37results about How to "Good Amorphous Formation Ability" patented technology

The invention relates to a preparation technology of a block zirconium-base amorphous alloy, in particular to a Zr-Cu-Ni-Al-Ag alloy with higher glass-forming ability and a preparation method thereof, and the characteristic thermodynamics parameter and the mechanical property of the alloy are characterized and tested at the same time. The alloy system is the Zr-Cu-Ni-Al-Ag alloy, which has the component ranges (by atom percentage) that Zr is 41 to 63, Cu is 18 to 46, Al is 4 to 15, Ni is 1.5 to 12.5, and Ag is 1.5 to 26. Based on a Zr-Cu-Ni-Al quaternary alloy, the forming ability of the amorphous alloy is increased through inhibiting the precipitation of a crystalline state phase. The preparation technology adopts an electric arc melting method to prepare a master alloy ingot, then adopts a copper mold casting method to prepare amorphous alloy rods with different diameters, and the alloy in the system can easily prepare amorphous round bars, the diameter of which can reach 2cm. Due to stronger amorphous forming ability and good mechanical property, the alloy has good application prospect.

The invention provides an iron base amorphous alloy expressed in a formula (I), wherein a, b, c, d and e respectively represent the atomic percentage contents of corresponding components: a is not bigger than 84.0 and not smaller than 80.5, b is not bigger than 9.0 and not smaller than 3.0, c is not bigger than 15.0 and not smaller than 8.0, d is not bigger than 0.3 and not smaller than 0.001, e is not bigger than 0.4, and the sum of a, b, c, d and e is 100; and M is an impurity element. In the iron base amorphous alloy provided by the invention, the saturation induction density of an alloy material is not lower than 1.62 T. The invention further provides a preparation method of the iron base amorphous alloy; further, the excellent soft magnetic properties can be obtained after proper heat treatment; the alloy material can be used for manufacturing iron core materials of power transformers, generators and engines; and FeaSibBcPdMe (I).

The invention discloses a strong-permanent-magnetic nano-porous Fe-Pt alloy and a preparation method thereof. The strong-permanent-magnetic nano-porous Fe-Pt alloy has the composition of FewCoxPtyPdz, is composed of an L10-FePt ordered hard magnetic phase, and has a complete doubly-connected nano-porous structure, a pore diameter of 10-50nm and a ligament thickness of 20-80nm; the coercivity, the magnetization intensity and the residual magnetism of the alloy under a 50kOe external magnetic field are 13.4-18.5kOe, 40.4-56.3 and 28.3-37.4emu / g respectively. A master alloy ingot is prepared by electric arc melting or induction melting during preparation; an alloy strip is prepared by single-roll spinning; a nano-complex-phase precursor containing hard-magnetic L10-FePt and soft-magnetic Fe2B is obtained directly or through an annealing treatment; the nano-porous Fe-Pt alloy with a single L10-FePt phase structure is obtained through an electrochemical dealloying process, thus filling up the technical gaps of a permanent-magnetic metal nano-porous material.

An iron-based amorphous alloy material with high glass-forming capability consists of the elements of Fe, Cr, Mo, C, B, Y and Co, wherein the atomic number ratio of the Fe, Cr, Mo, C, B, Y and Co are (24-32%):(16-24%):15%:14%:15%:6%:2%; the atomic number ratio of the elements of Fe, Cr, Mo, C, B, Y and Co are 24%:24%:15%:14%:15%:6%:2%; the atomic number ratio of the elements of Fe, Cr, Mo, C, B, Y and Co are 28%:20%:15%;14%:15%:6%:2%; and the atomic number ratio of the elements of Fe, Cr, Mo, C, B, Y and Co are 32%:16%:15%:14%:15%;6%:2%. The iron-based amorphous alloy material not only has a simple preparation technology, is low in cost, but also has good amorphous-forming capability and glass-forming capability, and also has mechanical properties with high strength and high hardness.

The invention relates to an amorphous alloy, the formula of which is CuaZrbMcBed, wherein the a, the b, the c and the d are mol percentages, a+b+c+d=100, a is smaller than or equal to 45 and is larger than or equal to 15, b is smaller than or equal to 50 and is larger than or equal to 10, c is smaller than or equal to 35 and is larger than or equal to 5, and d is smaller than or equal to 30 and is larger than or equal to 0; and the M is an element of transition group metal except the Cu and the Zr and is one or more than one of Al, Sn and Si. The amorphous alloy can effectively enhance the crystallization-inhibited capability of alloys, enables critical dimension to be accurate to a centimeter level and also greatly enhances the strength and the toughness. The invention also relates to a preparation method of the amorphous alloy, which has low requirement for vacuum degree and cooling rate, thereby lowering the requirement for smelting and forming equipment to enable the product to be easier to produce in commercial process.

The invention relates to Fe radical block non-crystal alloy based on F3-B-Y group cluster. It adds 2at.% Nb and 2at.% Zr or Hf or Ti or Mo or Ta on the base of Fe-B-Y ternary system to take micro alloying. The constituent interval is [(Fe12 / 13Y1 / 13)100-xBx]0.96Nb2M2, and x=15-26at.%. The method includes the following steps: mixing, melting in Fe-B internal alloy, taking negative pressure casting absorbing, the argon gas pressure is 0.06-0.08MPa, fusion melting current density is 180-220A / cm2, casting adsorbing current density is 280-310A / cm2, and draught head is 0.04+0.005MPa, the diameter of the block non-crystal is 3mm. The advantages of the invention are that it develops five Fe radical block non-crystal alloys. In the melting process, smelting Fe and B to form internal alloy, the volatilization of B would be avoided.

A CuZrNb-series non-crystal alloy block with high thermal stability, hardness and yield strength has a formular: (CuxZr1-x)1-yNby, where x=40-65 wt.% and y=1-15 wt.%.Its preparing steps include smelting pure Zr and Nb metals in non-consumable electroarc furnace under protection of argon gas, cooling, turning it over, loading in water-cooled copper crucible, smelting several times to obtain Zr(Nb) prealloy, mixing with Cu, smelting several times to obtain uniform CuZrNb alloy and negative-pressure casting with copper mould.

The invention discloses a Fe-based block noncrystal alloy and making method, which comprises the following steps: (1) allocating raw material with 48-70% Fe, 23-37% Nd, 4-10% Al and 2-6% B; (2) adopting copper mould suction adsorbing casting method to make the non-crystal alloy; (3) adding 2-8T pulse magnetic field with frequency at 0.02-0.05Hz; annealing in the vacuum under 100-350 deg.c for 10-30 min.

The present invention relates to a hard-magnetic FeZrNdYB nano bulk alloy with an alloying component (atomic percentage) as follows: Fe 56-76 percent, Zr 0.5-6 percent, Nd 2-10 percent, Y 2-8 percent and B 13-27 percent. The process is as follows: the raw materials are prepared according to the formulation and melted in a vacuumized non-consumable electroarc furnace under the protection of argon. The alloy is repeatedly melted, cast with a method of typpe matrix negative-pressure molding and a ferrous bulk amorphous alloy is obtained. The amorphous alloy is conducted with a vacuumized annealing treatment for 10-40 minutes at a temperature of 550-900 degrees Celsius system under a vacuum degree of 3 to 5 being multiply with 10-3Pa and thus a hard-magnetic FeZrNdYB nano bulk alloy is obtained with a crystal grain size of 20-70 nanometers. The maximum magnetic energy product of the alloy is 53 kilojoules per cubic meter.

Cu based Cu-Zr-Ti block amorphous alloy in new material field comprises Cu, Zr and Ti element, is characterized as: alloy general formula (Cu#-[x]Zr#-[1-x])#-[1-y]Ti#-[y], in which, 54at.%<=x<=70at.%, 54at.%<=x<=70at.%, optimum amorphous constituent:Cu#-[64]Zr#-[28.5]Ti#-[7.5]. The characters of preparation process are: non-self-consumable arc smelting of auxiliary material and alloy ingot, copper mould negative pressure casting of amorphous alloy, argon gas pressure 0.03+ / -0.01Mpa, current density 150+ / -10A / cm#+[2], air pressure difference 0.01+ / -0.005Mpa, obtaining diameter 3mm block amorphous alloy. Right amount of Ti element in Cu-Zr effectively promotes the amorphous alloy heat stability, amorphous ability and intensity.

The invention relates to a rare earth high-entropy bulk amorphous alloy with a magnetothermal effect and a preparation process thereof. The rare earth high-entropy bulk amorphous alloy comprises an amorphous phase with the volume fraction not lower than 95%. The ratio of various elements is an equal atomic ratio or a near equal atomic ratio. The components of the alloy mainly comprise La, Ce, Nd, Tb, Gd and Dy, transitional elements of Cu and Co, and the III main group element Al. The components of the alloy can be illustrated in formulas as shown in the specification. By adoption of the technical scheme, the rare earth bulk high-entropy amorphous alloy has good heat stability, excellent magnetothermal performance and application prospects in the field of magnetic refrigerating functional materials and structural materials compared with other component-based high-entropy amorphous alloys.

The invention relates to Sm radical Sm-Al-Co block non-crystal alloy that the constituents range is Smx(Al50-yCo50+y)100-x(x=50-58at%, y=-10-+7at%). The best constituents is Sm50Al25Co25, The method includes the following processes: mixing, taking copper film negative pressure casting adsorbing, the argon gas pressure is 0.06-0.08MPa, fusion melting current density is 120-140A / cm2, and draught head is 0.04+0.005MPa, the diameter of the block non-crystal is 3mm. The advantages of the invention are that it conquers the random of the constituents and develops Sm radical Sm-Al-Co block non-crystal alloy. It decreases the constituent deviation of testing Sm volatilizing quantity.

The invention relates to an iron-cobalt based bulk non-crystal alloy and a method for preparing the same. The iron-cobalt based bulk non-crystal alloy comprises the following components in atom content percentage: 28 to 40 percent of Fe, 28 to 40 percent of Co, 1 to 6 percent of Zr, 2 to 8 percent of Nd, 2 to 10 percent of Nb and 15 to 25 percent of B. The preparation method comprises the following steps: (1) the raw materials are prepared according to the ratio and smelted in a vacuum non-consumable arc-melting furnace under the protection of argon, the smelting current density is between 100 and 220A / cm<2>, and the mother alloy is turned over for smelting multiple times; and (2) the mother alloy after re-smelting is cast by a copper die negative pressure suction casting method to obtain the iron-cobalt based bulk non-crystal alloy. The magnetic alloy has good soft magnetization, and the maximum saturation magnetization reaches 79Am<2> / Kg.

The invention provides a multielement Mg-based amorphous alloy and belongs to the technical field of amorphous alloy. The multielement Mg-based amorphous alloy is characterized in that Mg65Cu22Ni3Y10-xNdx (x is 0,2,4,5,6 or 8) block amorphous alloy is prepared by using a wedge-shaped copper mould casting method, wherein the alloy with the best amorphous formation capacity is a Mg65Cu22Ni3Y5Nd5 amorphous alloy, and the amorphous formation critical thickness of the Mg65Cu22Ni3Y5Nd5 amorphous alloy is 3.6mm which is the maximum; the amorphous formation critical thickness of the Mg65Cu22Ni3Nd8Y2 alloy with the poorest amorphous formation capacity is also equivalent to that of the Mg65Cu22Ni3Y10 alloy, which indicates after Y is replaced by Nd, the amorphous formation capacity of the alloy is improved at different degrees; and the alloy with the best thermal stability is Mg65Cu22Ni3Y8Nd2 amorphous alloy, and the thermal stability of the Mg65Cu22Ni3Y8Nd2 amorphous alloy is greatly improved as compared with that of the Mg65Cu22Ni3Y10 alloy.

The application discloses a corrosion-resistant composite for a water turbine, and a preparation method and an application thereof. The corrosion-resistant composite for the water turbine is formed by compositing Fe-based amorphous material and in-situ synthesized boride, and consists of components by following specific weight percentage: 26wt% of Cr, 5-15wt% of B, 3wt% of Si, 3wt% of Cu, 5wt% of Ni, 10wt% of Mo and the balance Fe. The raw materials for preparing the corrosion-resistant composite for the water turbine are fed into a vacuum gas atomization furnace so as to be smelted and atomized, and amorphous material / boride composite powder is obtained after powder screening. When the amorphous material / boride composite powder is used for preparing a corrosion-resistant composite coating, the coating is prepared by adopting a hypersonic flame spraying technology. The corrosion-resistant composite for the water turbine can obtain the composite coating good in bonding strength with a base body, high in hardness, and excellent in corrosion resisting performance.

The invention discloses an Al-Ni-Y-Ca aluminum-based amorphous alloy and a preparation method thereof, and relates to the field of amorphous alloys. Nominal chemical components of the aluminum-based amorphous alloy are Al85-xNi7Y8Cax, where x is greater than 0 and smaller than 6; the atomic percent of Al+Ca is 85 percent, the atomic percent of Ni is 7 percent, and the atomic percent of Y is 8 percent. The alloy is prepared by using a melt-spinning method, Ar gas is adopted for protection, the injection pressure is 0.8MPa, the rotating speed of a copper roller is 30m / s, and the vacuum degree is 0.1 to 2Pa. The obtained aluminum-based amorphous alloy has a simple system, is low in cost, has good amorphous forming ability and thermal stability, and has a wide application prospect.

The invention provides a cobalt-based bulk amorphous alloy as shown in the formula CoaWbBc, wherein a, b and c are the atomic percents of corresponding elements; and a=54-70, b=15-30, c=12-19, and a+b+c=100. The cobalt-based bulk amorphous alloy provided by the invention has the superhigh strength, superhigh hardness, extremely high heat stability, the high amorphous forming ability and the good corrosion resistance and soft magnetic property. Experiment results show that the strength of the cobalt-based bulk amorphous alloy is 5500 MPa-6300 MPa, the glass transition temperature Tg is 844 K-960 K, and the corrosion current density in a 3.5 wt% NaCl solution is as low as 8 muA / cm<2>.

The invention discloses a method for inducing A184Ni10Gd6 amorphous alloy to generate phase separation. The method comprises the following steps: performing corrosion treatment on an A184Ni10Gd6 amorphous alloy strip in a nitric acid methanol solution, and washing to obtain an amorphous sample subjected to phase separation. The amorphous strip can be induced to generate phase separation by using a simple corrosion method, the method is simple and feasible, and the prepared sample is still in an amorphous state without conspicuous crystallization phenomenon. The corroded amorphous strip has honeycomb shaped holes, can be used for preparing a nano porous material and can be used in the fields such as catalysis and batteries. In addition, the plasticity of the amorphous alloy subjected to phase separation can be improved, expansion of a shearing zone can be obstructed by the second phase in partial areas, and thus the plasticity can be improved.

The invention relates to a FeZrYB series bulk amorphous alloy with excellent soft magnetic properties and a preparation method thereof. The alloy composition (atomic percentage) of the present invention is: Fe 63-83%, Zr 0.5-6%, Y 2-8%, B 13-27%. The preparation process of the alloy is as follows: the industrial pure metal raw material and FeB are mixed according to the alloy formula, and the vacuum non-consumable electric arc furnace is used for multiple smelting, and the copper mold negative pressure suction casting method is used to cast the bulk amorphous alloy. The bulk amorphous alloy of the invention has excellent soft magnetic properties, and the saturation magnetization is 1.1T. The bulk amorphous alloy of the invention can be widely used in magnetic devices in the fields of information, communication, computer and the like.

The invention discloses an iron-based amorphous / carbon nanotube composite material for a low-loss and high-corrosion-resistance transformer iron core and a preparing method and application of the iron-based amorphous / carbon nanotube composite material. The material comprises 98.5 wt%-99.5 wt% of an iron-based amorphous structure and 0.5 wt%-1.5 wt% of a carbon nanotube. The iron-based amorphous structure comprises following components including, by weight percent, 28 wt% of Cr, 3 wt% of B, 6 wt% of Si, 4 wt% of P, 5 wt% of Ni, 8 wt% of Mo 3wt% of Nb, and the balance Fe. The carbon nanotube isprepared through a chemical vapor deposition method. Firstly, raw materials for preparing the iron-based amorphous structure are added into a vacuum gas atomization furnace to be smelted and atomized,powder screening is conducted, then, 304 stainless steel is adopted for wrapping the powder, and a wire is formed. According to application of the finished wire to preparing of iron-based amorphous / carbon nanotube composite electromagnetic shielding materials, the rapid quenching technology is adopted for preparing an amorphous strip, and two spraying ports are adopted in the rapid quenching process for continuous and uniform spraying of the iron-based amorphous structure and the carbon nanotube. The prepared composite material is low in loss, high in energy efficiency and good in corrosion resisting performance, and wide application prospects are achieved.

The invention relates to a rare earth high-entropy bulk amorphous alloy with magnetocaloric effect and its preparation process. The rare-earth high-entropy bulk amorphous alloy contains an amorphous phase with a volume fraction of not less than 95%, and various elements are equal to Atomic ratio or nearly equivalent atomic ratio, the alloy composition mainly includes La, Ce, Nd, Tb, Gd, Dy, as well as transition group elements Cu, Co, and the main group III element Al, and its composition can be expressed by the following formula: (La 1 / 6 Ce 1 / 6 Nd 1 / 6 m 1 / 6 co 1 / 6 Cu 1 / 6 ) y Al x . or (La 1 / 6 Ce 1 / 6 Dy 1 / 6 Q 1 / 6 co 1 / 6 Cu 1 / 6 ) b Al a . Due to the adoption of the above technical solution, the present invention produces a rare earth block high-entropy amorphous alloy. Compared with other component-based amorphous high-entropy amorphous, it has good thermal stability and excellent magnetocaloric properties, and has application prospects in magnetic refrigeration functional materials and structural materials.

The invention discloses a hydrogenated heavy rare earth high-entropy composite material, a preparation method and application thereof. The chemical molecular formula of the hydrogenated heavy rare earth high-entropy composite material is A 20 B 18 C 18 co 20 al 24 h x , wherein A, B, and C are different from each other, and are respectively selected from one of Gd, Tb, Dy, Ho, Er, and Tm, and x>0. The preparation method includes: weighing the corresponding raw materials according to the chemical molecular formula of the high-entropy composite material; melting and cooling the raw materials to obtain a master alloy ingot; melting the master alloy ingot into an alloy melt, and sucking and casting it into a high-entropy amorphous alloy rod The material is crushed and ball-milled to obtain high-entropy amorphous alloy powder; the powder is treated with isothermal hydrogen absorption to obtain a hydrogenated heavy rare earth high-entropy composite material. The invention induces the precipitation of rare earth hydrides in the amorphous matrix by performing isothermal hydrogen absorption treatment on the high-entropy amorphous alloy, greatly improves the magnetic entropy change of the alloy, and at the same time significantly reduces the hysteresis loss of the alloy. The hydrogenated heavy rare earth high-entropy composite material can be used as a magnetic refrigerant.

The present invention relates to a smelting process of a master alloy containing phosphorus and carbon, which comprises the following steps: (1) mixing and melting an iron source and a carbon source at a first temperature to form a first pre-alloy melt, and make the first pre-alloy The mass content of each element of S, Al, Ti, Zr in the alloy melt is not more than 0.05%, wherein the first temperature is 1400°C-1600°C; (2) cooling the first pre-alloy melt to the second temperature, and adding a phosphorus source to the first pre-alloyed molten liquid for smelting to form a second pre-alloyed molten liquid, so that the mass content of each element of S, Al, Ti, and Zr in the second pre-alloyed molten liquid is not more than 0.05%, Wherein the second temperature is 1200°C-1350°C; additives are added to the second pre-alloyed molten liquid to form slagging and slagging off, and a master alloy containing phosphorus and carbon is obtained after filtering. The present invention also provides a master alloy containing phosphorus and carbon obtained by the above smelting process.

The invention discloses a Fe-based block noncrystal alloy and making method, which comprises the following steps: (1) allocating raw material with 48-70% Fe, 23-37% Nd, 4-10% Al and 2-6% B; (2) adopting copper mould suction adsorbing casting method to make the non-crystal alloy; (3) adding 2-8T pulse magnetic field with frequency at 0.02-0.05Hz; annealing in the vacuum under 100-350 deg.c for 10-30 min.

The invention discloses zircon-based amorphous alloy. The zircon-based amorphous alloy is composed of Zr, Hf, Al, Cu, Ni, Y and Ag elements. The zircon-based amorphous alloy is composed of, by atomic molar percentage, 40-70% of Zr, 1-10% of Hf, 15-40% of Al, 5-15% of Cu, 5-15% of Ni, 0.2-5% of Y and 0.2-5% of Ag. The zircon-based amorphous alloy is good in glass forming ability (GFA) and good in glass forming capacity, the zircon-based amorphous alloy is a specular surface after being formed and does not need to be additionally machined, and the cost is low.

The present invention provides a kind of such as formula Co a W b B c The cobalt-based bulk amorphous alloy shown, wherein a, b and c are the atomic percentages of the corresponding elements; a=54-70; b=15-30; c=12-19; ​​a+b+c=100 . The cobalt-based bulk amorphous alloy provided by this application has ultra-high strength, ultra-high hardness, extremely high thermal stability, strong amorphous forming ability, good corrosion resistance and soft magnetic properties; the experimental results show that this The strength of the cobalt-based bulk amorphous alloy provided by the application is 5500MPa-6300MPa, the glass transition temperature Tg is 844K-960K, and the corrosion current density in 3.5wt / % NaCl solution is as low as 8μA / cm 2 .