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Solid electrolyte film and preparation method and application thereof

A technology of solid electrolyte and electrolyte, which is applied in the direction of circuits, electrical components, secondary batteries, etc., can solve the problems of uncontrollable film width and thickness, difficult manufacturing process of solid electrolyte film, unstable electrochemical performance, etc., and achieve good biological performance. Effect of compatibility and degradability, good electrochemical stability, and good electrochemical performance

Pending Publication Date: 2021-12-10
NEW MATERIAL INST OF SHANDONG ACADEMY OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the technical problems in the invention and production of the solid electrolyte film of the degradable battery mainly include: 1. The solid electrolyte film of the degradable battery needs to have both electrochemical stability and degradability, so the material selection is extremely limited The electrochemical performance of the current degradable solid electrolyte membrane is unstable; 2. The production process of the solid electrolyte membrane for degradable batteries is relatively difficult, and the width and thickness of the membrane cannot be controlled

Method used

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  • Solid electrolyte film and preparation method and application thereof
  • Solid electrolyte film and preparation method and application thereof
  • Solid electrolyte film and preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] Step 1, preparation of cellulose airgel: add 20 g of carboxylated cellulose nanofibers to 60 mL of deionized water, then add 0.3 g of polyvinyl alcohol, and place in a constant temperature oil bath at 95°C for 2 hours. After the solution is cooled, quickly add 0.5g of citric acid and 0.5mL of phosphoric acid, and stir until uniform without lumps. Pour the uniform solution into a mold and put it in a refrigerator to freeze at -18°C for 2 hours, and finally freeze-dry it at -45°C and 20 Pa for 48 hours to obtain the cellulose airgel.

[0043] Step 2, preparation of colloidal guar gum electrolyte: ZnSO 4 (AR grade, Sigma) and MnSO 4 (AR grade, Sigma) was added to deionized water and stirred evenly, and ultrasonically removed air bubbles to obtain 10 mL of ZnSO with a concentration of 2 mol / L 4 and 0.1mol / LMnSO 4 mixed solution. Pour 0.6 g of guar gum into the mixed solution while stirring and mix evenly to obtain a colloidal guar gum electrolyte.

[0044]Step 3, prepa...

Embodiment 2

[0055] Same as Example 1, the difference is that step 3 is specifically: inject the colloidal guar gum electrolyte into the cellulose airgel using a syringe, fully mix (at this time, it is in a solid-liquid mixed state), and level it out with a medicine spoon. Spread it on a watch glass to form a film, and dry it to the desired humidity to obtain a solid electrolyte. Cut it into various sizes according to requirements, such as 1cm*1cm*0.06cm, to obtain a solid electrolyte film.

[0056] Results: The solid electrolyte film prepared in this example has no obvious difference from Example 1.

Embodiment 3

[0058] Same as Example 1, the difference is that step 3 is specifically: inject the colloidal guar gum electrolyte into the cellulose airgel using a syringe, then put the mixture (solid-liquid mixed state) into a beaker and stir until uniform Then pour it into a petri dish and spread it into a film to obtain a solid electrolyte. Cut it into various sizes according to requirements, such as 1cm*1cm*0.06cm, to obtain a solid electrolyte film.

[0059] Results: The solid electrolyte film prepared in this example has no obvious difference from Example 1.

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Abstract

The invention discloses a solid electrolyte film and a preparation method and application thereof, and belongs to the field of degradable batteries. The solid electrolyte film takes cellulose aerogel as a framework and takes colloidal guar gum electrolyte as a filler. The preparation method comprises the following steps: 1, preparing cellulose aerogel; 2, preparing a colloidal guar gum electrolyte; and 3, preparing a solid electrolyte film: doping the colloidal guar gum electrolyte into the cellulose aerogel to prepare the solid electrolyte film. The preparation method is simple in process, low in cost and suitable for large-scale production, and the prepared solid electrolyte film can effectively inhibit generation of zinc dendrites, so that the whole battery has high electrochemical stability, high specific capacity and good electrochemical performance.

Description

technical field [0001] The invention relates to the field of degradable batteries, in particular to a solid electrolyte film and its preparation method and application. Background technique [0002] At present, more than 50 million tons of e-waste are generated every year, and most of the e-waste is disposed of through landfill, which imposes a heavy burden on the environment. Therefore, the study of transient flexible electronic devices is particularly important. Transient electronics refers to state-of-the-art technologies that partially or completely degrade, dissolve or disintegrate under certain conditions in an actively and passively controlled manner. Transient electronic products can use biodegradable materials, or non-biodegradable materials that can be degraded by the environment to protect the environment. For green electronics, the introduction of degradable materials into consumer electronics or environmental monitors is expected to greatly alleviate landfill ...

Claims

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Application Information

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IPC IPC(8): H01M10/0565
CPCH01M10/0565Y02E60/10
Inventor 李勇许冉高萌谷倩倩李东玮王猛
Owner NEW MATERIAL INST OF SHANDONG ACADEMY OF SCI
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