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Preparation method of structure color developing material with uniform color generation and low angle dependence

A low-angle, dependent technology, applied in the direction of surface coating liquid devices, coatings, special surfaces, etc., can solve the problems of uneven particle deposition, uniform color distribution, etc., to achieve uniform color rendering, improved saturation, The effect of safe and non-toxic preparation process

Pending Publication Date: 2022-04-01
TIANJIN UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The purpose of the present invention is to solve the problems of color uniformity and angle dependence of structural chromogenic materials, so as to find suitable preparation conditions and processes to promote the prepared structural chromogenic materials to exhibit uniform color and low angle dependence. Features, that is to say, to solve the uniformity of color distribution caused by the uneven deposition of colloidal particles in the process of preparing structural chromogenic materials and the angular dependence of structural colors in the visible light band under different viewing angles, this paper The invention provides a complex composite particle coated with a specific substance on the surface of specially modified nano-microspheres to form a protruding structure with random discrete distribution of irregular shapes on the surface, and then through specific assembly and combination Preparation method of multi-layer structure color-developing material with uniform color and low angle dependence characteristics by other medium and process

Method used

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  • Preparation method of structure color developing material with uniform color generation and low angle dependence
  • Preparation method of structure color developing material with uniform color generation and low angle dependence
  • Preparation method of structure color developing material with uniform color generation and low angle dependence

Examples

Experimental program
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Effect test

Embodiment 1

[0042] Step 1: Use the improved Product D was prepared by adding 4ml tetraethyl orthosilicate into 42ml dehydrated ethanol, stirring to make it evenly mixed to make a colorless and transparent solution A; Mix 35ml of deionized water, stir to make it evenly mixed, and make a colorless and transparent solution B; mix solution A and solution B and let it stand, until the mixed solution appears milky white, then stir at 45°C at 2300 rpm The reaction was stirred at a rotating speed for 4.5 hours to obtain a uniformly mixed reaction product (milky white solution); the reaction product was cooled to room temperature, then centrifuged (centrifugation speed was 6000 rpm, centrifugation time was 20min), and the supernatant was poured off to obtain the product C: Centrifuge the product C with ethanol and deionized water respectively (centrifugation speed is 6000 rpm, centrifugation time is 20min), pour off the supernatant, repeat this process 2 times, and obtain silica precipitate prod...

Embodiment 2

[0050] Step 1: Use the improved Product D was prepared by adding 2ml of tetraethyl orthosilicate to 40ml of absolute ethanol, stirring to make it evenly mixed to make a colorless and transparent solution A; 4ml of 25%-28% ammonia, 45ml of absolute ethanol Mix 35ml of deionized water, stir to make it evenly mixed, and make a colorless and transparent solution B; mix solution A and solution B and let it stand, until the mixed solution appears milky white, then stir at 40°C at 2000 rpm The reaction was stirred at a rotating speed for 4 hours to obtain a uniformly mixed reaction product (milky white solution); the reaction product was cooled to room temperature, and then centrifuged (centrifugal speed was 8000 rpm, centrifugation time was 20min), and the supernatant was poured off to obtain product C The product C is centrifuged with ethanol and deionized water respectively (centrifugal speed is 6000 rpm, centrifugation time is 20min), pours off the supernatant, repeats this proce...

Embodiment 3

[0058] Step 1: Use the improved Product D was prepared by adding 3ml tetraethyl orthosilicate to 40ml dehydrated ethanol, stirring to make it evenly mixed to make a colorless and transparent solution A; Mix 30ml of deionized water, stir to make it evenly mixed, and make a colorless and transparent solution B; mix solution A and solution B and let it stand, until the mixed solution appears milky white, then stir at 40°C at 1800 rpm The reaction was stirred at a rotating speed for 4 hours to obtain a uniformly mixed reaction product (milky white solution); the reaction product was cooled to room temperature, and then centrifuged (centrifugal speed was 6000 rpm, centrifugation time was 20min), and the supernatant was poured off to obtain product C ; The product C is centrifuged with ethanol and deionized water respectively (centrifugal speed is 6000 rpm, centrifugation time is 20min), pours off the supernatant, repeats this process 2 times, and obtains a silica precipitate ; Dr...

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Abstract

The invention provides a preparation method of a uniform-color-generation low-angle-dependence structure color development material, and belongs to the technical field of preparation of structure color development materials. The problem of color distribution uniformity caused by non-uniform particle deposition in the process of forming the structural color developing material by colloidal particles and the problem of angle dependence of the presented structural color at different visual angles are solved. According to the method, the surface of a modified silicon dioxide special structure is coated with a specific substance, composite particles with irregular-shape protruding structures distributed randomly and discretely are prepared, and then the composite particles are combined with a transparent medium to form the structure color developing material with uniform color generation and low angle dependence. The structural color developing material prepared by the method has the characteristics of uniform color distribution, good color developing effect and low angle dependence, and can be applied to the fields of decoration, display, pigments, 3D printing coloring, printing, anti-counterfeit labels and the like.

Description

technical field [0001] The invention belongs to the technical field of preparation of structural chromogenic materials, and in particular relates to a preparation method of structural chromogenic materials with uniform color and low angle dependence. Background technique [0002] Structural color is a special color phenomenon produced by interference and diffraction between micro-nano-scale physical structures and light. Its unique structural color rendering characteristics and special structural color effects make it widely used in printing, textile, color reproduction and other fields. application value. According to the visual characteristics of the human eye, structural colors are usually divided into iridescent colors and non-iridescent colors. The structural color of iridescent color is angle-dependent, and it will change significantly with the change of viewing angle, which limits its application in the field of wide viewing angle; non-iridescent structural color has...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B05D5/06C08J7/04C08L23/28C08L27/16
Inventor 陈永利朱富林钟京昊王雪平
Owner TIANJIN UNIV OF SCI & TECH
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