Nickel-based chromium-nickel-cobalt superalloy argon arc welding wire for additive manufacturing and preparation method thereof

An additive manufacturing and superalloy technology, which is applied in the field of nickel-based chromium-nickel-cobalt superalloy argon arc welding wire and its preparation, can solve the problem that high temperature resistant nickel-based alloy materials are expensive, the performance is discontinuous, and the manufacturing process is impossible to achieve and other problems, to achieve the effect of improving anti-oxidative corrosion performance, enhancing precipitation strengthening effect, and good plasticity

Pending Publication Date: 2021-10-12
JIANGSU NEW HENGJI SPECIAL EQUIP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Although the structure of the DC counter-flow channel heat exchanger is very good, it is almost impossible to realize the traditional manufacturing process. Therefore, people have proposed a technical solution to prepare a new heat exchanger structure by using additive manufacturing technology. Additive manufacturing (3D printing ) molding method, because the high-temperature resistant nickel-based alloy material is very expensive, in order to reduce the overall manufacturing cost, the entire heat exchanger is divided into three sections according to the temperature range, namely the high temperature section of 650℃~800℃, the high temperature section of 500℃~650℃ For the middle temperature section and the low temperature section below 500°C, different alloy compositions are used in different temperature sections, which can not only meet the requirements of service conditions, but also greatly reduce the manufacturing cost; because the composition of different alloys is very different, their performance is also very different. In order to avoid the performance discontinuity caused by the composition discontinuity, it is necessary to increase the transition metal zone between the two different alloys to smooth the performance change caused by the dissimilar metals. Therefore, a total of 5 kinds of argon arc welding wires for additive manufacturing are required. to apply to actual working conditions

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] A nickel-based chromium-nickel-cobalt superalloy argon arc welding wire for additive manufacturing, prepared by the following steps:

[0028] Step 1. Alloy smelting: dosing according to the composition and mass percentage of the alloy in the welding wire, calculate the weight of the intermediate alloy of each component, put the intermediate alloy as raw material into the vacuum induction furnace for smelting, and smelt the alloy during the smelting process The composition of the alloy is continuously tested and controlled to ensure that when casting into an ingot, every 100kg of alloy contains C: 0.05kg, Cr: 25.5kg, Co: 20.0kg, Al: 1.3kg, Ti: 1.4kg, Nb+Ta: 1.4kg, Fe: 0.8kg, Mn: 0.5kg, Mo: 0.3kg, Si: 0.5kg, Cu: 0.1kg, P: 0.015kg, S: 0.010kg, B: 0.003kg, Ni: 48.122kg, the alloy solution is cast into an ingot Blank;

[0029] Step 2. Hot forging billet opening: Put the alloy billet into a heating furnace with an initial temperature of ≤600°C for heating, raise the temperat...

Embodiment 2

[0036] A chromium-nickel-cobalt superalloy argon arc welding wire for additive manufacturing, prepared by the following steps:

[0037] Step 1. Alloy smelting: dosing according to the composition and mass percentage of the alloy in the welding wire, calculate the weight of the intermediate alloy of each component, put the intermediate alloy as raw material into the vacuum induction furnace for smelting, and smelt the alloy during the smelting process The composition of the alloy is continuously tested and controlled to ensure that every 100kg alloy contains C: 0.045kg, Cr: 24kg, Co: 19.0kg, Al: 1.2kg, Ti: 1.0kg, Nb+Ta: 1.0kg, Fe : 1.0kg, Mn: 1.0kg, Mo: 0.5kg, Si: 1kg, Cu: 0.5kg, P: 0.02kg, S: 0.008kg, B: 0.0006kg, Ni: 49.7264kg, the alloy solution is cast into an alloy ingot ;

[0038] Step 2. Hot forging billet opening: Put the alloy billet into a heating furnace with an initial temperature ≤ 600°C for heating, raise the temperature to 1185°C, keep it warm for 400 minutes, t...

Embodiment 3

[0045] A chromium-nickel-cobalt superalloy argon arc welding wire for additive manufacturing, prepared by the following steps:

[0046] Step 1. Alloy smelting: dosing according to the composition and mass percentage of the alloy in the welding wire, calculate the weight of the intermediate alloy of each component, put the intermediate alloy as raw material into the vacuum induction furnace for smelting, and smelt the alloy during the smelting process The composition of the alloy is continuously tested and controlled to ensure that when casting into an ingot, every 100kg alloy contains C: 0.065kg, Cr: 26kg, Co: 21kg, Al: 1.4kg, Ti: 1.5kg, Nb+Ta: 1.6kg, Fe: 0.5kg, Mn: 0.8kg, Mo: 0.4kg, Si: 0.4kg, Cu: 0.4kg, P: 0.010kg, S: 0.005kg, B: 0.006kg, Ni: 45.914kg, the alloy solution is cast into an alloy ingot ;

[0047] Step 2. Hot forging billet opening: Put the alloy billet into a heating furnace with an initial temperature of ≤600°C for heating, raise the temperature to 1185°C, kee...

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Abstract

The invention discloses a chromium-nickel-cobalt superalloy argon arc welding wire for additive manufacturing and a preparation method thereof. The chromium-nickel-cobalt superalloy argon arc welding wire is characterized by comprising the following components in percentage by weight: 0.045-0.065% of C, 24.0-26.0% of Cr, 19.0-21.0% of Co, 1.2-1.4% of Al, 1.0-1.5% of Ti, 1.0-1.6% of Nb+Ta, less than or equal to 1.0% of Fe, less than or equal to 1% of Mn, less than or equal to 0.50% of Mo, less than or equal to 1% of Si, less than or equal to 0.5% of Cu, less than or equal to 0.020% of P, less than or equal to 0.010% of S, 0.0006-0.0060% of B and the balance Ni. The preparation method comprises the following steps: A, burdening, and forming of a steel ingot through pouring; B, steel ingot hot forging cogging; C, hot rolling annealing; D, acid pickling and coping; E, drawing step by step; and F, hydrogen annealing treatment. The performance of the chromium-nickel-cobalt superalloy argon arc welding wire ensures that the equipment operates safely and reliably under high-temperature and high-pressure corrosion working conditions.

Description

technical field [0001] The invention relates to an additive manufacturing technology, which is mainly applied to the additive manufacturing of the helium inlet side and the steam outlet side area (high temperature section of 650°C to 800°C) of the heat exchanger of the high temperature gas-cooled reactor steam generator. Specifically, it is a nickel-based chromium-nickel-cobalt superalloy argon arc welding wire for additive manufacturing and a preparation method thereof. The temperature of the material can be as high as about 850°C. Background technique [0002] The nuclear power steam generator is the heat exchange equipment that generates the steam required by the steam turbine, and it is also one of the most critical main equipment of the nuclear power plant. The steam generator is connected with the reactor pressure vessel, which not only directly affects the power and efficiency of the power plant, but also when exchanging heat, It also plays a role in blocking radioact...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B23K35/30B23K35/40B33Y70/00
CPCB23K35/304B23K35/40B33Y70/00B23K35/0261
Inventor 向俊陈敬一向田法王槐春
Owner JIANGSU NEW HENGJI SPECIAL EQUIP
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