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Production technology of ferrous sulfate vityiol from magnetite

A technology of ferrous sulfate and magnetite, applied in the field of inorganic salts, can solve the problems of unsuitability for large-scale industrial production, high impurity content of products, and high price of raw material iron filings, and achieves low raw material cost, reduced raw material cost, and low price. Effect

Inactive Publication Date: 2005-03-23
TAIYUAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
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AI Technical Summary

Problems solved by technology

[0010] The present invention is mainly aimed at the high price and limited source of raw material iron filings in the existing production process of ferrous sulfate heptahydrate, which is not suitable for large-scale industrial production, and the product has high impurity content, low grade and waste water and waste gas discharged during production. , the problem of serious environmental pollution by waste slag, and provide a process for producing ferrous sulfate heptahydrate from magnetite, which is cheap and easy to get, suitable for large-scale industrial production, and has no environmental pollution

Method used

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Embodiment Construction

[0016] Below in conjunction with embodiment the present invention is described in further detail:

[0017] Get the magnetite produced in Ekou, Shanxi as the raw material for producing ferrous sulfate heptahydrate, through mechanical crushing, ore grinding, it will be 100 mesh, and be selected into 65% ore powder with methods such as magnetic separation or flotation, and use Sulfuric acid-phosphoric acid mixed acid decomposition method and potassium dichromate volumetric method were used to determine the content of total iron and ferrous iron in Table 1:

[0018] mineral name

total iron T Fe %

FeO%

Fe 2 o 3 %

Shanxi Ekou magnetite powder

63.56

27.79

59.99

[0019] Magnetite powder and industrial sulfuric acid are raw materials to carry out the following steps successively:

[0020] (1) acid soluble

[0021] Fe in magnetite powder 3 o 4 The molar ratio with industrial sulfuric acid is 1:5, add the sulfuric acid...

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Abstract

A process for preparing FeSO4.7H2O from magnetite includes such steps as pulveriznig magntite, grinding, fine dressing, immersing in sulfuric acid, reducing, low-temp crystallizing and vacuum drying.

Description

technical field [0001] The invention belongs to the field of inorganic salts, and relates to a production process of ferrous sulfate heptahydrate, in particular to a process for producing ferrous sulfate heptahydrate by using magnetite as a raw material and adopting an acid dissolution-reduction two-step method. Background technique [0002] The production method of ferrous sulfate heptahydrate used in industry has two kinds at present: the first kind is iron filings-sulfuric acid method to produce ferrous sulfate heptahydrate, and its production technology is sulfuric acid and iron filings reaction, through precipitation, crystallization, dehydration Get ferrous sulfate. Its chemical reaction is as follows: [0003] <chemistry num="001"> <chem file="200410012473_cml001.xml" / > < / chemistry> [0004] The second is the production of ferrous sulfate heptahydrate by the titanium dioxide by-product method. The production process is to decompose ilmenite wit...

Claims

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Application Information

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IPC IPC(8): C01G49/14
Inventor 何凯邵建钢
Owner TAIYUAN UNIV OF TECH
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