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Catalytic reaction unit and reaction distillation tower

A technology of reactive distillation column and catalytic reaction, which is applied in distillation separation, distillation liquid distribution, chemical instruments and methods, etc., can solve the problems of inability to effectively solve the separation of gas-phase reaction products in the reaction zone, etc., to improve the equilibrium conversion rate and increase the driving force. , improve the effect of selectivity

Active Publication Date: 2022-05-10
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The object of the present invention is to provide a catalytic reaction unit and a distillation tower using the reaction unit, so as to overcome the inability to effectively solve the problem of gaseous reaction products from reaction in time in the prior art. Disadvantages of zone separation, especially for the case where the gas phase product can undergo secondary reactions, efficient separation can still be carried out

Method used

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  • Catalytic reaction unit and reaction distillation tower
  • Catalytic reaction unit and reaction distillation tower
  • Catalytic reaction unit and reaction distillation tower

Examples

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Effect test

Embodiment 1

[0051] The catalytic reaction unit of the invention is used in the hydrocracking reactor of the catalytic diesel hydrocracking process, and a pre refining reactor is connected in series upstream of the cracking reactor process to remove impurities in the feed oil. The catalyst uses similar catalysts applied in industrial units. The yield of cracked gasoline fraction is 50.3%, the Ron of gasoline is 88.4, and the liquid yield is 91.4%.

[0052] Operating conditions and results:

[0053] Density of catalytic diesel 0.9464g • cm -3 , distillation range 168-370 ℃;

[0054] Hydrogen purity 99.9%;

[0055] The nitrogen content of refined oil is 70-100mg kg -3 ;

[0056] The operating pressure of catalytic distillation column is 4.0Mpa;

[0057] Number of catalyst beds of catalytic distillation column: 1;

[0058] Space time velocity of cracking liquid LHSV: 1.5h -1 ;

[0059] Hydrogen oil volume ratio: 700:1;

[0060] Average reaction temperature: 350-360 ℃;

[0061] The yield of gasoli...

Embodiment 2

[0063]The catalytic reaction unit of the invention is used in the hydrocracking reactor of the catalytic diesel hydrocracking process, and a pre refining reactor is connected in series upstream of the cracking reactor process to remove impurities in the feed oil. The catalyst uses the same kind of catalyst applied in industrial plant and is fixed on the bed with stainless steel mesh. The gasoline fraction yield of cracked product is 54.2%, the gasoline octane number Ron is 93.5, and the liquid yield is 98.1%.

[0064] Operating conditions and results:

[0065] Density of catalytic diesel 0.9464g • cm -3 , distillation range 168-370 ℃;

[0066] Hydrogen purity 99.9%;

[0067] The nitrogen content of refined oil is 70-100mg kg -3 ;

[0068] The operating pressure of catalytic distillation column is 4.0Mpa;

[0069] Number of catalyst beds of catalytic distillation column: 10;

[0070] Space time velocity of cracking liquid LHSV: 1.5h -1 ;

[0071] The load of the downcomer on the fi...

Embodiment 3

[0078] The catalytic reaction unit of the invention is used in the hydrocracking reactor of the catalytic diesel hydrocracking process, and a pre refining reactor is connected in series upstream of the cracking reactor process to remove impurities in the feed oil. The catalyst uses the same kind of catalyst applied in industrial plant and is fixed on the bed with stainless steel mesh. The yield of gasoline fraction is 55.1%, the Ron of gasoline octane number is 93.4, and the liquid yield is 98.5%.

[0079] Operating conditions and results:

[0080] Density of catalytic diesel 0.9464g • cm -3 , distillation range 168-370 ℃;

[0081] The nitrogen content of refined oil is 70-100mg kg -3 ;

[0082] The operating pressure of catalytic distillation column is 6.0MPa;

[0083] Number of catalyst beds of catalytic distillation column: 10;

[0084] Liquid space-time velocity LHSV: 1.5h -1 ;

[0085] The load of the downcomer on the first floor is designed according to the feed volume, with...

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Abstract

The present invention discloses a catalytic reaction unit and a reaction distillation column, the catalytic reaction unit comprising: catalyst bed layers for filling a solid catalyst, the upper part of the solid catalyst filled in each catalyst bed layer having an inclined surface from the second layer; the liquid phase feeding subunit is arranged on the topmost first catalyst bed layer, and liquid phase feeding is guided downwards to the first catalyst bed layer; the gas-phase feeding subunit is arranged between the upper catalyst bed layer and the lower inclined surface, and gas-phase feed of each layer upwards enters the catalyst bed layer; the gas-phase channel and the gas-phase feeding subunit are in a relatively isolated state, and a gas-phase product generated after the gas-phase feeding material and the liquid-phase feeding material react on the catalyst bed layer directly enters the gas-phase channel. According to the invention, gas-phase reaction products can be separated from a reaction zone in time, and particularly, the gas-phase products can still be efficiently separated under the condition that secondary reaction can be carried out on the gas-phase products.

Description

technical field [0001] The invention relates to the field of petrochemical industry, in particular to a catalytic reaction unit and a reactive distillation column applying the unit. Background technology [0002] Catalytic distillation originated in the field of chemical industry. It is a technology that completes the catalytic reaction and distillation operation in one container. It has many advantages, such as energy saving, high efficiency, good economy and so on. In view of the advantages brought by catalytic distillation technology, it has been relatively mature in the field of chemical industry. As early as the 1960s, American enterprises have begun to use the concept of catalytic distillation to solve the problem that it is difficult to separate mixtures containing normal olefins, isoolefins and alkanes by traditional distillation due to similar boiling points. Then, based on the characteristics of different reactions, a variety of catalytic distillation equipment came int...

Claims

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Application Information

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IPC IPC(8): B01J8/04B01D3/00
CPCB01J8/0465B01J8/0492B01D3/009B01D3/008B01J2208/00911Y02P20/10
Inventor 赵玉琢
Owner CHINA PETROLEUM & CHEM CORP
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