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Preparation method and application of iron-loaded bentonite

A technology of bentonite and iron salt, applied in chemical instruments and methods, alkali metal oxides/hydroxides, inorganic chemistry, etc., can solve the problems of poor decolorization effect and difficult separation of bentonite, and solve the problems of solid-liquid separation and recovery , The effect of reducing the production cycle and reducing the production cost

Pending Publication Date: 2022-03-18
SHANDONG LUKANG ZHONGHE ENVIRONMENTAL PROTECTION TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Aiming at the above technical problems such as poor decolorization effect and difficult separation of powdered bentonite, the present invention provides a preparation method and application of iron-loaded bentonite. The prepared bentonite is in granular form, has good decolorization effect, and is easy to apply and easy to separate

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  • Preparation method and application of iron-loaded bentonite
  • Preparation method and application of iron-loaded bentonite

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Experimental program
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Effect test

Embodiment 1

[0022] The preparation method of the iron-loaded bentonite described in the present embodiment may further comprise the steps:

[0023] Step 1: Dry the natural bentonite mined in the mine at 85°C to a moisture content of 18%, grind it with a mill, and sieve it through an 80-mesh sieve to remove impurities;

[0024] Step 2: Add the sieved bentonite to sulfuric acid solution (mass fraction 10%), heat up to 75°C, stir for 4 hours and then cool to room temperature naturally, then adjust the activation solution to neutrality with alkali solution, the mass ratio of bentonite to sulfuric acid solution 1:0.5;

[0025] Step 3: Add ferric chloride solution (mass fraction 25%) into the activated bentonite, stir evenly, soak at room temperature for 9 hours, the ratio of ferric chloride solution to bentonite is 0.9ml:0.7g;

[0026] Step 4: add binder, binder addition is 1.8 times of bentonite quality, after mixing, become plastic solid material, binder selects carboxymethyl cellulose sodi...

Embodiment 2

[0029] The preparation method of the iron-loaded bentonite described in the present embodiment may further comprise the steps:

[0030] Step 1: Dry the natural bentonite mined in the mine at 85°C to a moisture content of 20%, grind it with a mill, and sieve it through an 80-mesh sieve to remove impurities;

[0031] Step 2: add the bentonite after sieving to sulfuric acid solution (mass fraction 12%), heat up to 80°C, stir for 3.5h and then cool to room temperature naturally, then adjust the activation solution to neutral with alkali solution, the quality of bentonite and sulfuric acid solution The ratio is 1:0.4;

[0032] Step 3: Add ferric chloride solution (mass fraction 25%) into the activated bentonite, stir evenly, soak at room temperature for 9 hours, the ratio of ferric chloride solution to bentonite is 0.9ml:0.8g;

[0033] Step 4: add binder, the amount of binder added is 1.8 times of the quality of bentonite, after mixing, it becomes a plastic solid material, and the...

Embodiment 3

[0036] The preparation method of the iron-loaded bentonite described in the present embodiment may further comprise the steps:

[0037] Step 1: Dry the natural bentonite mined in the mine at 85°C to a moisture content of 20%, grind it with a mill, and sieve it through an 80-mesh sieve to remove impurities;

[0038] Step 2: Add the sieved bentonite to sulfuric acid solution (mass fraction 15%), heat up to 85°C, stir for 3 hours and then cool to room temperature naturally, then adjust the activation solution to neutral with alkali solution, the mass ratio of bentonite to sulfuric acid solution is 1:0.3;

[0039] Step 3: Add ferric chloride solution (30% by mass) into the activated bentonite, stir evenly, soak at room temperature for 9 hours, the ratio of ferric chloride solution to bentonite is 0.7ml:1g;

[0040] Step 4: add binder, the amount of binder added is twice the mass of bentonite, after mixing, it will become a plastic solid, and the binder is a mixture of sodium carb...

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Abstract

The invention relates to the technical field of materials for wastewater treatment, in particular to a preparation method and application of iron-loaded bentonite, and the preparation method comprises the following steps: putting bentonite into an acid solution for activation, then putting into an iron salt solution for soaking, taking out after soaking, adding an adhesive for mixing, and finally mechanically extruding into a granular finished product to obtain the iron-loaded bentonite. The bentonite prepared by the method is granular, good in decoloring effect, easy to apply and convenient to separate, and the preparation method avoids the damage of a high-temperature calcination process in the prior art to a layered structure of the bentonite, reduces the production cost and shortens the production cycle.

Description

technical field [0001] The invention relates to the technical field of waste water treatment materials, in particular to a preparation method and application of iron-loaded bentonite. Background technique [0002] Bentonite is a non-metallic mineral with montmorillonite as the main mineral component. Due to the layered structure formed by the montmorillonite unit cell, there are some cations, such as Cu, Mg, Na, K, etc. These cations are related to the montmorillonite unit cell. The effect is very unstable and is easily exchanged by other cations, so it has a good ion exchange effect. It is a non-metallic mineral with the advantages of large specific surface area and good dispersion performance. It has strong adsorption capacity for pollutants. In recent years Bentonite is widely used in the adsorption treatment of organic pollutants and heavy metals in industrial wastewater. [0003] Bentonite is a good iron adsorbent. It can achieve the purpose of loading iron and improve...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J20/12B01J20/32B01J20/30B01J20/28C02F1/28
CPCB01J20/12B01J20/0229B01J20/3204B01J20/2803B01J20/28019C02F1/281
Inventor 胡保平刘振梁张先锋高敏邵珍珍高田
Owner SHANDONG LUKANG ZHONGHE ENVIRONMENTAL PROTECTION TECH