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Ceramic matrix composite slender thin-wall pipe fitting preparation method, ceramic matrix composite slender thin-wall pipe fitting based on method and application of pipe fitting

A composite material and ceramic-based technology, which is applied in the field of ceramic-based composite slender thin-walled pipe fittings and their preparation, can solve the problem of large residual porosity, inability to achieve ultra-long-diameter ratio, and inability to meet external and in-stack assessment requirements, etc. problem, to achieve the effect of economical efficiency, low cost and improved air tightness

Active Publication Date: 2022-02-18
XIAN XINGUI CERAMIC COMPOSITE MATERIAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The purpose of the present invention is to overcome the inability of existing methods to achieve super aspect ratio and ultra-thin wall thickness Cf / SiC or SiC Formation of f / SiC ceramic matrix composite fiber preforms and Cf / SiC or SiCf / SiC ceramic matrix composites prepared by existing methods due to residual For the problem that the porosity is too large to meet the assessment requirements outside the stack and into the stack, a method for preparing ceramic matrix composite pipe fittings with an ultra-length-to-diameter ratio and ultra-thin wall thickness is provided, and a ceramic matrix composite pipe fitting prepared based on the above method is also provided correspondingly. Slender and thin-walled pipe fittings, meeting the relevant assessment requirements and application requirements for fuel cladding tubes for gas-cooled reactors and fuel cladding tubes for pressurized water reactors

Method used

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  • Ceramic matrix composite slender thin-wall pipe fitting preparation method, ceramic matrix composite slender thin-wall pipe fitting based on method and application of pipe fitting
  • Ceramic matrix composite slender thin-wall pipe fitting preparation method, ceramic matrix composite slender thin-wall pipe fitting based on method and application of pipe fitting

Examples

Experimental program
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Effect test

Embodiment 1

[0036] This example is for SiC f The thickness of the middle layer of SiC composite material is 0.7mm, the thickness of the inner layer of SiC ceramic is 50±10μm, the thickness of the outer layer of SiC ceramic is 50±10μm, the length is 300mm, and the outer diameter is 9.50mm.f / SiC tube preparation.

[0037] Choose a suitable outer diameter, 300mm long stainless steel tubular or rod-shaped mandrel, and wind a 1mm thick paper layer (centrifugal paper or kraft paper, etc.) and 1.05mm thick SiC fiber cloth to form a 300mm long tubular fiber prefabricated body; the tubular fiber The preform is placed in the graphite outer mold (holes with a diameter of 2-3mm are evenly distributed on the mold wall of the graphite outer mold), and then the mandrel is extracted, and a 150 ± 20nm thick fiber is prepared on the tubular fiber preform by chemical vapor infiltration. Pyrolyze the carbon interface to form a tubular fiber preform containing the interface; remove the carbonized paper dust...

Embodiment 2

[0044] This example is for C f / The thickness of the middle layer of SiC composite material is 2mm, the thickness of the inner layer of SiC ceramic is 50±10μm, the thickness of the outer layer of SiC ceramic is 50±10μm, the length is 950mm, and the outer diameter is 29.00mm. f / SiC tube preparation.

[0045] Select a suitable outer diameter, 950mm long aluminum alloy tubular mandrel, and wrap 1.5mm thick centrifugal paper and 2.5mm thick SiC fiber cloth successively to form a 950mm long tubular fiber preform; place the tubular fiber preform in the graphite outer mold (the uniform diameter is 2-3mm hole on the mold wall of this graphite outer mold), then the mandrel is extracted out, adopts the chemical vapor infiltration method to prepare the pyrolytic carbon interface of 150 ± 20nm thickness on the tubular fiber prefabricated body, forms containing Tubular fiber preform at the interface; remove the carbonized centrifugal paper in the core of the fiber preform, and use trich...

Embodiment 3

[0052] SiC f The thickness of the middle layer of SiC composite material is 0.7mm, the thickness of the inner layer of SiC ceramic is 50±10μm, the thickness of the outer layer of SiC ceramic is 50±10μm, the length is 1200mm, and the outer diameter is 9.50mm. f / SiC tube preparation. .

[0053] Choose a suitable outer diameter, 1200mm long aluminum alloy rod-shaped mandrel is wound successively with 1mm thick centrifugal paper and 1.05mm thick SiC fiber cloth to form a 1200mm long tubular fiber prefabricated body; place the tubular fiber prefabricated body in the graphite outer mold ( Holes with a diameter of 2-3mm are evenly distributed on the mold wall of the graphite outer mold), and then the mandrel is pulled out, and a pyrolytic carbon interface with a thickness of 150 ± 20nm is prepared on the tubular fiber preform by chemical vapor infiltration to form an interface containing Tubular fiber prefabricated body; remove the carbonized centrifugal paper in the core of the ...

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Abstract

The invention relates to a ceramic matrix composite slender thin-wall pipe fitting preparation method, a ceramic matrix composite slender thin-wall pipe fitting based on the method and application of the pipe fitting. The problems that existing methods cannot achieve forming of a Cf / SiC or SiCf / SiC ceramic matrix composite fiber preform with the ultra-long diameter ratio and the ultra-thin wall thickness, and a prepared Cf / SiC or SiCf / SiC ceramic matrix composite cannot meet the out-of-pile and in-pile examination requirements due to the fact that the residual porosity is large are solved. The method comprises the following steps: firstly, preparing a Cf / SiC or SiCf / SiC composite pipe fitting as a middle layer of a target pipe fitting; secondly, dipping a middle layer of the processed ceramic matrix composite thin-walled thin-walled pipe fitting into the SiC whisker slurry, and densifying; then preparing a SiC ceramic inner layer and a SiC ceramic outer layer on the inner wall and the outer wall of the middle layer of the compact ceramic-based composite thin-walled pipe fitting correspondingly; and finally, polishing the inner layer and the outer layer of the prepared pipe fitting. The pipe fitting prepared by the method is relatively high in air tightness, and meets the related examination application requirements of a fuel cladding pipe for a gas cooled reactor and a fuel cladding pipe for a pressurized water reactor.

Description

technical field [0001] The invention provides a ceramic-matrix composite material slender thin-walled pipe fitting and a preparation method thereof, in particular to a three-layer composite structure C f / SiC or SiC f / SiC ceramic matrix composite pipe fittings and its preparation method and application. Background technique [0002] Among various types of nuclear reactors, modular high-temperature gas-cooled reactors have extremely high economic competitiveness in small and medium-sized unit scales because of their good safety, high efficiency, and multi-purpose features. In general, the outlet temperature of the modular high-temperature gas-cooled reactor coolant (such as helium) directly determines the efficiency of the high-temperature gas-cooled reactor. The higher the coolant temperature of the reactor, the higher the power generation efficiency can be obtained. The core type of the modular high-temperature gas-cooled reactor is divided into cylindrical core and pebb...

Claims

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Application Information

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IPC IPC(8): C04B35/80C04B35/573C04B35/622G21C3/07
CPCC04B35/80C04B35/573C04B35/622G21C3/07C04B2235/6567C04B2235/94Y02E30/30
Inventor 张海昇付志强刘持栋李建章成来飞
Owner XIAN XINGUI CERAMIC COMPOSITE MATERIAL CO LTD
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