Injection type bar planting adhesive and preparation method thereof
A reinforced rubber and injection technology, applied in the field of reinforced rubber, can solve the problems affecting the durability, uniformity and compactness of epoxy resin reinforced rubber, and prone to brittle failure, so as to reduce the local brittle fracture, The effect of promoting uniform distribution and improving water aging resistance
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preparation example 1
[0050] Weigh 5kg diethylenetriamine, 13kg diethylene glycol methyl ether, 6kg bisphenol A type liquid epoxy resin and 12kg epoxy butyl oleate, add 5kg diethylenetriamine to 8kg diethylene glycol methyl ether In the process, heat to 65°C while stirring, keep stirring at constant temperature, and dropwise add bisphenol A liquid epoxy resin to the mixture, control the dropping rate at 20g / min, continue for 5h, and continue to react for 1h after the dropwise addition is completed , to obtain a diethylenetriamine-epoxy resin prepolymer, add 5kg diethylene glycol methyl ether to the prepolymer, control the temperature at 60°C, continue to add epoxy butyl oleate dropwise, and control the rate of addition to 50g / min, continue for 4h, after the dropwise addition is completed, continue to react for 30min, after the reaction is completed, the product is distilled and passivated to obtain a flexible curing agent. Repeat the above steps several times to prepare for use.
preparation example 2
[0052] Take 10kg of nano-calcium carbonate and add it to 20L of absolute ethanol, stir, and ultrasonically disperse for 30 minutes to obtain a uniform suspension. Add 1.5kg of titanate coupling agent to the suspension, mix ultrasonically for 10 minutes, raise the temperature to 60°C, and react at a constant temperature 6h, the reaction solution is separated by a high-speed centrifuge, the speed of the centrifuge is controlled at 8000r / min, and the separated product is vacuum-dried and ground to obtain the modified nano-calcium carbonate. Repeat the above steps to prepare multiple times to meet the usage.
preparation example 3
[0054] Weigh 5kgKH-550 type silane coupling agent, 0.8kg graphene, and 0.4kg dicyclohexylcarbodiimide respectively, add graphene and dicyclohexylcarbodiimide to the silane coupling agent, ultrasonically disperse for 1h, and increase Temperature to 75°C, heat preservation reaction for 12 hours, after cooling, centrifuge, wash, and vacuum-dry to obtain modified graphene; repeat the above steps to prepare multiple times to meet the use.
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