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Elastic emulsion with high adhesive force and preparing method thereof

An elastic emulsion and strong adhesion technology, applied in the direction of coating, etc., can solve the problems of unsatisfactory substrate adhesion, easy staining, and easy foaming of the coating, so as to improve water resistance and stain resistance, improve The effect of tensile strength

Inactive Publication Date: 2017-01-04
江苏紫石化工科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Acrylic emulsion has the advantages of water resistance, transparency, weather resistance and chemical resistance, high strength, etc., and it is cheap, the synthesis process is mature, and the application field is widely in line with environmental protection requirements. Therefore, it has been widely used in the coating industry, especially in the field of architectural coatings. With the wide application and popularization, higher requirements are put forward for the latex in view of the easy cracking, easy staining and unsatisfactory adhesion to the substrate of the existing architectural coatings. In order to overcome the defects of the above-mentioned architectural coatings, The Chinese patent application number is CN98111639.6, which discloses a synthetic technology called pure acrylic elastic emulsion, which solves the shortcoming of easy cracking of architectural coatings to a certain extent, but also has insufficient adhesion to the substrate, and the coating is easy to be exposed to water. Disadvantages of foaming and poor stain resistance

Method used

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Examples

Experimental program
Comparison scheme
Effect test

specific Embodiment 1

[0021] An elastic emulsion with strong adhesion, said elastic emulsion with strong adhesion is composed of the following components in parts by weight: the core monomer is: 1 part of methyl methacrylate, 4 parts of styrene, and diene phthalate 0.1 part of propyl ester, 3 parts of butyl acrylate; shell monomer: 1 part of methyl methacrylate, 3 parts of styrene, 5 parts of butyl acrylate, 1 part of methacrylic acid, 0.1 part of glycidyl methacrylate, 0.1 part of silicone monomer, 0.1 part of diacetone amide, 0.2 part of adipic hydrazide, 0.5 part of emulsifier, 1 part of initiator, 48 parts of water.

[0022] The emulsifier is a mixture of two or more of allyl sulfonate, alkyl polyoxyethylene ether, and alkyl polyoxyethylene sulfate.

[0023] The initiator is a mixture of ammonium persulfate and potassium persulfate.

[0024] A kind of preparation method according to described strong adhesion elastic emulsion, comprises the steps:

[0025] (1) Turn on the agitator of the emuls...

specific Embodiment 2

[0032] A kind of strong adhesion elastic emulsion, described strong adhesion elastic emulsion is made up of following components according to weight parts: core monomer is: 10 parts of methyl methacrylate, 12 parts of styrene, phthalic acid diene 5 parts of propyl ester, 25 parts of butyl acrylate; shell monomer: 8 parts of methyl methacrylate, 10 parts of styrene, 12 parts of butyl acrylate, 2 parts of methacrylic acid, 5 parts of glycidyl methacrylate, 3 parts of silicone monomer, 7 parts of diacetone amide, 8 parts of adipic hydrazide, 2 parts of emulsifier, 1-3 parts of initiator, 52 parts of water.

[0033] The emulsifier is a mixture of two or more of allyl sulfonate, alkyl polyoxyethylene ether, and alkyl polyoxyethylene sulfate.

[0034] The initiator is a mixture of ammonium persulfate and potassium persulfate.

[0035] A kind of preparation method according to described strong adhesion elastic emulsion, comprises the steps:

[0036] (1) Turn on the agitator of the ...

specific Embodiment 3

[0043] An elastic emulsion with strong adhesion, said elastic emulsion with strong adhesion is composed of the following components in parts by weight: the core monomer is: 6 parts of methyl methacrylate, 9 parts of styrene, and diene phthalate 3 parts of propyl ester, 19 parts of butyl acrylate; shell monomer: 7 parts of methyl methacrylate, 8 parts of styrene, 10 parts of butyl acrylate, 1.4 parts of methacrylic acid, 3 parts of glycidyl methacrylate, 2 parts of silicone monomer, 4 parts of diacetone amide, 6 parts of adipic hydrazide, 1 part of emulsifier, 2 parts of initiator, 50 parts of water.

[0044] The emulsifier is a mixture of two or more of allyl sulfonate, alkyl polyoxyethylene ether, and alkyl polyoxyethylene sulfate.

[0045] The initiator is a mixture of ammonium persulfate and potassium persulfate.

[0046] A kind of preparation method according to described strong adhesion elastic emulsion, comprises the steps:

[0047] (1) Turn on the agitator of the emul...

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PUM

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Abstract

The invention discloses an elastic emulsion with high adhesive force and a preparing method thereof. The elastic emulsion is composed of, by weight, nuclear monomers: 1-10 parts of methyl methacrylate, 4-12 parts of styrene, 0.1-5 parts of diallyl phthalate and 3-25 parts of butyl acrylate; shell monomers: 1-8 parts of methyl methacrylate, 3-10 parts of styrene, 5-12 parts of butyl acrylate, 1-2 parts of methacrylic acid, 0.1-5 parts of glycidyl methacrylate, 0.1-3 parts of organosilicone monomer, 0.1-7 parts of diacetone amide, 0.2-8 parts of adipic dihydrazide, 0.5-2 parts of emulgator, 1-3 parts of initiator and 48-52 parts of water. An outer wall elastic coating prepared from the elastic emulsion has excellent base material adhesive force, the defect that an outer wall elastic coating foams in the presence of water is overcome, and water resistance and stain resistance are realized.

Description

technical field [0001] The invention belongs to the field of emulsions for architectural coatings, and in particular relates to an elastic emulsion with strong adhesion and a preparation method thereof. Background technique [0002] Acrylic emulsion has the advantages of water resistance, transparency, weather resistance and chemical resistance, high strength, etc., and it is cheap, the synthesis process is mature, and the application field is widely in line with environmental protection requirements. Therefore, it has been widely used in the coating industry, especially in the field of architectural coatings. With the wide application and popularization, higher requirements are put forward for the latex in view of the easy cracking, easy staining and unsatisfactory adhesion to the substrate of the existing architectural coatings. In order to overcome the defects of the above-mentioned architectural coatings, The Chinese patent application number is CN98111639.6, which discl...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F220/18C08F220/14C08F212/08C08F220/06C08F220/32C08F230/08C08F222/26C09D133/08
CPCC08F212/08C08F220/18C08F220/1804C09D133/08C08F220/14C08F220/06C08F220/325C08F230/08C08F222/26
Inventor 景伯华宋玉纳
Owner 江苏紫石化工科技有限公司
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