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Organic solvent-resistant ink for thermal sensing ribbon, release layer and preparation method of organic solvent-resistant ink

A technology resistant to organic solvents and organic solvents, applied in the field of thermal sensing ribbons, can solve the problems of easy shedding of organic solvents and restrictions on the promotion of thermal printing, achieve good alcohol resistance, improve the resultant force of adhesion, and improve scratch resistance performance effect

Pending Publication Date: 2022-05-24
福建鸣友新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0010] The technical problem to be solved by the present invention is that in the field of heat sensitive ribbons, the problem that the ink layer printed on the base material is easy to fall off when encountering organic solvents has not been effectively solved. This shortcoming limits the promotion of thermal printing. In order to solve this technical problem, an organic solvent-resistant ink and a release layer for a heat-sensing ribbon and a preparation method are proposed. In parts by weight, the heat-sensing ribbon ink layer material includes: saturated polyester resin 35 -55 parts, 2 parts of dispersant, 10-15 parts of pigment, 40-60 parts of ternary vinyl acetate resin, 300-500 parts of butanone

Method used

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  • Organic solvent-resistant ink for thermal sensing ribbon, release layer and preparation method of organic solvent-resistant ink

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] Example 1 (The molecular weight of the saturated polyester resin used in the ink layer is 8000, and the organic solvent used in the release layer is cyclohexanone)

[0032] An organic solvent-resistant ink for a thermal sensing ribbon, a release layer, and a preparation method, the thermal sensing ribbon-resistant organic solvent ink comprises: saturated polyester resin 35 g (molecular weight 8000, Tg point 65°C), Lubricant Moisture 17000 2 g, carbon black 10 g, ternary chloroacetate resin 40 g, butanone 300 g. The matching release layer includes: 10 g of silica microspheres, 70 g of polymethyl methacrylate, 30 g of polytetrafluoroethylene wax particles, and 400 g of cyclohexanone.

[0033] A preparation method of organic solvent-resistant ink for thermal sensing ribbon and release layer, comprising the following steps:

[0034] 1) Weigh 35 g saturated polyester resin (molecular weight 8000, Tg point 65°C), 40 g ternary chloroacetate resin, 10 g carbon black, and 2 g L...

Embodiment 2

[0040] Example 2 (the molecular weight of the saturated polyester resin used in the ink layer is 10,000, and the organic solvent used in the release layer is butanone)

[0041] An organic solvent-resistant ink for a thermal sensing ribbon, a release layer, and a preparation method, the thermal sensing ribbon-resistant organic solvent ink comprises: saturated polyester resin (molecular weight 10000, Tg point 60° C.) 40 g, Lubo Moisture 17000 2 g, carbon black 11 g, ternary chloroacetate resin 45 g, butanone 400 g. The matching release layer includes: 10 g of silica microspheres, 70 g of polymethyl methacrylate, 30 g of polytetrafluoroethylene wax particles, and 400 g of methyl ethyl ketone.

[0042] A preparation method of organic solvent-resistant ink for thermal sensing ribbon and release layer, comprising the following steps:

[0043] 1) Weigh 40 g of saturated polyester resin (molecular weight 10000, Tg point 60°C), 45 g of ternary chloride resin, 11 g of carbon black, and...

Embodiment 3

[0049] Example 3 (the molecular weight of the saturated polyester resin used in the ink layer is 15,000, and the organic solvent used in the release layer is cyclohexanone and methyl isobutyl ketone)

[0050] An organic solvent-resistant ink for a thermal sensing ribbon, a release layer, and a preparation method, the thermal sensing ribbon-resistant organic solvent ink comprises: saturated polyester resin (molecular weight 15000, Tg point 89°C) 45 g, Lubo Moisture 17000 2 g, carbon black 13 g, ternary chloroacetate resin 50 g, butanone 500 g. The matching release layer includes: 10 g of silica microspheres, 70 g of polymethyl methacrylate, 30 g of polytetrafluoroethylene wax particles, 200 g of cyclohexanone and 200 g of methyl isobutyl ketone.

[0051] A preparation method of organic solvent-resistant ink for thermal sensing ribbon and release layer, comprising the following steps:

[0052] 1) Weigh 45 g saturated polyester resin (molecular weight 15000, Tg point 89°C), 50 g...

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Abstract

The invention discloses organic solvent-resistant ink for a thermal sensing ribbon, a release layer and a preparation method, and relates to the technical field of thermal sensing ribbons, the organic solvent-resistant ink comprises 35-55 parts of saturated polyester resin, 2 parts of a dispersant, 10-15 parts of a pigment, 40-60 parts of ternary vinyl chloride-vinyl acetate resin, and 300-500 parts of butanone. According to the invention, the ternary vinyl chloride-vinyl acetate resin is added into the ink, so that the prepared ink material has better adhesive force with base materials, such as coated paper and isatin. Silicon dioxide microspheres in the release layer are hard in texture, wear-resistant and high-temperature-resistant, and the scratch resistance of printed patterns is remarkably improved after the surface of the ink layer is covered with the silicon dioxide microspheres. And the release layer taking high-molecular-weight polymethyl methacrylate as a main body has a firm supporting effect on the silicon dioxide microspheres and the polytetrafluoroethylene wax particles. Besides, gaps between the silicon dioxide microspheres and the polytetrafluoroethylene wax particles are filled with the release layer main body, so that the organic solvent is difficult to permeate and contact with the ink layer, and the ink layer has good organic solvent resistance.

Description

technical field [0001] The invention relates to the technical field of thermal sensing ribbons, in particular to an organic solvent-resistant ink for thermal sensing ribbons, a release layer and a preparation method. Background technique [0002] Thermal printers use a thermal print head to print the ink layer on the thermal ribbon on the substrate materials such as Xiaoyinlong and coated paper. Thus, the pre-set two-dimensional code, bar code, and text symbol content are formed on the base material. Thermal printers are widely used in the production process of distribution invoices, clothing labels, electronic product labels, commodity packaging bags, etc., which can greatly facilitate people's lives, so they are favored by ordinary people. [0003] The thermal sensing ribbon is an organic integration of four-layer structure, namely PET base film, back coating, ink layer, and release layer. Some thermal sensing ribbons for specific substrates also add a bonding layer outs...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D11/104C09D11/106C09D133/12C09D7/61C09D7/65B41J31/05
CPCC09D11/104C09D11/106C09D133/12C09D7/61C09D7/65C09D7/70B41J31/05C08L27/18C08K7/26
Inventor 罗海翔赖肇昌喻伟伟林咸旺陈广玉罗学涛黄柳青杨远浩
Owner 福建鸣友新材料科技有限公司
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