A miR-375 and PTX loaded four-way adapter RNA nano-drug and a preparation method and application thereof
A mir-375, nano-drug technology, applied in the field of tumor targeted therapy, can solve the problem of low drug targeted delivery efficiency, and achieve good esophageal squamous cell carcinoma inhibitory effect, effective treatment effect, and low off-target effect.
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[0026] The technical solution of the present invention will be further described below in conjunction with the examples, but it should not be understood as a limitation to the technical solution, and the adaptive improvements on this basis all belong to the protection scope of the present invention.
[0027] 1. Construction of 4WJ-miR-375-PTX:
[0028] (1) RNA oligonucleotide synthesis: synthesize oligonucleotides rG, rG, rC, rU, 2'F rC2'F rU phosphoramide monomer, 2'O-propargyl rC and rU phosphoramide monomer, and Analysis and purification by gel electrophoresis after desalting treatment by desalting column;
[0029] (2) Synthesis of PTX-azide compounds: PTX, 6-azidocaproic acid, N, N'-dicyclohexylcarbodiimide and 4-(dimethylamino)pyridine in a molar ratio of 1:2:2:1 The concentration was added to 10L of dichloromethane; the mixed solution was stirred overnight at room temperature for 16h, and the crude product was obtained by filtration and rotary evaporation; the crude pro...
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