Treatment of textile product for imparting water and oil repellency
a technology for textile products and oil repellency, applied in the direction of physical treatment, detergent compounding agents, liquid repellent fibres, etc., can solve the problems that the exhaust process oil repellency and soil releasability, and cannot achieve the requirements of water repellency and oil repellency. , to achieve the effect of reducing the amount of was
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example 2
Preparative Example 2
Preparation of (b) a Fluorine-containing Water- and Oil-repellent Agent Free of Vinyl Chloride
[0115] CH.sub.2.dbd.CHCOO(CH.sub.2).sub.2(CF.sub.2CF.sub.2).sub.nCF.sub.2C-F.sub.3 (a mixture of compounds wherein n is 3, 4 and 5 in a weight ratio of 5:3:1) (FA), stearyl acrylate (StA), 2-hydroxyethyl methacrylate (2ERA), glycidyl methacrylate (BLENMER G), N-methylolacrylamide (N-MAM), 3-chloro-2-hydroxypropyl methacrylate (TOPOLEN M), deionized water, n-laurylmercaptan (LSH), polyoxyethylene-alkylphenyl ether sulfate ammonium (HITENOL N-17, an anionic emulsifier), polyoxyethylenealkylpheny-l ether (NONION HS-220, a nonionic emulsifier), sorbitan monolaurate (LP-20R, a nonionic emulsifier) and dipropylene glycol monomethylether (DPM) were mixed in the amounts shown in Table 4 to give a mixture liquid.
[0116] This mixture liquid was heated at 60.degree. C. and emulsified by a high pressure homogenizer. The resultant emulsion was charged into a 1 L autoclave and subject...
example 1
[0117] 0.9 Grams of a mixture liquid of the fluorine-containing water- and oil-repellent agent (a) (which is a fluorine-containing water- and oil-repellent agent containing vinyl chloride) produced in Preparative Example 1 and the fluorine-containing water- and oil-repellent agent (b) (which is a water- and oil-repellent agent free of vinyl chloride) produced in Preparative Example 2 (the mixing weight ratio of 8 to 2 in terms of solid) and 5 g of a stain blocking agent FX-657 (manufactured by 3M) were diluted with water to 1,000 g to give a mixture liquid. The solid weight ratio of the water- and oil-repellent agent and the stain blocking agent was 1:5.6. The pH of the mixture liquid was adjusted to 1.5 by adding a 10% aqueous solution of sulfamic acid to give a treatment liquid.
[0118] A carpet (8.9 cm.times.18.2 cm, nylon 6,6, cut piled, density: 36 oz / yd.sup.2) was immersed in the treatment liquid for 30 seconds. Then, the carpet was squeezed to give the WPU (wet pick up) of 300%...
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