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Optical film and liquid crystal display device

A liquid crystal display element, optical film technology, applied in optics, polarizing elements, nonlinear optics, etc., can solve the problems of difficult to fix liquid crystal alignment structure, amorphous, and polymer without liquid crystal.

Inactive Publication Date: 2006-04-12
NIPPON OIL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

As polyesters having a dicyclohexane structure, 1,1'-dicyclohexyl-4,4'-dicarboxylic acid and 2,2'-bis(4-hydroxyphenyl)propane (=bisphenol A ) combined polyester (US Patent No. 3,505,281 specification), the obtained polymer has no liquid crystallinity and is amorphous
In addition, polyesters composed of 1,1'-dicyclohexyl-4,4'-dicarboxylic acid and hydroquinones (JP-A-4-359015) exhibit liquid crystallinity at 200°C or are infusible, so Crystallization proceeds at a temperature below this temperature, so the alignment structure of the liquid crystal is difficult to fix
[0015] Therefore, in the prior art, the current situation is that there are no examples of development of polymer liquid crystals with small wavelength dispersion characteristics and fixed liquid crystal alignment, and there are almost no examples of research.

Method used

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Examples

Experimental program
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Effect test

Embodiment 1

[0129] Put 40mmol of 1,1'-dicyclohexyl-4,4'-dicarboxylic acid, 60mmol of terephthalic acid, 50mmol of methyl hydroquinone diacetate and 50mmol of catechol diacetate in 200ml of acetic acid The outflow was carried out in a flask with a cooling tube under a nitrogen stream at 270°C for 6 hours, and then deacetate polymerization was carried out at this temperature under a nitrogen stream of 30 ml / min for 2 hours. The obtained polymer was dissolved in tetrachloroethane, and a large amount of methanol was added to refine the polymer. The polyester has an intrinsic viscosity of 0.23 dL / g, has a nematic phase as a liquid crystal phase, an isotropic phase-liquid crystal phase transition temperature of 270°C or higher, and a glass transition point of 80°C. In addition, it was found from the results of polarizing microscope observation that the orientation of the nematic liquid crystal phase is completely fixed below the glass transition temperature.

[0130] Next, a phenol / tetrachloro...

Embodiment 2～18 and comparative example 1

[0132] The research was carried out in the same manner as in Example 1, except that the types of monomers and the addition ratio were changed. The results are shown in Table 1. In addition, the polymer of Example 2 1 H-NMR spectrum is shown in Fig. 1, the polymkeric substance of embodiment 10 1 The H-NMR spectrum is shown in FIG. 2 . All of these polyesters show a uniform nematic liquid crystal phase above the glass transition temperature, and even when cooled to below the glass transition temperature, no transition to the nematic crystal phase is confirmed, and the orientation state formed in the nematic liquid crystal phase is fixed. .

Embodiment 19

[0134]An 8% by weight phenol / tetrachloroethane (60 / 40 weight ratio) mixed solvent solution of the polyester obtained in Example 7 was prepared. This solution was spin-coated on plain glass, and dried on a hot plate at 55°C for 20 minutes. After heat-treating in a clean oven at 220° C. for 20 minutes, it was taken out from the clean oven and cooled in natural air to obtain an optical film in which the orientation state of the nematic phase was fixed. The obtained optical film was transparent and uniform without orientation defects. As a result of observing the optical film under a crossed Nicol, no in-plane retardation was observed when viewed from the front, but a retardation occurred when viewed obliquely. As a result of interferometer observation with a polarizing microscope, a cross shape was observed, and as a result of observation with a 1 / 4 wavelength plate inserted, the second and fourth quadrants were observed to be black. From the above results, it can be seen that ...

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Abstract

The present invention provides an optical film which facilitates the immobilization of liquid crystal orientation, can realize the wavelength dispersion of small birefringence, can be easily manufactured at a low cost in industrial view and can also be exactly regulated in optical characteristics, such as wavelength dispersion of the birefringence, is immobilized with the desired orientation state and can be made uniform and larger in area. The optical film is composed of polyester including a structural unit derived from 1,1'-bicyclohexyl-4,4'-dicarboxylic acid and a structural unit derived from an aromatic diol-based compound of an ortho body and is obtained by cooling the orientation state formed during the thermal orientation of the polyester to its glass transition temperature or below so as to immobilize the orientation state.

Description

technical field [0001] The invention relates to an optical film which is easy to fix liquid crystal orientation, has small wavelength dispersion of birefringence, and is suitable for application in optical elements such as retardation film, circular polarizing plate, elliptical polarizing plate and liquid crystal display device using it. Background technique [0002] Polymer liquid crystals are being actively researched and developed in the field of heat-resistant high-functional resins utilizing their high heat resistance, moldability, etc., and in the field of functional materials utilizing liquid crystal alignment. In the field of heat-resistant high-functional resins, it has been developed and commercialized in various fields such as electronic and electric parts, automobile parts, OA and AV equipment parts, and sealing materials. On the other hand, in the field of functional materials, active development and research are being carried out for applications such as optica...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G02B5/30G02F1/1335C08G63/199C08G63/60C08J5/18C08L67/02G02F1/13363
Inventor 熊谷吉弘小林正明真崎仁诗
Owner NIPPON OIL CO LTD
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