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Aqueous dual membrane glue, and fabricating method

A technology of water-based laminating adhesive and softening water, which is applied in the field of laminating adhesive, can solve the problems of difficult promotion, high sales price, and performance that cannot reach the level of oil-based adhesives, and achieve the effect of reducing fire hazards and improving cohesion

Active Publication Date: 2006-12-06
上海奇想青晨新材料科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Expensive sales price, it is very difficult to promote in our country
For this reason, China has recently introduced a water-based laminating adhesive blended with PVA emulsion and tackifying resin. Although it solves the problems of toxicity and flammability, its performance still cannot reach the level of oil-based adhesives and can only be used for some adhesives. Low-end products
From the perspective of the market's requirements for the packaging industry, it is hoped that the quality of laminating products will be further improved. From a technical point of view, the oil-based adhesives commonly used in China cannot meet these requirements of users, and the domestic low-grade water-based adhesives cannot meet these requirements.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] Embodiment 1 (unit: kilogram)

[0020] formula:

[0021] Reactor:

[0022] 1. Demineralized water 200 phenol ether sulfuric acid 1.5 ammonium bicarbonate 0.3 sodium bicarbonate 0.2

[0023] 2. Demineralized water 8.0 ammonium persulfate 1.0

[0024] Pre-emulsification tank

[0025] 3. Demineralized water 200 phenol ether sulfuric acid 4.0 sulfosuccinic acid 1.0 ammonium bicarbonate

[0026] 1.5

[0027] 4. Butyl acrylate 300 Methyl methacrylate 200 Diallyl phthalate 20 Dodecyl mercaptan 0.5 Hydroxyethyl acrylate 10 Acrylic acid 10

[0028] 5. Demineralized water 8.0 N-methylolacrylamide 1.0

[0029] 6. Demineralized water 8.0 ammonium persulfate 1.0

[0030] 7. Mineral oil 1.0

[0031] 8. OT-753

[0032] 9. Water-soluble acrylic resin 10

[0033] 10. Ammonia 10

[0034] Steps:

[0035] Prepare the bottom liquid 1 in the reaction kettle in order, then start stirring to raise the temperature to 88°C; start the stirring in the pre-emulsifica...

Embodiment 2

[0036] Embodiment 2 (unit: kilogram)

[0037] formula:

[0038] Reactor

[0039] 1. Demineralized water 200 sulfosuccinic acid 6.0 water-soluble acrylic resin 5.0

[0040] 2. Demineralized water 8.0 ammonium persulfate 1.3

[0041] Pre-emulsification tank

[0042] 3. Demineralized water 200 phenol ether sulfuric acid 5.0 sulfosuccinic acid 5.0 sodium bicarbonate 2.0

[0043] 4. Butyl Acrylate 350 Methyl Methacrylate 150 Diallyl Phthalate 20

[0044] Dodecyl Mercaptan 0.5 Hydroxyethyl Acrylate 10 Acrylic Acid 10

[0045] 5. Demineralized water 8.0 N-methylolacrylamide 5.0

[0046] 6. Demineralized water 8.0 ammonium persulfate 1.3

[0047] 7. Mineral oil 1.0

[0048] 8. OT-753

[0049] 9. Water-soluble acrylic resin 10

[0050] 10. Ammonia 10

[0051] Steps

[0052] With embodiment 1.

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PUM

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Abstract

This invention discloses a method for preparing a water-borne laminating adhesive. The adhesive is composed of: monomers including acrylic acid and methyl methacrylate, functional monomers including diallyl phthalate, hydroxyethyl acrylate, diallyl maleate and N-hydroxymethylacrylamide, initiator ammonium perdulfate, emulsifiers including sulfosuccinic acid and phenol ether sulfuric acid, buffers including sodium bicarbonate and ammonium bicarbonate, lauryl mercaptan, functional accessory materials including OT-75, mineral oil and water-soluble acrylic resin, pH regulator ammonia solution, and soft water. The adhesive has such advantages as no pollution, no toxicity, high safety and high cohesive force.

Description

technical field [0001] The invention relates to a laminating adhesive applied to the bonding of paper-plastic composite materials, in particular to a water-based laminating adhesive and a manufacturing method thereof. Background technique [0002] With the rapid development of the packaging industry, paper-plastic composite materials are more and more widely used in our daily life. [0003] Adhesives used in paper-plastic composites are divided into two types: oily and water-based, but the toxicity and safety problems of oil-based glue are becoming more and more prominent. The health of workers is seriously damaged, and a large amount of volatilization during the drying process can easily cause fires. It is the general trend to replace oil-based glue with water-based glue in the laminating industry. [0004] Although water-based glue is safe and environmentally friendly, its synthesis technology is difficult and the cost of raw materials used is relatively high, which is m...

Claims

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Application Information

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IPC IPC(8): C09J133/04C08F20/10C08F2/24
Inventor 刘国富赵永奇毛继明戚向东
Owner 上海奇想青晨新材料科技股份有限公司
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