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Toughening agent with core-shell structure as well as preparation method and application of toughening agent

A technology of core-shell structure and toughening agent, which is applied in the field of core-shell structure toughening agent and its preparation, can solve the problems of reducing the mechanical properties of polydicyclopentadiene materials, achieve increased adhesion, improve impact resistance, Improve the effect of interfacial stress transfer

Pending Publication Date: 2022-04-05
GUANGDONG JUHANG INST FOR ADVANCED MATERIALS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Polydicyclopentadiene is usually toughened and modified by adding rubber and elastomers. When this type of modification method is toughened, part of the strength and heat resistance must be sacrificed, thus greatly reducing the mechanical properties of polydicyclopentadiene materials.

Method used

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  • Toughening agent with core-shell structure as well as preparation method and application of toughening agent
  • Toughening agent with core-shell structure as well as preparation method and application of toughening agent
  • Toughening agent with core-shell structure as well as preparation method and application of toughening agent

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Embodiment 1-5

[0035] Examples 1-5 are respectively examples of the core-shell structure toughening agent of the present invention. The preparation method of embodiment 1-5 toughening agent is: (1) heat treatment sepiolite at 250 DEG C for 4 hours, dry and also make it partly remove crystallization water at the same time, free moisture content is not higher than 0.2%; (2) Activation of sepiolite: use methanol as solvent, add sepiolite and ultrasonically stir at 55°C for 45 minutes, cool down to 45°C, add tris(2-hydroxyethyl)isocyanurate and methyl ethyl ketone peroxide to react for 2h, and dissolve the reaction solution Direct rotary steaming and drying, the obtained solid product is milled to obtain activated sepiolite particles with a particle size of 10-15 μm; (3) Preparation of the middle layer: stir the activated sepiolite particles with a small amount of styrene, and then add Cyclohexanone peroxide and hydroxyl-terminated butadiene were stirred evenly and then reacted at 140-145°C for ...

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Abstract

The invention discloses a core-shell structure flexibilizer as well as a preparation method and application thereof, and belongs to the field of high polymer materials. The toughening agent disclosed by the invention is of a three-layer core-shell structure comprising an inner core, a middle layer and an outer layer, the inner core is prepared from the following raw materials: sepiolite, tris (2-hydroxyethyl) isocyanurate and methyl ethyl ketone peroxide; the preparation raw materials of the middle layer comprise styrene, cyclohexanone oxide and hydroxyl-terminated butadiene; the outer layer is prepared from the following raw materials: N, N-dimethylaniline, norbornene-5, 6-cis-dicarboxylic anhydride and xylene. The toughening agent comprises a three-layer core-shell structure and has good bonding force with the polydicyclopentadiene resin, and the rigid core-shell structure provides good toughness for the resin and maintains the rigidity of the resin. When the toughening agent is applied to modification of a polydicyclopentadiene resin material, the mechanical property of the material is obviously improved.

Description

technical field [0001] The invention belongs to the field of polymer materials, and in particular relates to a toughening agent with a core-shell structure and a preparation method and application thereof. Background technique [0002] Polydicyclopentadiene is a new type of high-performance engineering plastic, which is formed by ring-opening metathesis of cyclopentadiene. It has excellent mechanical properties, electrical properties, corrosion resistance and easy decoration properties. It has become a polymer Research hotspots in the field of materials. The material can be flexibly designed according to the structure, so it can be used in a wide range of fields, including automobiles, sports equipment, medical equipment, etc. Although the overall performance of polydicyclopentadiene is better than that of common engineering plastics, with the expansion of its application range, the performance requirements for materials are gradually increasing, and the application of this...

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Application Information

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IPC IPC(8): C08F285/00C08F222/04C08L45/00C08L51/00
Inventor 甄智勇许宏武钟璐王洁湾
Owner GUANGDONG JUHANG INST FOR ADVANCED MATERIALS CO LTD