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Preparation method of Al-Mg-Mn alloy wire

An alloy wire and alloy technology, which is applied in the field of preparation of Al-Mg-Mn alloy wire, can solve problems such as Mg segregation, Mg element loss, broken wire, etc., and achieve uniform precipitation, high recrystallization fraction, and improved alloy resistance The effect of tensile strength

Inactive Publication Date: 2021-09-24
NORTHEASTERN UNIV
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] Due to the serious loss of Mg element in the welding process of Al-Mg series welding wire, the content of Mg element in the aluminum-magnesium welding wire is relatively high. However, the aluminum-magnesium alloy with high Mg content has the problem of difficult deformation, which leads to the phenomenon of wire breakage in the process of producing aluminum-magnesium welding wire. , seriously affecting production efficiency
Mn element can effectively improve the mechanical properties of aluminum-magnesium alloys. It is the most widely used alloying element in Al-Mg welding wire alloys. The content and existence form of Mn elements play an important role in the performance of aluminum-magnesium welding wire products; In the production process of welding wire, the alloying effect of Mn element has not received due attention; due to the serious Mg segregation phenomenon in the as-cast structure of aluminum-magnesium alloy, the homogenization heat treatment of ingot is a necessary process before extrusion deformation. Most of the homogenization process used is 450~550℃, holding time 12~24h, (for example, patent No. CN20151077963.5, CN201711233754.1 and other invention patents), mainly for the homogenization of Mg element, for the Mn element in the alloy At the same time, the impact of extrusion deformation and drawing annealing process on the effect of Mn element has not been paid attention to, which is one of the main reasons for the unsatisfactory quality and mechanical properties of the obtained alloy wire billet

Method used

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  • Preparation method of Al-Mg-Mn alloy wire
  • Preparation method of Al-Mg-Mn alloy wire
  • Preparation method of Al-Mg-Mn alloy wire

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0048] Prepare raw materials according to the alloy composition; the alloy composition contains Mg 6%, Mn 0.8%, Zr 0.1% by mass percentage, the rest is Al and unavoidable impurities; the unavoidable impurities contain Fe≤0.02% by mass percentage, and other impurity elements ≤0.001%; ​​the other impurity elements include Si, Zn, Cu, Ti and Cr;

[0049] Under the condition of argon atmosphere, the raw materials are smelted to obtain an alloy melt; the melting temperature is 740°C;

[0050] Use a metal mold to cast the alloy melt to form an ingot. When the temperature of the ingot drops to 450°C, water quench to room temperature, and then perform homogenization heat treatment at 360°C for 12 hours. After the homogenization heat treatment is completed, water quench to Normal temperature, made into homogenized ingot;

[0051] Heat the homogenized ingot to 500±10°C and keep it warm for 60 minutes; the large-sized Al in the ingot after heat preservation6 The average size of the Mn p...

Embodiment 2

[0057] Method is with embodiment 1, and difference is:

[0058] (1) The alloy composition contains Mg 6.5%, Mn 0.4%, Zr 0.2% by mass percentage;

[0059] (2) The melting temperature is 735°C;

[0060] (3) When the ingot temperature drops to 460°C, water quench to normal temperature;

[0061] (4) Homogenization heat treatment temperature 350°C, time 16h;

[0062] (5) After 500±10°C, heat preservation for 90 minutes; extrusion ratio 64; small and medium-sized Al extrusion rods 6 The Mn phase is spherical with a diameter of 100-150nm;

[0063] (6) A total of 6 times of drawing were carried out, with a total reduction of area of ​​84%; the temperature of each intermediate annealing was 450 ° C, the time was 10 min, and the diameter of the Al-Mg-Mn alloy wire was 2 mm;

[0064] (7) The tensile strength of the Al-Mg-Mn alloy wire is 430.54MPa, and the elongation is 13.4%;

[0065] (8) Perform final annealing to adjust the performance of the prepared Al-Mg-Mn alloy wire. The fin...

Embodiment 3

[0067] Method is with embodiment 1, and difference is:

[0068] (1) The alloy composition contains Mg 4.5%, Mn 1.5%, Zr 0.05% by mass percentage;

[0069] (2) The melting temperature is 720°C;

[0070] (3) When the ingot temperature drops to 470°C, water quench to normal temperature;

[0071] (4) Homogenization heat treatment temperature 370°C, time 15h;

[0072] (5) After 500±10°C, keep warm for 120 minutes; extrusion ratio is 36;

[0073] (6) A total of 10 times of drawing were carried out, with a total reduction of area of ​​96%; the temperature of each intermediate annealing was 400 ° C, the time was 20 minutes, and the diameter of the Al-Mg-Mn alloy wire was 2 mm;

[0074] (7) The tensile strength of the Al-Mg-Mn alloy wire is 470.1MPa, and the elongation is 15.5%;

[0075] (8) Perform final annealing to adjust the properties of the prepared Al-Mg-Mn alloy wire. The final annealing temperature is 400 ° C and the time is 20 minutes to obtain annealed Al-Mg-Mn alloy wir...

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Abstract

The invention discloses a preparation method of an Al-Mg-Mn alloy wire. The preparation method comprises the following steps of (1) preparing raw materials according to alloy components, wherein the alloy comprises the following components in percentage by weight: 4.5-6.5% of Mg, 0.4-1.5% of Mn, 0.05-0.2% of Zr, 0.05-0.25% of Sc and the balance of Al; or the alloy comprises the following components in percentage by weight: 4.5-6.5% of Mg, 0.4-1.5% of Mn, 0.05-0.2% of Zr and the balance of Al; (2) smelting the raw materials in a protective atmosphere; (3) conducting water quenching after pouring; (4) conducting homogenizing heat treatment and water quenching; (5) conducting hot extrusion at 500+ / -10 DEG C; conducting water cooling to normal temperature; and (6) conducting cold drawing on an extrusion bar. By means of the method, the solid solution effect of the Mg element in the aluminum alloy and the second phase strengthening effect of the Mn element in the aluminum alloy can be effectively combined; and according to the wire, a small amount of Sc is added on the basis of the Al-Mg-Mn alloy, so that the tensile strength of an alloy bar can be effectively improved.

Description

technical field [0001] The invention belongs to the technical field of aluminum alloy material processing, and in particular relates to a preparation method of Al-Mg-Mn alloy wire. [0002] technical background [0003] Due to the serious loss of Mg element in the welding process of Al-Mg series welding wire, the content of Mg element in the aluminum-magnesium welding wire is relatively high. However, the aluminum-magnesium alloy with high Mg content has the problem of difficult deformation, which leads to the phenomenon of wire breakage in the process of producing aluminum-magnesium welding wire. , seriously affecting production efficiency. Mn element can effectively improve the mechanical properties of aluminum-magnesium alloys. It is the most widely used alloying element in Al-Mg welding wire alloys. The content and existence form of Mn elements play an important role in the performance of aluminum-magnesium welding wire products; In the production process of welding wire...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C21/06C22C1/03C22F1/047C21D8/06C21D1/26B23K35/28B23K35/40B21C37/04C21D1/18
CPCC22C21/06C22C1/026C22C1/03C22F1/047C22F1/002C21D1/26C21D8/06B23K35/286B23K35/40B21C37/04
Inventor 管仁国王玉杨博威
Owner NORTHEASTERN UNIV
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