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Modified organic silicon defoaming agent and preparation method thereof

An organosilicon defoamer and modification technology, applied in separation methods, chemical instruments and methods, foam dispersion/prevention, etc., can solve the problem that the surface liquid of the defoamer is easily oxidized, reduces the defoaming and foam suppression performance, and has poor stability. and other problems to achieve the effect of ensuring stability and use effect, reducing water foam, and improving dispersion performance

Pending Publication Date: 2022-02-25
湖北兴发环保科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Increasing the solid content of the agent can increase the concentration of the agent and reduce the cost of transportation and use, but the production cost increases, the stability is poor, and obvious stratification is prone to occur, and the liquid on the surface of the defoamer is more likely to oxidize and deteriorate, which reduces the product’s durability. Defoaming and antifoaming properties
[0003] CN 104225965 A provides an organosilicon defoamer and its preparation method. The preparation process of the invention takes a long time and consumes a lot of energy, and the prepared product will have emulsion delamination and color change in the actual application process. Phenomena such as red becoming darker have an impact on its application

Method used

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  • Modified organic silicon defoaming agent and preparation method thereof
  • Modified organic silicon defoaming agent and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0029] Add 60g of simethicone oil to the beaker, under stirring (150r / min), slowly add 5g of hydrophobic fumed silica, and after stirring for 1 hour, add 35.5g of high boiling silicone oil to make a silicone paste. After raising the temperature to 120° C., the temperature was kept for 3 hours. After the temperature drops to 40°C, add Span-Tween mixed emulsifier (17.5g each of Span-80 and Tween-80), and after stirring for 30 minutes, continue to add polyvinyl alcohol aqueous solution (dissolve 16.5g polyvinyl alcohol in 200g deionized water), 0.5g sodium citrate and 150g deionized water, and emulsified for 2 hours under stirring at 2500r / min to obtain silicone defoamer I.

Embodiment 2

[0031] Add 60g of simethicone to the beaker, and slowly add 2.5g of hydrophobic fumed silica and 2.5g of hydrophilic fumed silica under stirring (150r / min), and then add 35.5g of fumed silica after stirring for 1 hour High-boiling silicone oil is used to make silicone paste, and the temperature of the silicone paste is raised to 120°C and then kept for 3 hours. After the temperature drops to 40°C, add Span-Tween mixed emulsifier (17.5g each of Span-80 and Tween-80), and after stirring for 30 minutes, continue to add polyvinyl alcohol aqueous solution (dissolve 16.5g polyvinyl alcohol in 200g deionized water), 0.5g of sodium citrate and 150g of deionized water, and emulsified for 2 hours under stirring at 2500r / min to obtain silicone defoamer II.

Embodiment 3

[0033] Add 80g of simethicone oil to the beaker, under stirring (200r / min), slowly add 5g of hydrophobic fumed silica and 2g of hydrophilic fumed silica, stir for 1 hour, then add 50g of high boiling silicone oil Make a silicone paste, heat the silicone paste to 120°C and keep it warm for 4 hours. After the temperature drops to 40°C, add Span-Tween mixed emulsifier (20g Span-80 and 24g Tween-80), and after stirring for 30 minutes, continue to add polyvinyl alcohol aqueous solution (dissolve 16.5g polyvinyl alcohol in 200g deionized water), 0.5g sodium citrate, 0.5g ascorbic acid, and 200g deionized water, and emulsified for 1 hour under stirring at 2500r / min to obtain silicone defoamer III.

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Abstract

The invention relates to a modified organic silicon defoaming agent and a preparation method thereof. The modified organic silicon defoaming agent comprises the following components in parts by weight: 0.5-1% of fumed silica, 10-30% of dimethyl silicone oil, 5-25% of high-boiling silicone oil, 5-15% of an emulsifier, 2-5% of a thickener, 0.1-0.5% of a stabilizer and 40-80% of deionized water. According to the invention, the production cost of the produced modified organic silicon defoaming agent is reduced and the stability and the use effect of the produced defoaming agent are improved by adjusting the type and the addition amount of the fumed silica (white carbon black) and the types and the addition modes of additives. Impurities such as nitrogen and phosphorus are not introduced; and meanwhile, water body foam is reduced, and a long-term foam inhibition effect is provided. Meanwhile, the solid content of the produced defoaming agent is high, and transportation and use of the defoaming agent are facilitated.

Description

technical field [0001] The invention relates to a modified organosilicon defoamer and a preparation method thereof, which is mainly used for defoaming liquids in industrial production, and can also be used for defoaming liquids such as sewage. While impurities such as nitrogen and phosphorus are not introduced, Reduce water foam and provide long-term anti-foam effect. Background technique [0002] Silicone defoamer can not only remove the foam on the liquid surface of the process medium in the production process, but also inhibit the generation of water foam, thereby improving the separation, gasification, effects such as drainage. In the actual production process, it is necessary to further reduce costs and improve production efficiency to increase the competitiveness of products. Increasing the solid content of the agent can increase the concentration of the agent and reduce the cost of transportation and use, but the production cost increases, the stability is poor, and...

Claims

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Application Information

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IPC IPC(8): B01D19/04
CPCB01D19/0409
Inventor 郑巍李永刚袁木平刘舜杨超龙张波崔建宇屠宏飞
Owner 湖北兴发环保科技有限公司
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