Sm Al Co system Sm base ternary block amorphous alloy

An amorphous alloy, 1.sm-al-co technology, applied in the field of Sm-Al-Co bulk amorphous alloy, can solve the problem of easy oxidative burning and volatilization, increase the cost of the alloy, and the alloy composition is easy to deviate from the amorphous composition and other problems, to achieve the effect of simple alloy composition and reducing composition deviation

Inactive Publication Date: 2006-11-29
DALIAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The disadvantages of this five-element alloy are: ①The multi-component optimization of the components is complicated, which makes it difficult to improve the performance of the alloy through component optimization on the basis of this composition, and the cost of the alloy is also increased due to the large number of components; ②In order to determine the bulk non- The composition of c

Method used

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  • Sm Al Co system Sm base ternary block amorphous alloy

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] Embodiment one, Sm 50 Al 25 co 25 Preparation of Bulk Amorphous Alloy and Its Properties Test

[0037] The first step, the weighing of the composition ratio

[0038] According to the atomic percentage in the design composition, it is converted into a weight percentage wt.%, and the pure metal Sm, Al, and Co raw materials with a purity of 99.9% are weighed in proportion for use; 2% more Sm has been added in advance for weighing. Compensation for volatilization during alloy melting;

[0039] The second step, Sm 50 Al 25 co 25 Melting of ternary alloy ingot

[0040] The mixture of Al, Co and rare earth metal Sm is placed in a water-cooled copper crucible of a non-consumable arc melting furnace, and melted under the protection of argon. First, the vacuum is evacuated to 10 -2 Pa, then filled with argon until the pressure is 0.06MPa, the melting current density range is 140A / cm 2 , after melting, continue to smelt for 10 seconds, turn off the power, let the alloy co...

Embodiment 2

[0047] Embodiment 2, Sm 58 Al 21 co 21 Preparation of Bulk Amorphous Alloy and Its Properties Test

[0048] The first step, the weighing of the composition ratio

[0049] According to the atomic percentage in the design composition, it is converted into a weight percentage wt.%, and the pure metal Sm, Al, and Co raw materials with a purity of 99.9% are weighed in proportion for use; 2% more Sm has been added in advance for weighing. compensate for its volatilization;

[0050] The second step, Sm 58 Al 21 co 21 Melting of ternary alloy ingot

[0051] The smelting method of alloy ingot adopts the method for the second step in the embodiment one to carry out; Vacuumizing is 10 -2 Pa, filled with argon gas pressure is 0.08MPa, the current density used for melting is 120A / cm 2 , repeated smelting 3 times to obtain a ternary alloy ingot with uniform composition;

[0052] The third step, Sm 58 Al 21 co 21 Composition inspection of ternary alloy ingot

[0053] The inspec...

Embodiment 3

[0060] Embodiment three, Sm 54 Al 19.8co 26.2 Bulk amorphous alloy preparation

[0061] The first step, the weighing of the composition ratio

[0062] According to the atomic percentage in the design composition, it is converted into a weight percentage wt.%, and the pure metal Sm, Al, and Co raw materials with a purity of 99.9% are weighed in proportion for use; 2% more Sm has been added in advance for weighing. compensate for its volatilization;

[0063] The second step, Sm 54 Al 19.8 co 26.2 Melting of ternary alloy ingot

[0064] The smelting method of alloy ingot adopts the method for the second step in the embodiment one to carry out; Vacuumizing is 10 -2 Pa, filled with argon gas pressure is 0.07MPa, the current density used for melting is 130A / cm 2 , repeated smelting 3 times to obtain a ternary alloy ingot with uniform composition;

[0065] The third step, Sm 54 Al 19.8 co 26.2 Composition inspection of ternary alloy ingot

[0066] The inspection method ...

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Abstract

The invention relates to Sm radical Sm-Al-Co block non-crystal alloy that the constituents range is Smx(Al50-yCo50+y)100-x(x=50-58at%, y=-10-+7at%). The best constituents is Sm50Al25Co25, The method includes the following processes: mixing, taking copper film negative pressure casting adsorbing, the argon gas pressure is 0.06-0.08MPa, fusion melting current density is 120-140A/cm2, and draught head is 0.04+0.005MPa, the diameter of the block non-crystal is 3mm. The advantages of the invention are that it conquers the random of the constituents and develops Sm radical Sm-Al-Co block non-crystal alloy. It decreases the constituent deviation of testing Sm volatilizing quantity.

Description

technical field [0001] The invention relates to a series of Sm-Al-Co bulk amorphous alloys with strong amorphous forming ability, belonging to the field of new materials. Background technique [0002] Amorphous metal alloys are a class of metals or alloys with short-range order and long-range disorder structures, and they have high comprehensive mechanical properties and unique physical and chemical properties. However, due to the influence of metal or alloy amorphous forming ability (that is, the ability to form amorphous alloy), the preparation of such materials requires a higher cooling rate, and the general critical cooling rate is 10 5 K / s. In the order of cooling speed from high to low, commonly used quenching technologies include: melt atomization, thin film deposition technology, and copper roller quenching strip machine technology. The material form is often low-dimensional materials such as powder, thin strip, etc., and its application range are therefore greatly...

Claims

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Application Information

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IPC IPC(8): C22C45/00C22C1/02
Inventor 董闯吴江王清羌建兵王英敏
Owner DALIAN UNIV OF TECH
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