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Method for micro-arc depositing ceramic layer onto positive and negative bipolarities on magnesium alloy

A technology of micro-arc electrodeposition and magnesium alloy, which is applied in the direction of anodic oxidation, electrolytic inorganic material coating, etc., can solve the problems of high production cost and large power consumption, achieve high production efficiency, reduce power consumption, and reduce energy consumption. Effect

Inactive Publication Date: 2005-11-09
UNIV OF SCI & TECH BEIJING
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] The present invention aims at the problems of high power consumption and high production cost in the above-mentioned micro-arc oxidation treatment on the surface of magnesium alloys, and proposes that magnesium alloy workpieces are used for both cathode and anode bipolar poles, and ceramics are deposited by micro-arc electrodeposition on the surface of magnesium alloys by using symmetrical AC pulse voltage. layer, not only can obtain a coating with good performance, but also the process and equipment are simple, and the work efficiency is high

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  • Method for micro-arc depositing ceramic layer onto positive and negative bipolarities on magnesium alloy
  • Method for micro-arc depositing ceramic layer onto positive and negative bipolarities on magnesium alloy
  • Method for micro-arc depositing ceramic layer onto positive and negative bipolarities on magnesium alloy

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Embodiment Construction

[0022] Using a bidirectional full-wave pulsed micro-arc oxidation power supply, connect the magnesium alloy specimen to the positive and negative poles of the power supply respectively. The entire technological process is: sample grinding, cleaning, degreasing, connecting wires electrified, micro-arc oxidation, cleaning the sample, and drying.

[0023] Taking AZ91D cast magnesium alloy as an example, the optimal scheme of cathode and anode bipolar micro-arc electrodeposition on the surface of magnesium alloy obtained by orthogonal optimization of electrolyte parameters and electrical parameters is as follows:

[0024] Na 2 SiO 3 9H 2 O 15g / L

[0025] NaOH 5g / L

[0026] h 3 BO 3 3g / L

[0027] CeF 4 ·H 2 O 1g / L

[0028] pH 12~13

[0029] Frequency 50Hz

[0030] Duty cycle 0.5

[0031] Time 60min

[0032] Voltage 220V

[0033] figure 2 and image 3 The structure and morphology of the cathode and anode AZ91D cast magnesium alloy micro-arc ceramic lay...

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Abstract

A technology for electrically depositing a ceramic layer on the surface of Mg alloy with the microarc between cathode and anode is disclosed. The pretreated Mg-alloy workpiece is connected respectively to the positive and negative electrodes of a high-power full-wave pulse power supply and then put in the alkaline electrolyte prepared from deionized water and sodium silicate. The cathode and anode of the electrolyzer are Mg-alloy workpiece. The symmetrical AC pulse voltage is used for the microarc depositing on the surface of Mg-alloy workpiece. The output voltage of power supply is continuously raised up with the progress of microarc oxidizing. Its advantages are less heat and energy consumption, low cost, and high effect and productivity.

Description

Technical field: [0001] The invention relates to a surface coating coating technology, in particular to a method for micro-arc electrodepositing a ceramic layer on an alloy surface. Background technique: [0002] Magnesium is the lightest metal material in engineering materials (density is 1.74g / cm 3 ), its alloys with aluminum, zinc, molybdenum, zirconium and other elements are widely used in automobiles, electronic aviation and other fields due to their excellent physical and mechanical properties. However, the chemical properties of magnesium are very active (the equilibrium potential is -2.34V), and its natural oxide film is loose and porous, which cannot form a good protective effect on the substrate, resulting in poor corrosion resistance of magnesium and its alloys, which seriously restricts the corrosion resistance of magnesium and its alloys. Alloys are used in various industries. [0003] The ceramic layer formed on the metal surface by micro-arc oxidation treatm...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C25D5/18C25D9/04C25D11/30
Inventor 张巍李久青刘元刚
Owner UNIV OF SCI & TECH BEIJING
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