Application of interface molecule with multifunctional active sites
An active site, multi-functional technology, applied in the field of solar cells, can solve the problem of single action site of passivation molecules, achieve the effect of promoting large-scale and commercialization process, reducing film defects, and improving humidity stability
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Embodiment 1
[0038] Method for preparing perovskite solar cells:
[0039] The difference from the comparison example is that the following operations need to be performed before step (4):
[0040] A4 molecules were dissolved in isopropanol to prepare a modification layer solution with a concentration of 0.5 mg / mL, and then spin-coated on the perovskite film under the conditions: 5000rpm, 30s. No annealing is required after spin coating to obtain a modified layer.
[0041]
[0042] figure 1 In order to compare the current-voltage forward sweep curves of perovskite solar cells in Example 1 and Example 1, and obtain each photovoltaic parameter of the two kinds of batteries according to the figure, the results are shown in Table 1, by figure 1 It can be seen from Table 1 that the efficiency of the perovskite solar cell in Example 1 is significantly improved.
[0043] Table 1
[0044]
[0045] figure 2 In order to compare the defects of the light-absorbing layer of the perovskite so...
Embodiment 2
[0051] The difference from Example 1 is that the modified molecule A4 is replaced by A8, the concentration is 10mg / mL, the rotation speed is 6000rpm, and annealing at 25°C for 60min is required after the spin coating.
[0052]
[0053]
[0054] Figure 7 It is the current-voltage forward sweep curve of the perovskite solar cell in Example 2. It can be seen that the efficiency of the cell is 21.06%. Compared with the efficiency of the cell in the comparative example (20.83%), the device efficiency is significantly improved.
Embodiment 3
[0056] The difference from Example 1 is that the electron transport layer used in step (2) is titanium dioxide.
[0057] Figure 8 It is the current-voltage forward sweep curve of the perovskite solar cell in Example 3. It can be seen that the efficiency of the cell is 21.25%, which is significantly improved compared to the efficiency of the cell in the comparative example (20.83%).
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