Low alloy steel resisting CO2 and H2S corrosion

A low-alloy steel, carbon dioxide technology, applied in the field of low-alloy steel, can solve the problems of increasing the difficulty and cost of smelting, high uniform corrosion rate of steel, and increased alloy cost, and achieves the effect of good H2S corrosion performance and major economic and social benefits.

Inactive Publication Date: 2004-04-07
BAOSHAN IRON & STEEL CO LTD
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Problems solved by technology

Not only that, the patented composition only eliminates the steel's resistance to CO due to the absence of Cu elements 2 Local corrosion phenomenon, while the uniform corrosion rate of steel is still high
In addition, the addition of B element greatly increases the difficulty and cost of steel smelting; while the Cr content in JP 2000063994 patent steel is between 3.0 and 9.0%, which belongs to th

Method used

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Embodiment Construction

[0032]Table 1 shows the chemical composition of the test steel, A1-A6 is the alloy steel of the present invention, B1-B4 is the control steel, wherein B1 and B2 are the common N80 and C90 steel pipes commonly used in oil fields at present, and B3 and B4 are respectively the comparison patents Composition of alloy steel.

[0033] As shown in Table 2, the alloy steel of the present invention conforms to the performance requirements of API 5CT of N80 grade steel through smelting, forging, rolling, suitable heat treatment and mechanical performance test, and the mechanical performance test is carried out according to GB6 397-86 standard. in CO 2 In the typical corrosion environment of Jianghan Oilfield, where the corrosion is more prominent, an autoclave corrosion simulation comparison test was carried out. The test results show that the annual corrosion rate of the alloy steel of the present invention is 5-15% lower than that of steel pipes such as N80, C90, and P110 currently us...

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Abstract

The present invention is one kind of low alloy steel capable of being used in oil well pipe to resist CO2 and H2S corrosion. Chemically, its consists of C 0.01-0.30 wt%, Si 0.10-1.0 wt%, Mn 0.10-2.0, Cr 0.50-3.0 wt%, Mo 0.01-1.0 wt%, Ce 0.01-0.25 wt%, V 0.005-0.1 wt%, Cu 0.05-1.0 wt%, Al 0.01-0.10 wt% and small amount of Nb if necessary, except Fe and inevitable impurity, with impurity elements being less than 0.05 wt%. The alloy steel of the present invention after hardening and tempering has mechanical performance reaching the requirement on API 80 and 90 level steel but obviously improved CO2 and H2S corrosion resistance, and is economic oil well pipe steel with moderate cost.

Description

technical field [0001] The invention relates to a low-alloy steel, especially low-alloy steel for carbon dioxide and hydrogen sulfide corrosion-resistant oil well pipes. Background technique [0002] CO 2 and H 2 S corrosion has been a major problem restricting the development of oil and gas fields for a long time. 2 and H 2 Ordinary carbon steel pipes or simple anti-sulfur oil well pipes are used in the S corrosion environment, which has caused many serious corrosion accidents in the oil field, resulting in economic losses and the protective measures taken for this have seriously affected the economic benefits of the oil field. [0003] At present, severe CO is common in most oilfields. 2 and H 2 S corrosion problem. And each year due to CO 2 and H 2 Accidents caused by S corrosion have brought economic losses of more than 100 million yuan to oil fields. From the perspective of anticorrosion of materials, in high CO 2 and H 2 In the highly corrosive environment f...

Claims

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Application Information

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IPC IPC(8): C22C38/24C22C38/26
Inventor 张忠铧郭金宝
Owner BAOSHAN IRON & STEEL CO LTD
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