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Method for preparing films of cobalt silicate

A technology of cobalt silicide and thin film, which is applied in the field of preparation of cobalt silicide thin film, and can solve the problems of poor thermal stability and limitation of thin film

Inactive Publication Date: 2006-12-06
SHANGHAI HUA HONG NEC ELECTRONICS
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  • Summary
  • Abstract
  • Description
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  • Application Information

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Problems solved by technology

[0004] The preparation method of cobalt silicide thin film in the prior art adopts Co, Si direct reaction forms CoSi 2 Thin film, the film cannot withstand high temperature treatment above 900°C, and the thermal stability of the film is poor, so it is limited in the application of conventional CMOS technology

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  • Method for preparing films of cobalt silicate
  • Method for preparing films of cobalt silicate
  • Method for preparing films of cobalt silicate

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Embodiment Construction

[0013] Such as figure 1 As shown, a method for preparing a cobalt silicide thin film of the present invention includes the following steps. First, Ti with a thickness of 25-45 Ȧ and a thickness of 70-150 Ȧ are respectively deposited on a silicon substrate with a 100-crystal orientation by physical vapor deposition. Co and TiN with a thickness of 80-200 Ȧ; followed by pure N at 5slm 2 The medium temperature is 580-700°C, and the process time is 60-120S for rapid annealing; again in the mixed solution of ammonium hydroxide, hydrogen peroxide and deionized water (NH 4 OH:H 2 o 2 :H 2 O=1:5:5, referred to as APM) and sulfuric acid and hydrogen peroxide mixed solution (H 2 SO 4 :H 2 o 2 =4:1, referred to as SPM) for selective etching in the chemical solution tank; finally, perform the second rapid annealing in 5slm pure N2, the temperature is 825-900°C, and the process time is 30-60S.

[0014] CoSi produced by a method for preparing a cobalt silicide thin film according to ...

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Abstract

The method for preparing thin film of cobalt silicide includes steps: first, depositing Ti, Co, TiN in sequence on silicon base plate; next, carrying out short annealing in N2; then, carrying out selected etching in liquor tank of containing APM and SPM respectively; finally, carrying out second short annealing in N2. Thin film of cobalt silicide prepared by the disclosed method possesses advantages of less defect density on film, better heat stability, silicide and silicon matched to crystal lattice on substrate well so as to have more flattening interface, and reduced leakage current of PN junction.

Description

technical field [0001] The invention relates to the field of integrated circuit production and manufacturing, in particular to a method for preparing a cobalt silicide thin film. Background technique [0002] As the size of silicon unit devices continues to develop in the direction of deep submicron, polycrystalline CoSi 2 The phase transition of thin films on narrow polysilicon lines is not limited by the nucleation process, so it is widely used in VLSI manufacturing processes. Polycrystalline CoSi 2 When manufacturing VLSI, self-aligned CoSi can be formed on silicon wafers without photolithography on MOS devices. 2 Drain-source contact and gate electrode. As the size of CMOS devices continues to decrease in the horizontal and vertical directions, the shallow junction limits the thickness of the polycrystalline metal silicide film. When the film becomes thinner, the silicide or silicon interface is uneven and the thermal stability is poor, which seriously affects the PN ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L21/3205H01L21/321H01L21/318
Inventor 陆杰季芝慧
Owner SHANGHAI HUA HONG NEC ELECTRONICS
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