Packaging wrapping film and preparation method thereof
A technology of stretch film and thermoplastic elastomer, which is applied in the field of packaging stretch film and its preparation, can solve the problems of further improvement of mechanical properties, easy occurrence of extravasation, poor stability of material properties, etc.
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[0037] As a preferred embodiment, the waste polyareneoxadiazole fiber is a waste product of Baodren short fiber; its average diameter is 1-3 μm, and its aspect ratio is 20-30.
[0038] As a preferred embodiment, the vinyl-terminated nitrile rubber is VTBN1300X33LC, a product of CVC Specialty Chemicals Co., Ltd., USA.
[0039] As a preferred embodiment, the rosin polyether sulfonate is a rosin polyether prepared according to the method of Example 1 of the Chinese invention patent of application number 201711335006.4 (this article is incorporated herein by reference as part of the present invention) Sulfonate.
[0040] As a preferred embodiment, the initiator is at least one of cumene hydroperoxide, methyl ethyl ketone peroxide, diisopropyl peroxydicarbonate, and azobisisobutyronitrile.
[0041] As a preferred embodiment, the environmentally friendly plasticizer is at least one of tributyl citrate, trioctyl citrate, and epoxidized soybean oil.
[0042] The invention also discl...
Embodiment 1
[0053] A wrapping stretch film, characterized in that it is prepared from the following components in parts by weight:
[0054] Waste thermoplastic elastomer TPEE 25 parts,
[0055] 4 parts of waste polyarylene oxadiazole fiber,
[0056] Terminal vinyl nitrile rubber 15 parts,
[0057]Rosin polyether sulfonate 4 parts,
[0058] 1.5 parts of pentaerythritol tetra-3-mercapto propionate,
[0059] 1.0 parts of 1-allyl-3-methyl imidazole chloride,
[0060] 0.4 part of initiator,
[0061] 0.2 parts of phosphorus pentoxide,
[0062] Environmentally friendly plasticizer 0.5 parts.
[0063] The waste thermoplastic elastomer TPEE is a waste product of EM550 thermoplastic elastomer TPEE; the waste polyarylene oxadiazole fiber is a waste product of Baodren short fiber; its average diameter is 1 μm, and the aspect ratio for 20.
[0064] The vinyl-terminated nitrile rubber is VTBN1300X33LC, a product of CVC Specialty Chemicals Co., Ltd., USA; the initiator is cumene hydroperoxide; a...
Embodiment 2
[0067] A wrapping stretch film, characterized in that it is prepared from the following components in parts by weight:
[0068] Waste thermoplastic elastomer TPEE 27 parts,
[0069] 5 parts of waste polyarylene oxadiazole fibers,
[0070] Terminal vinyl nitrile rubber 11 parts,
[0071] Rosin polyether sulfonate 2.5 parts,
[0072] 0.7 parts of pentaerythritol tetra-3-mercaptopropionate,
[0073] 0.6 parts of 1-allyl-3-methyl imidazole chloride,
[0074] 0.25 part of initiator,
[0075] 0.12 parts of phosphorus pentoxide,
[0076] Environmentally friendly plasticizer 0.3 parts.
[0077] The waste thermoplastic elastomer TPEE is selected from the waste product of the thermoplastic elastomer TPEE whose brand is EM630; the waste polyarylene oxadiazole fiber is a waste product of Baodren staple fiber; its average diameter is 1.5 μm, and its length is The diameter ratio is 22; the vinyl-terminated nitrile rubber is VTBN1300X33LC, a product of CVC Specialty Chemicals Co., Ltd...
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