Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Preparation method of foamed polypropylene beads

A technology for foaming polypropylene and polypropylene, which is applied in the field of foaming polypropylene to achieve the effects of low molding and sintering pressure, excellent apparent quality, and reduced residual content

Active Publication Date: 2021-12-24
WUXI HI TEC ENVIRONMENTAL MATERIAL CO LTD
View PDF9 Cites 3 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the above patented technologies have obtained foamed bead products with less surface attachments, there is still room for further improvement

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] R3410 is used as the base material, and 10% (mass percentage) masterbatches are made of crystal nucleating agent NA-11, talc powder and tris(2,3-dibromopropyl) phosphate respectively.

[0037] Particle making: mechanically mix R3410, crystallization nucleating agent masterbatch, cell nucleating agent masterbatch, and organic phosphate compound masterbatch in proportion, and then melt and mix them through a single-screw extruder, and extrude wire drawing and pelletizing , to obtain polypropylene particles with a unit weight of 1.2 mg and a length of 2.0 mm. The mass percentages of each component in the prepared polypropylene particles are: R3410 96.35%, crystal nucleating agent 1.5%, cell nucleating agent 0.15%, and organic phosphate compounds 2%.

[0038]Kettle pressure foaming: In a high-pressure reaction kettle with a volume of 50L, add 20kg of polypropylene particles, 20kg of deionized water, 0.05kg of washed kaolin, 0.006kg of sodium methyl stearate polyoxyethylene ...

Embodiment 2

[0044] Using R3410 as the base material, the crystallization nucleating agent NA-11, talcum powder and tricresyl phosphate were respectively made into 10% (mass percentage) master batches.

[0045] Particle making: mechanically mix R3410, crystallization nucleating agent masterbatch, cell nucleating agent masterbatch, and organic phosphate compound masterbatch in proportion, and then melt and mix them through a single-screw extruder, and extrude wire drawing and pelletizing , to obtain polypropylene particles with a unit weight of 0.8 mg and a length of 1.8 mm. The mass percentages of the components in the prepared polypropylene particles are: R3410 94%, crystal nucleating agent 1.7%, cell nucleating agent 0.3%, and organic phosphate compounds 4%.

[0046] Kettle pressure foaming: In a high-pressure reactor with a volume of 50L, add 18kg of polypropylene particles, 22kg of deionized water, 0.015kg of washed kaolin, 0.02kg of sodium methyl stearate polyoxyethylene ether sulfona...

Embodiment 3

[0050] R3410 was used as the base material, and 10% (mass percent) masterbatches were made of crystallization nucleating agent NA-11, talcum powder and lauryl ether phosphate.

[0051] Particle making: mechanically mix R3410, crystallization nucleating agent masterbatch, cell nucleating agent masterbatch, and organic phosphate compound masterbatch in proportion, and then melt and mix them through a single-screw extruder, and extrude wire drawing and pelletizing , to obtain polypropylene particles with a unit weight of 1.8 mg and a length of 2.5 mm. The mass percentages of the components in the prepared polypropylene particles are: R3410 99%, crystal nucleating agent 0.9%, cell nucleating agent 0.05%, and organic phosphate compounds 0.05%.

[0052] Kettle pressure foaming: In a high-pressure reactor with a volume of 50L, add 18kg of polypropylene particles, 22kg of deionized water, 0.053kg of washed kaolin, 0.012kg of sodium methyl stearate polyoxyethylene ether sulfonate, and ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
lengthaaaaaaaaaa
melting pointaaaaaaaaaa
melt flow indexaaaaaaaaaa
Login to View More

Abstract

The invention belongs to the technical field of foamed polypropylene, and relates to a preparation method of foamed polypropylene beads, which comprises the following steps: (1) adding polypropylene particles, a dispersion medium, a dispersing agent and a dispersing aid into a closed high-pressure-resistant kettle, and conducting stirring to form a dispersion system; (2) conducting heating to a certain temperature, and conducting filling with a certain amount of CO2; and (3) releasing the dispersion to normal pressure to obtain foamed polypropylene beads, conducting washing with cleaning water, conducting dehydrating, and conducting drying to obtain a foamed polypropylene bead finished product. The polypropylene particles comprise the following components in percentage by weight: 94 to 99.94 percent of polypropylene, 0.01 to 2 percent of a crystallization nucleating agent, 0.02 to 4 percent of an organophosphate compound and 0.03 to 0.3 percent of a cell nucleating agent. The polypropylene particles used in the invention contain organophosphate compounds, and have the effect of inhibiting the particles from caking in a kettle or the beads from caking outside the kettle in the high-temperature and high-pressure kettle type foaming process, so that the use amount of a dispersing agent can be reduced, the content of attachments on the surface of the foamed polypropylene bead finished product is lower than 200ppm, and a water vapor molded part is lower in sintering pressure and excellent in apparent quality.

Description

technical field [0001] The invention belongs to the technical field of expanded polypropylene, and in particular relates to a preparation method of expanded polypropylene beads. Background technique [0002] Expanded polypropylene beads (EPP) can be easily molded into application parts of various shapes through the steam molding process, and the EPP beads produced by the mainstream batch foaming method in the industry have a closed-cell structure and a high expansion rate. High, endowing EPP parts with excellent dimensional accuracy and lightweight characteristics, many performance advantages make EPP widely used in automotive cushioning and protection parts, packaging and transportation cushioning materials and lightweight structural parts and other application scenarios. [0003] The manufacturing process of EPP produced by the kettle method is as follows: the foamable polypropylene-based polymer material is extruded and granulated by the extruder unit to obtain particles ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/14C08L71/02C08K5/521C08K3/34C08K5/42C08J9/16C08J9/12
CPCC08J9/16C08J9/122C08J9/0095C08J9/0038C08J9/0066C08J9/0033C08J2203/06C08J2323/14C08J2471/02
Inventor 熊业志曾佳刘缓缓蒋璠晖史亚杰宋新意杨亮炯路骐豪周仲波卢汉州朱民何若虚
Owner WUXI HI TEC ENVIRONMENTAL MATERIAL CO LTD
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products