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Method for preparing chemicals through crude oil double-pipe series multi-zone catalytic conversion

A catalytic conversion and chemical technology, applied in the production of bulk chemicals, organic chemistry, chemical recovery, etc., can solve the problems of low aromatics content in gasoline, low aromatics content in gasoline, low yield of low-carbon olefins, etc., to reduce coke Yield, increase aromatics content, increase yield effect

Active Publication Date: 2021-10-08
CHINA UNIV OF PETROLEUM (EAST CHINA)
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, with this method, only a certain amount of propylene can be increased, the ethylene yield is low, and the content of aromatics in gasoline is low
Patents CN1557915A, CN1069054A, CN1237477A, ​​WO99 / 57230, US7261807, US4980053, US6569316, MAXOFIN process, PetroFCC process, LOCC process, NEXCC process, MILOS process, HS-FCC process, etc. also have low yields of low-carbon olefins and gasoline aromatics low content problem

Method used

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  • Method for preparing chemicals through crude oil double-pipe series multi-zone catalytic conversion
  • Method for preparing chemicals through crude oil double-pipe series multi-zone catalytic conversion
  • Method for preparing chemicals through crude oil double-pipe series multi-zone catalytic conversion

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] This example takes an upward reaction tube with a swirl structure as an example. After desalination and dehydration, the crude oil is divided into light components and heavy components according to the boiling point after desalination and dehydration, and fractions below 200°C are classified into light components. , The distillate above 200°C is a heavy component.

[0034] see figure 2 In the schematic process flow diagram shown, low-carbon alkanes 121 are injected from the lower part of the first riser reactor 102, and the high-temperature regeneration from the first regenerator 103 is transported by the regeneration inclined pipe 105, and the pre-lifting steam or lifting dry gas 104 is lifted up. Catalyst undergoes contact reaction, reacts for 0.1-5.0s at 600-800°C, agent-oil ratio 5-30, and pressure 0.1-0.4MPa, then leaves the light alkane reaction zone 123 and enters the first heavy oil reaction zone 124. The bottom of the reaction zone 124 is mixed with crude oil...

Embodiment 2

[0036] The upward reaction tube with swirl feed structure is adopted, and the crude oil is directly fed.

[0037] see figure 2 In the schematic process flow diagram shown, low-carbon alkanes 121 are injected from the lower part of the first riser reactor 102, and the high-temperature regeneration from the first regenerator 103 is transported by the regeneration inclined pipe 105, and the pre-lifting steam or lifting dry gas 104 is lifted up. Catalyst undergoes contact reaction, reacts for 0.1-5.0s at 600-800°C, agent-oil ratio 5-30, and pressure 0.1-0.4MPa, then leaves the light alkane reaction zone 123 and enters the first heavy oil reaction zone 124. The bottom of the reaction zone is mixed with crude oil 101 preheated to 150-250°C, reacted at 500-700°C, agent-oil ratio 5-30, and pressure 0.1-0.4MPa for 0.1-5.0s, then enters the gas-solid separator 106 for For the separation of the oil agent, the reaction oil gas 107 is injected into the second reaction tube to continue th...

Embodiment 3

[0039] A descending reaction tube with a swirling feed structure is adopted. After desalination and dehydration, the crude oil is divided into light components and heavy components according to the boiling point after desalination and dehydration, and fractions greater than 200°C °C fractions are heavy components. For the specific process, refer to Example 1.

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Abstract

The invention discloses a method for preparing chemicals from crude oil through double-tube series multi-zone catalytic conversion, which comprises the following steps of: directly feeding the crude oil or firstly desalting and dehydrating the crude oil, and then carrying out flash evaporation or distillation to divide the crude oil into light and heavy components, and adopting a catalyst with high olefin selectivity, high hydrothermal stability, high strength and heavy metal resistance, the two serially connected novel structure reaction tubes are utilized to strengthen the contact reaction of oil gas and a catalyst, the reaction is controlled by zones, the feeding modes are optimally combined according to different properties of reaction materials, and the appropriate reaction conditions of different materials are controlled, so that the aims of improving the yield of low-carbon olefins and improving the content of aromatic hydrocarbons in pyrolysis gasoline can be fulfilled.

Description

technical field [0001] The invention relates to the technical field of petroleum processing, in particular to a method for producing chemicals through catalytic conversion of crude oil with two pipes in series and multiple zones. Background technique [0002] Low-carbon olefins such as ethylene and propylene are basic organic synthetic raw materials for petrochemical industry. With the rapid development of the world economy, their market demand is also increasing year by year, and the growth rate of propylene demand has exceeded that of ethylene. At present, more than 90% of the world's ethylene and nearly 70% of the propylene are derived from steam cracking processes that use light petroleum hydrocarbons such as ethane, naphtha, and light diesel oil as raw materials. However, the reaction severity of steam cracking is high, the reaction temperature even exceeds 1100°C, and the residence time is shortened to less than 0.2 seconds. The space for technological progress is alre...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G55/00C10G3/00C10G1/00C10G1/10C07C4/06C07C11/04C07C11/06C07C11/08
CPCC10G55/00C10G3/42C10G1/08C10G1/10C10G1/002C07C4/06C10G2400/02C10G2400/20C10G2300/10C10G2300/1037C10G2300/1044C10G2300/104C10G2300/1077C10G2300/107C10G2300/70C07C11/04C07C11/06C07C11/08Y02P30/20Y02P20/52Y02P20/584
Inventor 张金弘田原宇杨朝合山红红高春晓
Owner CHINA UNIV OF PETROLEUM (EAST CHINA)