Composition and heat conducting material
A technology of composition and phenolic compound, which is applied in the field of composition and thermally conductive materials, and can solve problems such as difficult heat control of power semiconductor devices
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[0554] Hereinafter, the present invention will be described in further detail based on examples. Materials, usage amounts, ratios, processing contents, processing procedures, and the like shown in the following examples can be appropriately changed unless departing from the gist of the present invention. Therefore, the scope of the present invention should not be limitedly interpreted by the Examples shown below.
[0555] [Preparation and evaluation of compositions]
[0556] [various ingredients]
[0557] Various components used in Examples and Comparative Examples are shown below.
[0558]
[0559] The phenol compounds used in Examples and Comparative Examples are shown below.
[0560] In addition, the following phenolic compounds A-1 to A-13 are phenolic compounds represented by the general formula (1).
[0561] In addition, in the following phenolic compounds, Mn represents the number average molecular weight of the phenolic compound. The phenolic compound described ...
Synthetic example A-1
[0567] Phenol compound A-1 was obtained by the following method.
[0568] In the flask, 30 g of phloroglucinol as a monomer and 100 g of water as a solvent were mixed and stirred. In the above-mentioned flask, 0.6 g of oxalic acid and 14.5 g of 37% by mass formalin were further added as a catalyst, and stirred at 105° C. for 4 hours. After cooling the contents of the above-mentioned flask to room temperature, the slurry obtained in the flask was filtered to obtain a crude product (filtrate) of a phenol compound. The obtained crude product was dissolved in 200 g of acetone, and the insoluble matter was removed by filtration with celite. Acetone was distilled off from the filtrate under reduced pressure, water was added to obtain a slurry again, and the slurry was filtered to obtain phenol compound A-1 (filter).
Synthetic example A-2
[0570] Phenolic compound A-2 was obtained by the method similar to synthesis example A-1 except having made the addition amount of 37 mass % formalin into 12.9 g.
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