil bath for 12 hours, the stirring speed was 200 rpm, and ...

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Abstract

The invention discloses a preparation method of a catalyst for formaldehyde degradation by recycling waste carbon batteries. The method comprises the following steps: (1) removing the waste carbon battery in a glove box in an argon atmosphere, collecting the obtained positive electrode material, and conducting grinding and crushing; (2) weighing the powder, adding deionized water, conducting stirring, conducting cleaning, conducting filtering until the pH value of filtrate is 7-8, and collecting cleaned and filtered black powder; and (3) putting the powder into an oven at the temperature of 60-150 DEG C, conducting drying for 12-24 hours, mixing the collected solid with a sulfuric acid solution, conducting heating and stirring for 5-15 hours under the condition of oil bath at the temperature of 60-120 DEG C at the stirring speed of 200-300 revolutions per minute, then conducting filtering to obtain a solid, washing the solid with deionized water to be neutral, and finally putting the solid into an oven at the temperature of 60 DEG C, and conducting drying for 12 hours, so as to obtain a sample which can be directly used for a formaldehyde degradation catalyst. The method is simple in steps and easy to operate, and the prepared formaldehyde degradation catalyst has high formaldehyde degradation efficiency and good stability.

Description

Technical field [0001] The present invention relates to a process for recycling of waste material carbaldehyde cathode of a battery using a carbon catalyst degradation, belonging to the scope of the preparation of inorganic materials. Background technique [0002] Formaldehyde is volatile organic compounds VOCs (Volatile Organic Compounds) in the main one of the highest of the two toxic chemicals in China priority control list. Formaldehyde has become one of the most important indoor air pollutants not only affect the body's upper respiratory tract and lungs; cause liver function, immune function, nervous system abnormalities; resulting in loss of function of the central part; and prolonged exposure to high concentrations of formaldehyde can cause a variety of cancer. In June 2004, IARC carcinogens formaldehyde rise from second-class to a class of carcinogens. Indoor formaldehyde release process up to 3 to 15 years, China on March 1, 2003 implementation of the "indoor air quality...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J23/34B01D53/86B01D53/72
CPCB01J23/34B01D53/8668B01D2257/708B01D2258/06
Inventor 金顶峰王俊杰俞天寿柳宛彤金红晓李静彭晓领洪波王新庆
Owner CHINA JILIANG UNIV
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