Lithium ion battery non-aqueous electrolyte containing cyano cyclic unsaturated hydrocarbon compound and lithium ion battery
A lithium-ion battery, non-aqueous electrolyte technology, applied in the field of lithium-ion battery non-aqueous electrolyte and lithium-ion batteries, can solve the problems of interface film instability, impedance, gas production and voltage drop increase, and achieve improved cycle performance And discharge performance, increase life and stability, improve the effect of storage capacity
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Embodiment 1
[0034]The non-aqueous electrolyte solution for lithium-ion batteries was prepared as follows: in a glove box, ethylene carbonate (EC), propylene carbonate (PC), diethyl carbonate (DEC) and ethyl methyl carbonate (EMC) were mixed according to mass Mix at a ratio of 25:5:50:20 to obtain a mixed solvent, and then add LiPF to the mixed solvent 6 , LiDFOB, LiBF 4 The mixed lithium salt of composition (mass ratio is LiPF 6 :LiDFOB:LiBF 4 =0.95:0.0375:0.0125) to prepare an electrolyte with a mixed lithium salt concentration of 1.3M. After that, 0.5% vinylene carbonate (VC), 5% fluoroethylene carbonate (FEC), 4% 1,3-propane sultone (PS) and 1% of the compound (1) was stirred evenly to obtain the non-aqueous electrolyte solution for the lithium ion battery of Example 1.
Embodiment 2-12
[0036] Examples 2-12 are also specific examples of electrolyte preparation. Except for the parameters in Table 1, other parameters and preparation methods are the same as in Example 1. The electrolyte formulation is shown in Table 1.
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