Polishing system and method of its use

An additive, selected technology for use in chemical instruments and methods, grinding/polishing equipment, polishing compositions containing abrasives, etc., to address pitting, undesirable effects, oxide corrosion, and via metal issues

Inactive Publication Date: 2002-09-18
CABOT MICROELECTRONICS CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although metal and barrier metal removal rates are usually removed with a single system, the combination of via metal and tantalum and similar materials using a conventional polishing system can cause undesirable effects such as oxide corrosion and via metal pitting

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment

[0043] The following examples further illustrate the invention, but it is obvious that they do not limit the scope of the invention in any way.

Embodiment 4

[0046] Wafer of Example 4.

[0047] The test wafer removal rate was determined by directly measuring the thickness of each test wafer before and after polishing using a Tencor(R) SurfscanUV 1050 machine with a Tencor RS-75.

[0048] Unless otherwise specified, ammonium hydroxide (NH 4 OH) All but one of the following examples (ie, Example 7) were adjusted to the target pH.

Embodiment 1

[0050] This example demonstrates that the rate of polishing of the first metal layer achievable by the system of the present invention is related to the presence and characteristics of polishing additives in the system.

[0051] Respectively with 2% by weight of alumina (especially Cabot's Semi-Sperse® W-A355 product), 1% by weight of oxidizing agent (especially H 2 o 2 ), 2.2% by weight polishing additive (particularly aminotris(methylene phosphonic acid) (i.e. Dequest® 2000 product)), or 0M, 0.037M or 0.33M ammonia (0% by weight NH 3 , about 0.06 wt% NH 3 with about 0.56 wt% NH 3 ) and 0.08% by weight of film formers (especially triazoles) in three different polishing systems (referred to as systems 1A-1C) to polish copper wafers, wherein HNO 3 or KOH to adjust the pH of each system to 8.5.

[0052] As a comparison, also with 2% by weight of alumina (especially Cabot's Semi-SperseW-A355 product), % by weight of oxidizing agent (especially H 2 o 2 ), 0.33M ammonia (ie a...

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PUM

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Abstract

The invention provides a system for polishing one or more layers of a multi-layer substrate that includes a first metal layer and a second layer comprising (i) a liquid carrier, (ii) at least one oxidizing agent, (iii) at least one polishing additive that increases the rate at which the system polishes at least one layer of the substrate, wherein the polishing additive is selected from the group consisting of pyrophosphates, condensed phosphates, phosphonic acids and salts thereof, amines, amino alcohols, amides, imines, imino acids, nitriles, nitros, thiols, thioesters, thioethers, carbothiolic acids, carbothionic acids, thiocarboxylic acids, thiosalicylic acids, hydroxylates, carbonylates, carboxylates, and acids thereof, and mixtures thereof, (iv) at least one stopping compound, and (v) a polishing pad and / or an abrasive. The invention also provides a method of polishing a substrate comprising contacting a surface of a substrate with the system and polishing at least a portion of the substrate therewith. Moreover, the invention provides a method for polishing one or more layers of a multi-layer substrate that includes a first metal layer and a second layer comprising (a) contacting the first metal layer with the system, and (b) polishing the first metal layer with the system until at least a portion of the first metal layer is removed from the substrate.

Description

field of invention [0001] The invention relates to a polishing system and a method for polishing a substrate, in particular to a method for polishing a multilayer substrate including a first metal layer and a second layer. Background of the invention [0002] Integrated circuits are fabricated from millions of active devices formed in or on a substrate such as a silicon wafer. The active devices are chemically and physically connected to a substrate and interconnected through the use of multilayer connection layers to form functional circuits. A typical multilayer interconnect includes a first metal layer, an intervening dielectric layer, and sometimes third and subsequent metal layers. Using interlayer dielectrics such as doped and undoped silicon dioxide (SiO 2 ) and / or low-k dielectrics to electrically isolate different metal layers. [0003] Metal vias are used to achieve electrical connections between different interconnect layers. For example...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B24B57/02B24D11/00C09G1/02C09K3/14H01L21/304
CPCC09G1/02H01L21/304
Inventor 王淑敏弗拉斯塔·布鲁西克考夫曼史蒂文·K·梅鲁姆宾周仁杰艾萨克·K·彻里安
Owner CABOT MICROELECTRONICS CORP
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