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Repairing agent as well as preparation method and application thereof

A technology of remediation agent and catalyst, which is applied in the field of contaminated soil remediation, and can solve problems such as poor synchronous remediation effect

Pending Publication Date: 2021-11-30
HEBEI YUHUAN ENVIRONMENTAL PROTECTION TECH CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, for heavy metal and organic compound-contaminated soil, a simple combination of single / similar pollutant remediation technologies is currently used, but this simple combination method does not fully consider the adsorption behavior, chemical action, and soil pollution of compound pollutants in soil. Factors such as biological interactions, resulting in poor synchronous repair

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0048] Preparation of porous spherical ceramics: 20-50 parts of quartz sand, 20-50 parts of zirconia, 5-20 parts of alumina, 10-30 parts of piezoelectric catalyst, 0.5-2 parts of pore-forming agent and 1-3 parts of binder Mix, granulate, dry, and sinter at 1100-1350°C for 3-5 hours to obtain porous spherical ceramics with a diameter of 10-25mm;

[0049] Preparation of biochar: pyrolyze agricultural and forestry waste at 650-850°C for 5-6 hours to obtain it;

[0050] Preparation of the restorative agent: mix 3-30 parts of porous ceramics and 2-10 parts of biochar to obtain the product.

[0051] Restoration: After mixing the soil to be repaired and the repairing agent according to the mass ratio of 100:5-40, add water to make the moisture content of the mixture 30wt%-70wt%, then carry out wet grinding and mixing for 0.5-3h, and the stirring speed is 1000-3000 rpm / min.

[0052] The mixing and stirring in the above wet milling is carried out in the process of wet milling.

Embodiment 1

[0056] The present embodiment provides a kind of remediation method of remediation agent in the soil polluted by heavy metals and organic matter, specifically comprises the following steps:

[0057] Preparation of porous spherical ceramics: 25 parts of quartz sand, 40 parts of zirconia, 10 parts of alumina, 30 parts of piezoelectric catalyst lead zirconate titanate, 2 parts of pore-forming agent ammonium bicarbonate and 2 parts of binder polyvinyl alcohol are mixed, After granulation and drying, sinter at 1100°C for 5 hours to obtain porous spherical ceramics with a diameter of 15-20mm;

[0058] Preparation of biochar: pyrolyze rice husk at 650°C for 6 hours to obtain it;

[0059] Preparation of repairing agent: mix 20 parts of porous ceramics and 5 parts of biochar to get it;

[0060] Restoration: After mixing the soil to be repaired and the repairing agent according to the mass ratio of 100:25, add water to make the moisture content of the mixture 50wt%, and then carry out ...

Embodiment 2

[0063] The present embodiment provides a kind of remediation method of remediation agent in the soil polluted by heavy metals and organic matter, specifically comprises the following steps:

[0064] Preparation of porous spherical ceramics: 20 parts of quartz sand, 50 parts of zirconia, 5 parts of alumina, 20 parts of piezoelectric catalyst (10 parts of bismuth oxychloride and 10 parts of barium titanate), 0.5 part of pore-forming agent sodium carbonate and bonding Mix 3 parts xanthan gum, granulate, dry and sinter at 1350°C for 4 hours to obtain porous spherical ceramics with a diameter of 20-25mm;

[0065] Preparation of biochar: pyrolyze peanut shells at 850°C for 5 hours to obtain;

[0066] Preparation of restoration agent: mix 30 parts of porous ceramics and 2 parts of biochar to get it;

[0067] Restoration: After mixing the soil to be repaired and the repairing agent according to the mass ratio of 100:32, add water to make the moisture content of the mixture 30wt%, and...

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Abstract

The invention relates to a repairing agent as well as a preparation method and application thereof. The repairing agent comprises porous ceramic and biochar; the porous ceramic comprises the following raw materials in parts by weight: 20-50 parts of quartz sand, 20-50 parts of zirconium oxide, 5-20 parts of aluminum oxide, 10-30 parts of a piezoelectric catalyst, 0.5-2 parts of a pore forming agent and 1-3 parts of a binder. According to the repairing agent provided by the invention, through mutual cooperation of the specific porous ceramic and the biochar, synchronous oxidation / reduction of heavy metals and oxidative degradation of organic pollutants can be realized. In addition, the repairing agent provided by the invention does not contain chemical agents, does not cause secondary pollution to soil, and has a good application prospect.

Description

technical field [0001] The invention relates to the field of contaminated soil remediation, in particular to a remediation agent and its preparation method and application. Background technique [0002] Soil pollution refers to the phenomenon that harmful substances produced by human activities enter the soil. When the content exceeds the self-purification ability of the soil itself, it will cause changes in the composition and properties of the soil, reduce the yield and quality of crops, and endanger human health. Among them, heavy metals and organic matter are the two most typical soil pollutants, and. According to statistics, heavy metals and petroleum hydrocarbon organic pollutants are the two main pollutants detected at present, and most of them are complex pollution sites of heavy metals and organic substances. [0003] At present, soil remediation is mostly aimed at the remediation of single or similar pollutants. For example, for heavy metal-contaminated soil, rem...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K17/40B09C1/08
CPCC09K17/40B09C1/08
Inventor 陈辉霞佟雪娇张红玲刘星海何谦宋庆赟徐红彬冯爱茜赵倩云
Owner HEBEI YUHUAN ENVIRONMENTAL PROTECTION TECH CO LTD