Process for improving the co-polymerization of ethylene and an olefin co-monomer in a polymerization loop reactor.
An olefin comonomer and loop reactor technology, applied in the field of olefin polymerization, can solve problems such as difficulty in controlling reaction parameters, and achieve the effects of less temperature oscillation, improved fluctuation, and reduced risk of swelling
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[0026] The invention is particularly applicable to the copolymerization process of ethylene and olefin comonomers in a polymerization loop reactor. The term "ethylene copolymerization" includes the copolymerization of ethylene and olefinic comonomers. Polymerization of ethylene involves feeding to a reactor reactants comprising monomeric ethylene, light hydrocarbon diluent, catalyst, comonomer and optionally a cocatalyst and a terminator such as hydrogen. The term "copolymer" means a polymer prepared by linking two different types on the same polymer chain.
[0027] Olefin comonomers suitable according to the present invention may include, but are not limited to, aliphatic C 3 -C 20 alpha-olefins. suitable aliphatic C 3 -C 20 Examples of alpha-olefins include propylene, 1-butene, 4-methyl-1-pentene, 1-hexene, 1-octene, 1-decene, 1-dodecene, 1-tetradecene ene, 1-hexadecene, 1-octadecene and 1-eicosene. The invention is specifically described with reference to the copolym...
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