This invention discloses an inorganic-doped surface-grafted demulsification functional layer oil-water separation
microsphere resin agglomeration material and its preparation method. The invention uses
diallyl phthalate-
acrylate highly absorbent resin as a substrate, and simultaneously introduces a certain proportion of hydrophilic monomers to form a synergistic effect. Through multi-level structural design, surface phosphonation modification is initiated, and chemically grafted demulsification functional molecular chain matrix and -Si-O-P-
inorganic nanoparticles are constructed on the resin surface. This creates a four-in-one micro-nano multi-level rough structure integrating "highly absorbent substrate-
phosphine coordination interface-micro-nano rough structure-demulsification functional layer," possessing both demulsification and agglomeration adsorption functions. This invention achieves the
coupling of demulsification and agglomeration adsorption functions at the molecular scale, exhibiting highly efficient separation performance for emulsified
oily wastewater. It realizes integrated and efficient separation of emulsified
oily wastewater through demulsification-agglomeration-adsorption, and possesses excellent cyclic regeneration stability.