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Refining process for obtaining solid Al2O3 inclusions

A kind of inclusion and solid-state technology, which is applied in the manufacture of converters, etc., can solve the problems of excessive Ds inclusions and Ca in easy-to-reduce slag, and achieve the effect of ensuring purity

Inactive Publication Date: 2022-03-01
ZENITH STEEL GROUP CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In aluminum deoxidized steel, calcium aluminate with low melting point is easily formed, which causes the problem of excessive Ds inclusions
Control the inclusions into solid Al before the end of refining 2 o 3 It has become the subject of current research. In the prior art, generally by controlling the timing of alloy addition and the basicity of slag, the Al 2 o 3 The purpose of transforming inclusions into calcium aluminate is to realize the Al in steel before the end of refining. 2 o 3 However, this method is to add Al block after the furnace for deoxidation. During the refining process, Al is easy to reduce Ca in the slag, especially when the intensity of argon gas stirring is high, resulting in the end of refining. Inclusions transform to calcium aluminate, not all Al can be obtained 2 o 3 or Al 2 o 3 and a small amount of MgO inclusions

Method used

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  • Refining process for obtaining solid Al2O3 inclusions
  • Refining process for obtaining solid Al2O3 inclusions
  • Refining process for obtaining solid Al2O3 inclusions

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] Converter blowing is completed, tapping temperature is 1635°C, tapping S: 0.012%, and 605kg of silicomanganese, 180kg of ferrosilicon, 562kg of ferromanganese, 320kg of recarburizer, 500kg of lime and 250kg of fluorspar are added sequentially from tapping 30s, and tapping The time is 5 minutes, and samples are taken after tapping.

[0025] Adjust the argon flow rate to 60L / min before refining and heating up, and measure the temperature at 1535°C. During the heating process, add 100kg of lime to make slag, and add 120kg of calcium carbide to deoxidize the slag surface. When the molten steel temperature is 1602°C, stop heating and feed it at one time 300m aluminum wire, after feeding the Al wire, the molten steel is transferred to RH for vacuum treatment, and the composition of the slag after refining is shown in Table 1 (unit / %).

[0026] Table 1

[0027]

[0028] Al inclusions before RH treatment 2 o 3 ,Such as figure 1 shown.

[0029] RH boost gas flow 70m 3 / ...

Embodiment 2

[0035] Converter blowing is over, tapping temperature is 1628°C, tapping S: 0.015%, and 760kg silicomanganese, 270kg ferrosilicon, 100kg recarburizer, 500kg lime and 200kg fluorspar are added sequentially from tapping 30s, tapping time is 4.5min, Samples were taken after tapping.

[0036] Adjust the argon flow rate to 50L / min before refining and heating up, and measure the temperature at 1548°C. During the heating process, add 50kg of lime to make slag, and add 80kg of calcium carbide to deoxidize the slag surface. When the molten steel temperature is 1618°C, stop heating and feed it at one time 180m aluminum wire, after feeding the Al wire, the molten steel is transferred to RH for vacuum treatment, and the composition of the slag after refining is shown in Table 2 (unit / %).

[0037] Table 2

[0038]

[0039] Al inclusions before RH treatment 2 o 3 ,Such as figure 2 shown.

[0040] RH lift gas flow 80m 3 / h, vacuum treatment for 20min, feeding 40m calcium wire for t...

Embodiment 3

[0046] Converter blowing is over, tapping temperature is 1645°C, tapping S: 0.009%, 1320kg silicomanganese, 1610kg ferromanganese, 80kg recarburizer, 500kg lime and 150kg fluorite are added sequentially from tapping 30s, tapping time is 4min, tapping Samples were taken after the steel was finished.

[0047] Adjust the argon flow rate to 55L / min before refining and heating up, and measure the temperature at 1525°C. During the heating process, add 100kg of lime to make slag, and add 120kg of calcium carbide to deoxidize the slag surface. When the molten steel temperature is 1606°C, stop heating and feed it at one time 300m aluminum wire, after feeding the Al wire, the molten steel is transferred to RH for vacuum treatment, and the composition of the slag after refining is shown in Table 3 (unit / %).

[0048] table 3

[0049]

[0050] Al inclusions before RH treatment 2 o 3 ,Such as image 3 shown.

[0051] RH lift gas flow 90m 3 / h, vacuum treatment for 25min, feeding 30...

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Abstract

The invention relates to a refining process for obtaining solid Al2O3 inclusions, which comprises the following steps of: controlling the addition of a deoxidizing agent in a converter tapping process, namely, not adopting aluminum deoxidization, and adopting silicon-manganese alloy and calcium carbide to carry out post-converter deoxidization, adjusting other chemical components except Al element in the components after tapping in place during tapping, and controlling the alkalinity of refining slag to be between 1.0 and 3.0; and in the refining heating process, the argon flow of ladle bottom blowing is controlled, the argon flow is smaller than 100 L / min, after the temperature of the molten steel meets the requirement, the Al content is adjusted in place at a time through an aluminum wire, so that solid Al2O3 inclusions are obtained, and the molten steel is transferred to an RH vacuum tank to be treated. According to the BOF-LF-RH-CC technological process production process adopted for the aluminum-containing steel, inclusions are controlled to be solid Al2O3 in the LF refining procedure, generation of low-melting-point calcium aluminate before the LF refining procedure is finished is effectively controlled, the Al2O3 inclusions are efficiently removed through RH vacuum, and it is guaranteed that the cleanliness of molten steel is high, and the inclusions are few.

Description

technical field [0001] The invention relates to the technical field of steelmaking, in particular to a method for obtaining solid Al 2 o 3 Refining process of inclusions. Background technique [0002] The Al element in aluminum-killed steel not only acts as a deoxidizer in the smelting process, but also refines the grains and improves the properties of the steel. In the production process of aluminum killed steel, the solid Al produced by aluminum deoxidation 2 o 3 It is easy to float and remove, especially in the process of vacuum treatment. A large number of studies have shown that Al 2 o 3 The removal efficiency of inclusions is extremely high. But in the smelting process, it is difficult to control the inclusions in the steel into solid Al 2 o 3 , especially during the refining process, calcium-containing alloys promote solid Al 2 o 3 The transformation of inclusions to calcium-aluminate inclusions and the reaction of slag-steel lead to the reduction of CaO in ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C21C5/28C21C7/06C21C7/10C22C38/02C22C38/04C22C38/06
CPCC21C5/28C21C7/06C21C7/10C22C38/06C22C38/04C22C38/02
Inventor 屠兴圹徐建飞秦福同苏振伟周淼赵赟
Owner ZENITH STEEL GROUP CORP
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