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Platinum film with high resistance temperature coefficient and preparation method thereof

A temperature coefficient and thin film preparation technology, applied in the field of platinum thin films, can solve the problems affecting the response performance of platinum thin film resistance temperature sensors, the failure of platinum thin film resistance temperature sensors, and the decrease of resistance temperature coefficient, achieving excellent high temperature stability and weakening the agglomeration effect. , the effect of high temperature coefficient of resistance

Pending Publication Date: 2022-07-29
江苏精瓷智能传感技术研究院有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Among them, the scattering of electrons by the surface of the film and the interface with the substrate, and the scattering of electrons by defects such as impurities, grain boundaries, dislocations, and holes in the film will affect the temperature coefficient of resistance of the film, causing its temperature coefficient of resistance to decrease or Unstable, affecting the response performance of platinum thin film resistance temperature sensor
[0004] Although platinum has good stability, at high temperatures, platinum thin films often undergo serious agglomeration behavior, pinholes will appear in the thin film, and the pinholes that continue to grow will turn into holes, which will affect the response of platinum thin film resistance temperature sensors Performance, the pores continue to grow and even make the film completely rupture after contacting each other, resulting in the failure of the platinum thin film resistance temperature sensor

Method used

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  • Platinum film with high resistance temperature coefficient and preparation method thereof
  • Platinum film with high resistance temperature coefficient and preparation method thereof
  • Platinum film with high resistance temperature coefficient and preparation method thereof

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preparation example Construction

[0065] On the other hand, the present invention provides a preparation method of the above-mentioned platinum thin film, comprising the following steps:

[0066] S1. Provide a ceramic substrate, and deposit an oxygen-containing platinum film on the ceramic substrate.

[0067] S2, heat-treating the above-mentioned thin film to cause thermal decomposition, agglomeration and solid-state dehumidification of the oxygen-containing platinum thin film.

[0068] S3. Continue to deposit a metal platinum film on the above-mentioned film.

[0069] S4, heat-treating the above-mentioned thin film to obtain the desired platinum thin film.

[0070] S5. The above steps S1 and S2 can be repeated, and the steps S1, S2, S3 and S4 can be repeated until the desired platinum thin film is obtained.

[0071] In another aspect, the present invention provides another method for preparing the above-mentioned platinum thin film, comprising the following steps:

[0072] S1. Provide a ceramic substrate, ...

Embodiment 1

[0080] The present embodiment provides a method for preparing a platinum thin film with high temperature coefficient of resistance and excellent high temperature stability, comprising the following steps:

[0081] S1. Provide a ceramic substrate 1, and deposit a layer of oxygen-containing platinum film 2 on the ceramic substrate, such as figure 1 shown.

[0082] S2, heat treatment of the oxygen-containing platinum thin film 2, so that the oxygen-containing platinum thin film undergoes thermal decomposition, agglomeration and solid-state dehumidification to obtain a thin film 3, such as figure 2 shown. In this step, the metal platinum precipitated when the oxygen-containing platinum film is thermally decomposed will also undergo agglomeration and solid-state dehumidification during the heat treatment process. The agglomeration and solid-state dehumidification process has a certain selection effect. Absorbing" and "merging" platinum that has poor adhesion to the substrate, an...

Embodiment 2

[0086] This embodiment provides another method for preparing a platinum thin film with high temperature coefficient of resistance and excellent high temperature stability, comprising the following steps:

[0087] S1. Provide a ceramic substrate 1, and deposit a layer of oxygen-containing platinum film 2 on the ceramic substrate, such as Figure 5 shown.

[0088] S2, deposit a layer of metal platinum film 4 on the above-mentioned oxygen-containing platinum film 2, such as Image 6 shown.

[0089] S3, heat treatment of the oxygen-containing platinum film 2 and the metal platinum film 4 to obtain a platinum film with high temperature coefficient of resistance and excellent high temperature stability, such as Figure 7 shown.

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Abstract

The invention relates to the technical field of film preparation, in particular to a platinum film with a high resistance temperature coefficient and a preparation method thereof. An oxygen-containing platinum thin film layer is deposited on an aluminum oxide substrate, the binding force between the platinum thin film and the aluminum oxide substrate is improved through the thermal decomposition, agglomeration and solid-state dehumidification processes of the oxygen-containing platinum thin film layer in the subsequent heat treatment process, meanwhile, isolated platinum mass points formed through thermal decomposition of the oxygen-containing platinum thin film serve as nucleation points, and the nucleation efficiency of the platinum thin film is improved. Recrystallization and grain growth of the subsequently deposited platinum film are promoted, and the platinum film with high resistance temperature coefficient and excellent high-temperature structural stability can be obtained after heat treatment. The prepared platinum film is high in resistance temperature coefficient, good in high-temperature structural stability and simple in structure and process, other metal layers or insulating layers do not need to be introduced to serve as adhesion layers or transition layers, the method is effective, economical and practical, and the prepared platinum film has wide application prospects in the field of high-temperature platinum film sensors.

Description

technical field [0001] The invention relates to a platinum film, in particular to a high temperature coefficient of resistance platinum film and a preparation method thereof. Background technique [0002] Platinum has good high temperature oxidation resistance and good resistance-temperature linear relationship in a wide temperature range, and has a wide range of applications in resistance temperature sensors, resistance bodies, heaters, electrodes, etc. Compared with the traditional wire-wound platinum resistance temperature sensor, the thin-film platinum resistance temperature sensor has the advantages of small size, fast response, low cost, and easy integration, and has gradually replaced the wire-wound platinum resistance temperature sensor. However, thin-film platinum resistance temperature sensors usually face problems such as low resistance temperature coefficient and poor high-temperature stability. Compared with other high-temperature temperature sensors such as the...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23C14/18C23C14/58C23C16/06C23C16/56
CPCC23C14/185C23C14/5806C23C14/5853C23C16/06C23C16/56
Inventor 蒲健陈茂冯江涛池波
Owner 江苏精瓷智能传感技术研究院有限公司
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