Waterborne anti-static epoxy floor paint and preparation method thereof

A technology of epoxy floor paint and anti-static ring, applied in epoxy resin coatings, conductive coatings, coatings, etc., can solve the problem of inability to increase anti-static properties, reduce mechanical properties of epoxy floor paint, and poor dispersion of conductive fillers and other problems, to achieve the effect of balancing emulsification and curing rates, improving mechanical properties, and increasing dispersibility

A technology of epoxy floor paint and anti-static ring, applied in epoxy resin coatings, conductive coatings, coatings, etc., can solve the problem of inability to increase anti-static properties, reduce mechanical properties of epoxy floor paint, and poor dispersion of conductive fillers and other problems, to achieve the effect of balancing emulsification and curing rates, improving mechanical properties, and increasing dispersibility

CN113549385AActive Publication Date: 2021-10-26辽宁鹏维化工制漆有限责任公司
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  • Waterborne anti-static epoxy floor paint and preparation method thereof
  • Waterborne anti-static epoxy floor paint and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] A preparation method of water-based antistatic epoxy floor paint, comprising the following steps:

[0036]S1: Preparation of composite conductive material: (1) Stir and disperse 21 parts of 3-aminopropyltriethoxysilane weighed in absolute ethanol, set the stirring speed to 400rmp, and stir for 40 minutes; add ammonia solution Adjust the pH to 10; add 46 parts of silica nanoparticles, react for 1 hour, centrifugally wash, filter, and dry at 55°C to obtain aminated silica for use; (2) ultrasonically disperse 8 parts of graphene oxide airgel In deionized water, add aminated silicon dioxide, set the stirring to 500rmp; add ammonia water, set the reaction temperature to 90°C and react for 5 hours, filter and wash, and freeze-dry at -50°C to obtain a composite conductive material for future use.

[0037] S2: Preparation of water-based epoxy curing agent; 12 parts of triethylenetetramine weighed are dissolved in 2-butoxyethanol and n-butanol mixed solvent; 86 parts of bispheno...

Embodiment 2

[0040] A preparation method of water-based antistatic epoxy floor paint, comprising the following steps:

[0041] S1: Preparation of composite conductive material: (1) Stir and disperse 16 parts of 3-aminopropyltriethoxysilane weighed in absolute ethanol, set the stirring speed to 300rmp, and stir for 40 minutes; add ammonia solution Adjust the pH to 10; add 40 parts of silica nanoparticles, react for 1 hour, centrifugally wash, filter, and dry at 50°C to obtain aminated silica for use; (2) Ultrasonic disperse 8 parts of graphene oxide airgel In deionized water, add aminated silicon dioxide, set the stirring to 500rmp; add ammonia water, set the reaction temperature to 90°C and react for 5 hours, filter and wash, and freeze-dry at -30°C to obtain a composite conductive material for future use.

[0042] S2: Preparation of water-based epoxy curing agent; dissolve 10 parts of triethylenetetramine weighed in 2-butoxyethanol and n-butanol mixed solvent; configure 80 parts of bisphe...

Embodiment 3

[0045] A preparation method of water-based antistatic epoxy floor paint, comprising the following steps:

[0046] S1: Preparation of composite conductive material: (1) Stir and disperse 24 parts of 3-aminopropyltriethoxysilane weighed in absolute ethanol, set the stirring speed to 400rmp, and stir for 60 minutes; add ammonia solution Adjust the pH to 10; add 60 parts of silica nanoparticles, react for 2 hours, centrifugally wash, filter, and dry at 55°C to obtain aminated silica for use; (2) ultrasonically disperse 12 parts of graphene oxide airgel In deionized water, add aminated silicon dioxide, set the stirring to 600rmp; add ammonia water, set the reaction temperature to 95°C and react for 6 hours, filter and wash, and freeze-dry at -50°C to obtain a composite conductive material for later use.

[0047] S2: Preparation of water-based epoxy curing agent; dissolve 15 parts of triethylenetetramine weighed in 2-butoxyethanol and n-butanol mixed solvent; configure 95 parts of b...

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Abstract

The invention discloses a water-based anti-static epoxy floor paint and a preparation method thereof. The epoxy floor paint comprises component A slurry and component B slurry; the component A slurry is prepared from the following raw materials in parts by weight: 82 to 90 parts of bisphenol A epoxy resin and 12 to 20 parts of reactive diluent; and the component B slurry is prepared from the following raw materials in parts by weight: 50 to 62 parts of waterborne epoxy curing agent, 8 to 12 parts of composite conductive material, 0.1 to 2 parts of defoaming agent and 0.05 to 2 parts of flatting agent. The waterborne epoxy curing agent has the excellent effects that (1) the emulsifying and curing rates are effectively balanced, and the waterborne epoxy curing agent with double functions of emulsifying and curing is obtained; (2) the three-dimensional structure of the composite conductive material is utilized to increase the flow and permeation of the liquid resin; the dispersity of the composite conductive material is improved; an effective conductive network is constructed, electrostatic charges are eliminated, and the anti-static property is improved; the water-based epoxy curing agent is assisted to solve the problem of stress concentration; and the page interaction is increased, and the mechanical property is improved.

Description

technical field [0001] The invention relates to the technical field of epoxy floors, in particular to a water-based antistatic epoxy floor paint and a preparation method thereof. Background technique [0002] The bisphenol A type epoxy resin of the present invention is a thermosetting resin with excellent anticorrosion performance and environmental friendliness, therefore, it is widely used in epoxy floor paints and in organic anticorrosion coatings. Traditional epoxy floor paint consists of two components, A and B. Usually, the curing agent is a separate component, which is mixed with bisphenol A epoxy resin to cure before use. The water solubility of materials within two components, and the compatibility between the two components have been the focus of research. Especially the water solubility of bisphenol A epoxy resin and the compatibility with curing agent. Therefore, preparing a curing agent with bisphenol A type epoxy resin emulsifying function is one of the ways t...

Claims

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Application Information

Patent Timeline
26 Oct 2021
Publication
CN113549385A
IPC
C09D163/00; C09D5/24; C08G59/50
CPC
C09D163/00; C09D5/24; C08G59/504; C09D7/62; C08K2201/011; C08K7/24; C08K3/36; C08K9/06
Inventors
李立军